-
4
-
-
2742548357
-
-
J. Jortner and J. Ulstrup, J. Chem. Phys. 63, 4358 (1975); J. Jortner and M. Bixon, ibid. 88, 167 (1988); J. Cortes, H. Heitele, J. Jortner, J. Phys. Chem. 98, 2527 (1994).
-
(1975)
J. Chem. Phys.
, vol.63
, pp. 4358
-
-
Jortner, J.1
Ulstrup, J.2
-
5
-
-
0038964839
-
-
J. Jortner and J. Ulstrup, J. Chem. Phys. 63, 4358 (1975); J. Jortner and M. Bixon, ibid. 88, 167 (1988); J. Cortes, H. Heitele, J. Jortner, J. Phys. Chem. 98, 2527 (1994).
-
(1988)
J. Chem. Phys.
, vol.88
, pp. 167
-
-
Jortner, J.1
Bixon, M.2
-
6
-
-
0001007423
-
-
J. Jortner and J. Ulstrup, J. Chem. Phys. 63, 4358 (1975); J. Jortner and M. Bixon, ibid. 88, 167 (1988); J. Cortes, H. Heitele, J. Jortner, J. Phys. Chem. 98, 2527 (1994).
-
(1994)
J. Phys. Chem.
, vol.98
, pp. 2527
-
-
Cortes, J.1
Heitele, H.2
Jortner, J.3
-
9
-
-
0002322432
-
-
C. Creutz, Prog. Inorg. Chem. 30, 1 (1983); K. Prassides, Ed., Mixed Valency Systems: Applications in Chemistry, Physics, and Biology (NATO ASI Ser., Kluwer Academic, Dordrecht, Netherlands, 1991).
-
(1983)
Prog. Inorg. Chem.
, vol.30
, pp. 1
-
-
Creutz, C.1
-
10
-
-
0003740824
-
-
NATO ASI Ser., Kluwer Academic, Dordrecht, Netherlands
-
C. Creutz, Prog. Inorg. Chem. 30, 1 (1983); K. Prassides, Ed., Mixed Valency Systems: Applications in Chemistry, Physics, and Biology (NATO ASI Ser., Kluwer Academic, Dordrecht, Netherlands, 1991).
-
(1991)
Mixed Valency Systems: Applications in Chemistry, Physics, and Biology
-
-
Prassides, K.1
-
11
-
-
0000776899
-
-
N. S. Hush, Prog. Inorg. Chem. 8, 391 (1967); Coord. Chem. Rev. 64, 135 (1985).
-
(1967)
Prog. Inorg. Chem.
, vol.8
, pp. 391
-
-
Hush, N.S.1
-
12
-
-
33749130604
-
-
N. S. Hush, Prog. Inorg. Chem. 8, 391 (1967); Coord. Chem. Rev. 64, 135 (1985).
-
(1985)
Coord. Chem. Rev.
, vol.64
, pp. 135
-
-
-
13
-
-
1842365332
-
-
note
-
max relates to the V shown in Fig. 1 (10). For example, the V values estimated for Paddon-Row's σ-bridged aromatic, cyanoolefin systems (11), which appeared to be the best-documented series of such measurements available, have recently been retracted, with the statement that both the CT band intensities and back-ET rate constants are basically determined by mixing of the IV state with locally excited states (10).
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-
-
15
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0002566614
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-
N. S. Hush et al., Chem. Phys. Lett. 117, 8(1985); H. Oevering et al., J. Am. Chem. Soc. 109, 3258 (1987); M. N. Paddon-Row et al., J. Phys. Chem. 92, 6958 (1988); H. Oevering, J. W. Verhoeven, M. N. Paddon-Row, J. M. Warman, Tetrahedron 45, 4751 (1989); J. M. Warman et al., J. Phys. Chern. 95, 1979 (1991); J. Kroon, J. W. Verhoeven, M. N. Paddon-Row, A. M. Oliver, Angew. Chem. Int. Ed. Engl. 30, 1358 (1991); J. Kroon et al., J. Phys. Chem. 97, 5065 (1993).
-
(1985)
Chem. Phys. Lett.
, vol.117
, pp. 8
-
-
Hush, N.S.1
-
16
-
-
33845282528
-
-
N. S. Hush et al., Chem. Phys. Lett. 117, 8(1985); H. Oevering et al., J. Am. Chem. Soc. 109, 3258 (1987); M. N. Paddon-Row et al., J. Phys. Chem. 92, 6958 (1988); H. Oevering, J. W. Verhoeven, M. N. Paddon-Row, J. M. Warman, Tetrahedron 45, 4751 (1989); J. M. Warman et al., J. Phys. Chern. 95, 1979 (1991); J. Kroon, J. W. Verhoeven, M. N. Paddon-Row, A. M. Oliver, Angew. Chem. Int. Ed. Engl. 30, 1358 (1991); J. Kroon et al., J. Phys. Chem. 97, 5065 (1993).
-
(1987)
J. Am. Chem. Soc.
, vol.109
, pp. 3258
-
-
Oevering, H.1
-
17
-
-
33845279571
-
-
N. S. Hush et al., Chem. Phys. Lett. 117, 8(1985); H. Oevering et al., J. Am. Chem. Soc. 109, 3258 (1987); M. N. Paddon-Row et al., J. Phys. Chem. 92, 6958 (1988); H. Oevering, J. W. Verhoeven, M. N. Paddon-Row, J. M. Warman, Tetrahedron 45, 4751 (1989); J. M. Warman et al., J. Phys. Chern. 95, 1979 (1991); J. Kroon, J. W. Verhoeven, M. N. Paddon-Row, A. M. Oliver, Angew. Chem. Int. Ed. Engl. 30, 1358 (1991); J. Kroon et al., J. Phys. Chem. 97, 5065 (1993).
-
(1988)
J. Phys. Chem.
, vol.92
, pp. 6958
-
-
Paddon-Row, M.N.1
-
18
-
-
0000316512
-
-
N. S. Hush et al., Chem. Phys. Lett. 117, 8(1985); H. Oevering et al., J. Am. Chem. Soc. 109, 3258 (1987); M. N. Paddon-Row et al., J. Phys. Chem. 92, 6958 (1988); H. Oevering, J. W. Verhoeven, M. N. Paddon-Row, J. M. Warman, Tetrahedron 45, 4751 (1989); J. M. Warman et al., J. Phys. Chern. 95, 1979 (1991); J. Kroon, J. W. Verhoeven, M. N. Paddon-Row, A. M. Oliver, Angew. Chem. Int. Ed. Engl. 30, 1358 (1991); J. Kroon et al., J. Phys. Chem. 97, 5065 (1993).
-
(1989)
Tetrahedron
, vol.45
, pp. 4751
-
-
Oevering, H.1
Verhoeven, J.W.2
Paddon-Row, M.N.3
Warman, J.M.4
-
19
-
-
0005834661
-
-
N. S. Hush et al., Chem. Phys. Lett. 117, 8(1985); H. Oevering et al., J. Am. Chem. Soc. 109, 3258 (1987); M. N. Paddon-Row et al., J. Phys. Chem. 92, 6958 (1988); H. Oevering, J. W. Verhoeven, M. N. Paddon-Row, J. M. Warman, Tetrahedron 45, 4751 (1989); J. M. Warman et al., J. Phys. Chern. 95, 1979 (1991); J. Kroon, J. W. Verhoeven, M. N. Paddon-Row, A. M. Oliver, Angew. Chem. Int. Ed. Engl. 30, 1358 (1991); J. Kroon et al., J. Phys. Chem. 97, 5065 (1993).
-
(1991)
J. Phys. Chern.
, vol.95
, pp. 1979
-
-
Warman, J.M.1
-
20
-
-
33749309544
-
-
N. S. Hush et al., Chem. Phys. Lett. 117, 8(1985); H. Oevering et al., J. Am. Chem. Soc. 109, 3258 (1987); M. N. Paddon-Row et al., J. Phys. Chem. 92, 6958 (1988); H. Oevering, J. W. Verhoeven, M. N. Paddon-Row, J. M. Warman, Tetrahedron 45, 4751 (1989); J. M. Warman et al., J. Phys. Chern. 95, 1979 (1991); J. Kroon, J. W. Verhoeven, M. N. Paddon-Row, A. M. Oliver, Angew. Chem. Int. Ed. Engl. 30, 1358 (1991); J. Kroon et al., J. Phys. Chem. 97, 5065 (1993).
-
(1991)
Angew. Chem. Int. Ed. Engl.
, vol.30
, pp. 1358
-
-
Kroon, J.1
Verhoeven, J.W.2
Paddon-Row, M.N.3
Oliver, A.M.4
-
21
-
-
18644376896
-
-
N. S. Hush et al., Chem. Phys. Lett. 117, 8(1985); H. Oevering et al., J. Am. Chem. Soc. 109, 3258 (1987); M. N. Paddon-Row et al., J. Phys. Chem. 92, 6958 (1988); H. Oevering, J. W. Verhoeven, M. N. Paddon-Row, J. M. Warman, Tetrahedron 45, 4751 (1989); J. M. Warman et al., J. Phys. Chern. 95, 1979 (1991); J. Kroon, J. W. Verhoeven, M. N. Paddon-Row, A. M. Oliver, Angew. Chem. Int. Ed. Engl. 30, 1358 (1991); J. Kroon et al., J. Phys. Chem. 97, 5065 (1993).
-
(1993)
J. Phys. Chem.
, vol.97
, pp. 5065
-
-
Kroon, J.1
-
22
-
-
0027851751
-
-
S. F. Nelsen, H. Chang, J. J. Wolff, J. Adamus, J. Am. Chem. Soc. 115, 12276 (1993).
-
(1993)
J. Am. Chem. Soc.
, vol.115
, pp. 12276
-
-
Nelsen, S.F.1
Chang, H.2
Wolff, J.J.3
Adamus, J.4
-
24
-
-
0030759794
-
-
S. F. Nelsen, M. T. Ramm, J. J. Wolff, D. R. Powell, ibid. 119, 6863 (1997).
-
(1997)
J. Am. Chem. Soc.
, vol.119
, pp. 6863
-
-
Nelsen, S.F.1
Ramm, M.T.2
Wolff, J.J.3
Powell, D.R.4
-
30
-
-
1842365898
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note
-
-1 used here.
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-
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31
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1842405222
-
-
note
-
et far simpler than the case for nonadiabatic ET systems.
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-
-
-
33
-
-
0000842531
-
-
S. K. Doom and J. T. Hupp, J. Am. Chem. Soc. 111, 1142 (1989); A. B. Meyers, Chem. Rev. 96, 911 (1996).
-
(1996)
Chem. Rev.
, vol.96
, pp. 911
-
-
Meyers, A.B.1
-
34
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-
1842290795
-
-
note
-
2/λ provides an excellent approximation to ΔG* for our compounds.
-
-
-
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35
-
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1842369510
-
-
note
-
et,ad significantly.
-
-
-
-
36
-
-
1842333726
-
-
note
-
2 [equation 3b of (26)], which they note produces a contribution that is about 11% smaller with a virtually identical dependence on n; they also indicate in appendix 3 (26) that the true dependence may be even more complicated.
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-
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37
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0001752788
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I. R. Gould, R. H. Young, L. J. Mueller, A. C. Albricht, S. Farid, J. Am. Chem. Soc. 116, 8188 (1994).
-
(1994)
J. Am. Chem. Soc.
, vol.116
, pp. 8188
-
-
Gould, I.R.1
Young, R.H.2
Mueller, L.J.3
Albricht, A.C.4
Farid, S.5
-
38
-
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1842408820
-
-
note
-
et and ΔG°, it is usually stated that all three parameters were determined from the fit. This determination cannot be made for any of our data because of the strong interaction of these parameters.
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-
-
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39
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1842373695
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note
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We thank the National Science Foundation for partial financial support of this work through grant CHE-9417946 and R. Young, for extended discussions.
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