Synthesis and application of complexes of a novel chiral diphenylphosphino-functionalized N-heterocyclic carbene

Synlett

Volumn , Issue 10, 2004, Pages 1789-1793

  Bappert, Erhard ^a   Helmchen, Günter ^a  

^a UNIVERSITY OF HEIDELBERG   (Germany)

Author keywords

Asymmetric catalysis; Chiral N heterocyclic carbenes; Chiral P ligands; Enantioselective hydrogenation; Rhodium

Indexed keywords

CARBENOID; HETEROCYCLIC COMPOUND; PHOSPHINIC ACID DERIVATIVE;

ARTICLE; ASYMMETRIC CATALYSIS; CATALYSIS; CHEMICAL REACTION; CHIRALITY; ENANTIOSELECTIVITY; HYDROGENATION; LIGAND BINDING; REACTION ANALYSIS; SYNTHESIS;

EID: 4143151719     PISSN: 09365214     EISSN: None     Source Type: Journal    
DOI: 10.1055/s-2004-829548     Document Type: Article

References (51)

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48. 2 as eluent. After evaporation of the solvent, 2-methyl-succinic acid dimethyl ester was obtained in quantitative yield. The ee value was determined to be 98.2% ee by GC on a chiral phase (analytical data cf. Table 1).
49. (a) The rhodium complex (S,S)-6 was also tested in the catalytic asymmetric addition of phenylboronic acid to enones. Using 3 mol% of the complex (S,S)-6 enantioselectivities up to 94% could be achieved (b) J.-M. Becht and E. Bappert, unpublished results.
50. (a) The rhodium complex (S,S)-6 was also tested in the catalytic asymmetric addition of phenylboronic acid to enones. Using 3 mol% of the complex (S,S)-6 enantioselectivities up to 94% could be achieved (b) J.-M. Becht and E. Bappert, unpublished results.
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