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Volumn 24, Issue 3, 2005, Pages 338-340

A ruthenium olefin metathesis catalyst with a four-membered N-heterocyclic carbene ligand

Author keywords

[No Author keywords available]

Indexed keywords

BOND DISTANCES; LIGANDS; METATHESIS REACTIONS; STERIC HINDRANCE;

EID: 13444272137     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om049092h     Document Type: Article
Times cited : (89)

References (38)
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    • For recent reviews on applications of ruthenium-based catalysts
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    • Schrock, R.R.1
  • 6
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    • Fürstner, A.1
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    • (d) Fürstner, A. Angew. Chem. 2000, 112, 3140-3172; Angew. Chem., Int. Ed. 2000, 39, 3012-3043.
    • (2000) Angew. Chem., Int. Ed. , vol.39 , pp. 3012-3043
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    • 0035794963 scopus 로고    scopus 로고
    • (b) Choi, T.-L.; Chatterjee, A. K.; Grubbs, R. H. Angew. Chem. 2001, 113, 1317-1319; Angew. Chem., Int. Ed. 2001, 40, 1277-1279.
    • (2001) Angew. Chem., Int. Ed. , vol.40 , pp. 1277-1279
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    • 0000833459 scopus 로고    scopus 로고
    • (d) Bielwaski, C. W.; Grubbs, R. H. Angew. Chem. 2000, 112, 3025-3028; Angew. Chem., Int. Ed. 2000, 39, 2903-2906.
    • (2000) Angew. Chem. , vol.112 , pp. 3025-3028
    • Bielwaski, C.W.1    Grubbs, R.H.2
  • 15
    • 0034682918 scopus 로고    scopus 로고
    • (d) Bielwaski, C. W.; Grubbs, R. H. Angew. Chem. 2000, 112, 3025-3028; Angew. Chem., Int. Ed. 2000, 39, 2903-2906.
    • (2000) Angew. Chem., Int. Ed. , vol.39 , pp. 2903-2906
  • 28
    • 13444299540 scopus 로고    scopus 로고
    • note
    • int = 0.1018), 456 parameters, R1(I > 2σ(I)) = 0.0554, wR2(all data) - 0.0959.
  • 29
    • 13444307561 scopus 로고    scopus 로고
    • note
    • 2.20 Crystallographic data have been deposited at the CCDC, 12 Union Road, Cambridge CB2 1EZ, U.K. and copies can be obtained on request, free of charge, by quoting the publication citation and the deposition numbers 243404 (5) and 247037 (analogue of 3).
  • 30
    • 13444286737 scopus 로고    scopus 로고
    • note
    • carbone = 1.982-1.974 ̊).
  • 32
    • 0000322262 scopus 로고    scopus 로고
    • Theoretical calculations on the free carbene showed the same behavior Su, M.-D.; Chu, S.-Y. Chem. Phys. Lett. 1999, 308, 283-288.
    • (1999) Chem. Phys. Lett. , vol.308 , pp. 283-288
    • Su, M.-D.1    Chu, S.-Y.2
  • 33
    • 13444275872 scopus 로고    scopus 로고
    • Conversion is determined by GC spectroscopy with tridecane as standard
    • Conversion is determined by GC spectroscopy with tridecane as standard.
  • 34
    • 13444313222 scopus 로고    scopus 로고
    • note
    • 1H NMR.
  • 35
    • 13444284550 scopus 로고    scopus 로고
    • note
    • In comparison with complex 2, a smaller PDI was obtained when the reaction was run neat. This can be attributed to a slowergelling process (complex 2, 30 min; complex 5,6 h) that favors better diffusion inside the sample.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.