Os(III)(N2)Os(II) complexes at the localized-to-delocalized, mixed- valence transition

Journal of the American Chemical Society

Volumn 121, Issue 3, 1999, Pages 535-544

  Demadis, Konstantinos D ^a,b   El Samanody, El Sayed ^a   Coia, George M ^a,c   Meyer, Thomas J ^a  

^a University of North Carolina at Chapel Hill   (United States)

^b NALCO COMPANY   (United States)

^c CALIFORNIA INSTITUTE OF TECHNOLOGY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

METAL COMPLEX; NITROGEN; OSMIUM; OSMIUM COMPLEX; SOLVENT; UNCLASSIFIED DRUG;

ARTICLE; CIS TRANS ISOMERISM; COMPLEX FORMATION; CRYSTAL STRUCTURE; ELECTRON TRANSPORT; ORIENTATION; OXIDATION;

EID: 0033608114     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja982802o     Document Type: Article

References (108)

1. Richardson, D. E.; Sen, J. P.; Buhr, J. D.; Taube, H. Inorg. Chem. 1982, 21, 3136.
2. Magnuson, R. H.; Taube, H. J. Am. Chem. Soc. 1972, 94, 7213.
3. Che, C-M.; Lam, H.-W.; Tong, W.-F.; Lai, T.-R; Lau, T.-C. J. Chem. Soc. Chem. Commun. 1989, 1883.
4. Lam, H.-W.; Che. C-M.; Wong, K.-Y. J. Chem. Soc., Dalton Trans. 1992, 1411.
5. Williams, D. S.; Coia, G. M.; Meyer, T. J. Inorg. Chem. 1995, 34, 586.
6. Coia, G. M. Ph.D. Dissertation, The University of North Carolina, Chapel Hill, 1996.
7. Coia, G. M.; Demadis, K. D.; Meyer, T. J. Manuscript in preparation.
8. Demadis, K. D.; Meyer, T. J.; White, P. S. Inorg. Chem. 1997, 36, 5678.
9. Demadis, K. D.; El-Samanody, E.-S.; Meyer, T. J.; White, P. S. Inorg. Chem. 1998, 37, 838.
10. Demadis, K. D.; Meyer, T. J.; White, P. S. Inorg. Chem. 1998, 37, 3610.
11. (a) Crevier, T. J.; Mayer, J. M. J. Am. Chem. Soc. 1998, 120, 5595.
12. (b) Crevier, T. J.; Mayer, J. M. Angew. Chem., Int. Ed. Engl. 1998, 37, 1891.
13. Huckel, W.; Bretschneider, H. Ber. Chem. 1937, 9, 2024.
14. Byers, P. K.; Canty, A. J.; Honeyman, R. T. J. Organomet. Chem. 1990, 385, 421.
15. Johnson, C. K. ORTEP: A Fortran Thermal Ellipsoid Plot Program: Technical Report ORNL-5138: Oak Ridge National Laboratory: Oak Ridge, TN, 1976.
16. Gabe, E. J.; Le Page, Y.; Charland, J.-P.; Lee, F. L.; White, P. S. J. Appl. Crystallogr. 1989, 22, 384.
17. International Tables for X-ray Crystallography: Kynoch Press: Birmigham, U.K., 1974; Vol. IV.
18. Ware, D. C.; Taube, H. Inorg. Chem. 1991, 30, 4605.
19. Mizobe, Y.; Yokobayashi, Y.; Oshita, H.; Takahashi, T.; Hidai, M. Organometallics 1994, 13, 3764.
20. Fryzuk, M. D.; Haddad, T. S.; Mylvaganam, M.; McConville, D. H.; Retting, S. J. J. Am. Chem. Soc. 1993, 115, 2782
21. Cohen, J. D.; Mylvaganam, M.; Fryzuk, M. D.; Loehr, T. M. J. Am. Chem. Soc. 1994, 116, 9529
22. Schrock, R. R.; Wesolek, M.; Liu, A. H.; Wallace, K. C.; Dewan, J. C. Inorg. Chem. 1988, 27, 2050.
23. O'Donoghue, M. B.; Zanetti, N. C.; Davis, W. M.; Schrock, R. R. J. Am. Chem. Soc. 1997, 119, 2753.
24. Dilworth, J. R.; Henderson, R. A.; Hills, A.; Hughes, D. L.; Macdonald, C; Stephens, A. N.; Walton, D. R. M. J. Chem. Soc., Dalton Trans. 1990, 1077.
25. Wilkinson, P. G.; Houk, N. B. J. Chem. Phys. 1956, 24, 528.
26. (a) Pelikán, R.; Boèa, R. Coord. Chem. Rev. 1984, 55, 55.
27. (b) Henderson, R. A. Trans. Met. Chem. 1990, 15, 330.
28. (c) Leigh, G. J. Acc. Chem. Res. 1992, 25, 177.
29. III-Cl bond lengths: (a) Bright, D.; Ibers, J. A. Inorg. Chem. 1969, 8, 1078. (b) Aslanov, L.; Mason, R.; Wheeler, A. G.; Whimp, P. O. J. Chem. Soc. Chem. Commun. 1979, 30. (c) Champness, N. R.; Levason. W.; Mould, R. A. S.; Pletcher, D.; Webster, M. J. Chem. Soc., Dalton Trans. 1991, 2777. (d) Champness, N. R.; Levason, W.; Pletcher, D.; Spicer, M. D.; Webster, M. J. Chem. Soc., Dalton Trans. 1992, 2201.
30. III-Cl bond lengths: (a) Bright, D.; Ibers, J. A. Inorg. Chem. 1969, 8, 1078. (b) Aslanov, L.; Mason, R.; Wheeler, A. G.; Whimp, P. O. J. Chem. Soc. Chem. Commun. 1979, 30. (c) Champness, N. R.; Levason. W.; Mould, R. A. S.; Pletcher, D.; Webster, M. J. Chem. Soc., Dalton Trans. 1991, 2777. (d) Champness, N. R.; Levason, W.; Pletcher, D.; Spicer, M. D.; Webster, M. J. Chem. Soc., Dalton Trans. 1992, 2201.
31. III-Cl bond lengths: (a) Bright, D.; Ibers, J. A. Inorg. Chem. 1969, 8, 1078. (b) Aslanov, L.; Mason, R.; Wheeler, A. G.; Whimp, P. O. J. Chem. Soc. Chem. Commun. 1979, 30. (c) Champness, N. R.; Levason. W.; Mould, R. A. S.; Pletcher, D.; Webster, M. J. Chem. Soc., Dalton Trans. 1991, 2777. (d) Champness, N. R.; Levason, W.; Pletcher, D.; Spicer, M. D.; Webster, M. J. Chem. Soc., Dalton Trans. 1992, 2201.
32. III-Cl bond lengths: (a) Bright, D.; Ibers, J. A. Inorg. Chem. 1969, 8, 1078. (b) Aslanov, L.; Mason, R.; Wheeler, A. G.; Whimp, P. O. J. Chem. Soc. Chem. Commun. 1979, 30. (c) Champness, N. R.; Levason. W.; Mould, R. A. S.; Pletcher, D.; Webster, M. J. Chem. Soc., Dalton Trans. 1991, 2777. (d) Champness, N. R.; Levason, W.; Pletcher, D.; Spicer, M. D.; Webster, M. J. Chem. Soc., Dalton Trans. 1992, 2201.
33. II-Cl bond lengths: (a) Chakravarty, A. R.; Cotton, F. A.; Schwotzer, W. Inorg. Chim. Acta 1984, 84, 179. (b) Cotton, F. A.; Diebold, M. P.; Matusz, M. Polyhedron 1987, 6, 1131. (c) Robinson, P. D.; Ali, I. A.; Hinckley, C. C. Acta Crystallogr. 1991, C47, 651. (d) Levason, W.; Champness, N. R.; Webster, M. Acta Crystallogr. 1993, C49, 1884.
34. II-Cl bond lengths: (a) Chakravarty, A. R.; Cotton, F. A.; Schwotzer, W. Inorg. Chim. Acta 1984, 84, 179. (b) Cotton, F. A.; Diebold, M. P.; Matusz, M. Polyhedron 1987, 6, 1131. (c) Robinson, P. D.; Ali, I. A.; Hinckley, C. C. Acta Crystallogr. 1991, C47, 651. (d) Levason, W.; Champness, N. R.; Webster, M. Acta Crystallogr. 1993, C49, 1884.
35. II-Cl bond lengths: (a) Chakravarty, A. R.; Cotton, F. A.; Schwotzer, W. Inorg. Chim. Acta 1984, 84, 179. (b) Cotton, F. A.; Diebold, M. P.; Matusz, M. Polyhedron 1987, 6, 1131. (c) Robinson, P. D.; Ali, I. A.; Hinckley, C. C. Acta Crystallogr. 1991, C47, 651. (d) Levason, W.; Champness, N. R.; Webster, M. Acta Crystallogr. 1993, C49, 1884.
36. II-Cl bond lengths: (a) Chakravarty, A. R.; Cotton, F. A.; Schwotzer, W. Inorg. Chim. Acta 1984, 84, 179. (b) Cotton, F. A.; Diebold, M. P.; Matusz, M. Polyhedron 1987, 6, 1131. (c) Robinson, P. D.; Ali, I. A.; Hinckley, C. C. Acta Crystallogr. 1991, C47, 651. (d) Levason, W.; Champness, N. R.; Webster, M. Acta Crystallogr. 1993, C49, 1884.
37. (a) Dilworth, J. R.; Richards, R. L. In Comprehensive Organometallic Chemistry; Wilkinson, G., Stone, F. G. A., Abel, E. W., Eds.; Pergamon Press: Oxford, 1982; Vol. 8, p 1073, and references therein.
38. (b) George, T. A. In Homogeneous Catalysis with Metal Phosphine Complexes; Pingolet, L. H., Ed.; Plenum Press: New York, 1983; p 405.
39. (c) Chatt, J.; Dilworth, J. R.; Richards, R. L. Chem. Rev. 1978, 78, 589.
40. (a) Beck, J.; Schweda, E.; Strähle, J. Z. Naturforsch. 1985, B40, 1073.
41. (b) Bardwell, D. A.; Cargill Thompson, M. W.; McCleverty, J. C.; Ward, M. D. J. Chem. Soc., Dalton Trans. 1996, 873.
42. (c) Constable, E. C. Metals and Ligand Reactivity; VCH Publishers: New York, 1996, and references therein.
43. Demadis, K. D.; El-Samanody, E.-S.; Meyer, T. J.; White, P. S. Submitted for publication.
44. Goodman, B. A.; Raynor, J. B. Adv. Inorg. Chem. Radiochem. 1970, 13, 135.
45. (a) Richter, M. M.; Brewer, K. J. Inorg. Chim. Acta 1991, 180, 125.
46. (b) Johnson, S. R.; Westmoreland, D. T.; Caspar, J. V.; Barqawi, K. R.; Meyer, T. J. Inorg. Chem. 1988, 27, 3195.
47. (c) Creutz, C; Chou, M.; Netzel, T. L.; Okamura, M.; Sutin, N. J. Am. Chem. Soc. 1980,102, 1309.
48. (d) Pankuch, B. J.; Lacky, D. E.; Crosby, G. A. J. Phys. Chem. 1980, 84, 2061.
49. (e) Lacky, D. E.; Pankuch, B. J.; Crosby, G. A. J. Phys. Chem. 1980, 84, 2068.
50. (f) Kober, E. M.; Meyer, T. J. Inorg. Chem. 1982, 21, 3967.
51. (g) Kober, E. M.; Caspar, J. V.; Sullivan, B. P.; Meyer, T. J. Inorg. Chem. 1988, 27, 4587.
52. (a) Llobet, A.; Hodgson, D. J.; Meyer, T. J. Inorg. Chem. 1990, 29, 3760.
53. (b) Llobet, A.; Doppélt, P.; Meyer, T. J. Inorg. Chem. 1988, 27, 514.
54. Kober, E. M.; Marshall, J. L.; Dressick, W. J.; Sullivan, B. P.; Caspar, J. V.; Meyer, T. J. Inorg. Chem. 1985, 24, 2755.
55. (a) Roffia, S.; Ciano, M. J. Electroanal. Chem. 1979, 100, 809.
56. (b) Sullivan, B. P.; Caspar, J. V.; Johnson, S. R.; Meyer, T. J. Organometallics 1984, 3, 1241.
57. (c) Root, M. J.; Sullivan, B. P.; Meyer, T. J.; Deutsch, E. Inorg. Chem. 1985, 24, 2731.
58. (a) Sen, J.; Taube, H. Acta Chem. Scand. 1979, A33, 125.
59. (b) Taube, H. J. Pure. Appl. Chem. 1979, 51, 901.
60. (c) Creutz, C.; Chou, M. H. Inorg. Chem. 1987, 26, 2995.
61. (d) Dubicki, L.; Ferguson, J.; Krautz, E. R.; Lay, P. A.; Maeder, M.; Taube, H. J. Phys. Chem. 1984, 88, 3940.
62. (e) Aràneo, A.; Mercati, G.; Morazzoni, F.; Napoletano, T. Inorg. Chem. 1977, 16, 1196.
63. (a) Henderson, R. A.; Leigh, G. J.; Pickett, C. J. Adv. Inorg. Chem. Radiochem. 1983, 27, 197.
64. (b) Hidai, M.; Mizobe, Y. Chem. Rev. 1995, 95, 1115.
65. (c) Bee, M. W.; Kettle, S. F. A.; Powell, D. B. Spectrochim. Acta 1974, 30A, 1637.
66. Bee, M. W.; Kettle, S. F. A.; Powell, D. B. Spectrochim. Acta 1975, 31A. 89
67. (a) Demadis, K. D.; Neyhart, G. A.; Kober, E. M.; Meyer, T. J. J. Am. Chem. Soc. 1998,120, 7121.
68. (b) Demadis, K. D.; Neyhart, G. A.; Kober, E. M.; Meyer, T. J.; White, P. S. Manuscript in preparation.
69. Kober, E. M. Ph.D. Dissertation, The University of North Carolina, Chapel Hill, 1982.
70. Kober, E. M.; Meyer, T. J. Inorg. Chem. 1983, 22, 1614.
71. Neyhart, G. A.; Timpson, C. J.; Bates, W. D.; Meyer, T. J. J. Am. Chem. Soc. 1996, 118, 3730.
72. Chen, P.; Meyer, T. J. Chem. Rev. 1998, 98, 1439.
73. (a) Callahan, R. W.; Meyer, T. J. Chem. Phys. Lett. 1976, 39, 82.
74. (b) Callahan, R. W.; Keene, F. R.; Meyer, T. J.; Salmon, D. J. J. Am. Chem. Soc. 1977, 99, 1064.
75. (a) Gress, M. E.; Creutz, C; Quicksall, C. O. Inorg. Chem. 1981, 20, 1522.
76. (b) Creutz, C; Chou, M. H. Inorg. Chem. 1981, 20, 1522.
77. (c) Wishart, J. F.; Bino, A.; Taube, H. Inorg. Chem. 1986, 25, 3318.
78. (a) Marcus, R. A. In Tunneling in Biological Systems; Chance, B., DeVault, D. C., Frauenfelder, H., Marcus, R. A., Schrieffer, J. R., Sutin, N., Eds.; Academic Press: New York, 1979; p 109.
79. (b) Marcus, R. A. J. Chem. Phys. 1956, 24, 979.
80. (c) Marcus, R. A. J. Chem. Phys. 1956, 24, 966.
81. (a) Dogonadze, R. R.; Kalman, E.; Kornyshev, A. A.; Ulstrup, J., Eds. The Chemical Physics of Solvation, Part. A; Elsevier Science Publishers B.V.: Amsterdam, 1985.
82. (b) Ulstrup, J. Charge-Transfer processes in Condensed Media. Lecture Notes in Chemistry; Springer-Verlag: New York, 1979; Vol. 10.
83. (c) Böttcher, C. J. F. Theoryof Electric Polarization; Elsevier Publishing Co.; New York, 1952.
84. (d) Fröhlich, H. Theory of Dielectrics: Oxford University Press: Oxford, 1949.
85. (e) Cole, R. H. In Molecular Liquids-Dynamics and Interactions; Barnes, A. J., et al., Eds.; D. Reidel Publishing Co.: New York, 1984; p 59.
86. (a) Hush, N. S. Prog. Inorg. Chem. 1967, 8, 391.
87. (b) Hush, N. S. Electrochim. Acta 1968,13, 1005.
88. (c) Creutz, C. Prog. Inorg. Chem. 1983, 30, 1.
89. Reimers, J. R.; Hush, N. S. Inorg. Chem. 1990, 29, 3686.
90. Hupp. J. T.; Dong, Y.; Blackburn. R. L.; Lu, H. J. Phys. Chem. 1993, 97, 3278.
91. (a) Omberg, K. M.; Schoonover, J. R.; Treadway, J. A.; Leasure, R. M.; Dyer, R. B.; Meyer, T. J. J. Am. Chem. Soc. 1997, 119, 7013.
92. (b) Mallick, P. K.; Danzer, G. D.; Strammen, D. P.; Kincaid, J. R. J. Phys. Chem. 1988, 92, 5628.
93. (c) Strommen. D. P.; Mallick, P. K.; Danzer, G. D.; Lumpkin, R. S.; Kincaid, J. R. J. Phys. Chem. 1990, 94, 1357.
94. (a) Hush, N. S. In Mixed-Valence Compounds: Brown. D. B., Ed.; Reidel Publishing Company: Dordrecht. 1980; p 151.
95. (b) Cribb. P. H.; Nordholm, S.; Hush. N. S. in Tunneling in Biological Systems: Chance, B., DeVault, D. C., Frauenfelder, H., Marcus, R. A., Schrieffer, J. R., Sutin, N., Eds.; Academic Press: New York. 1979; p 139.
96. (a) Marcus, R. A. Annu. Rev. Phys. Chem. 1966, 15, 155.
97. (b) Marcus, R. A.; Sutin. N. Biophy. Biochim. Acta 1985, 811, 5.
98. (c) Sutin, N. Prog. Inorg. Chem. 1983, 30, 411.
99. (d) Newton, M. D.; Sutin, N. Annu. Rev. Phys. Chem. 1984, 35, 437.
100. (e) Sutin. N. Acc. Chem. Res. 1982, 15, 275.
101. (f) Marcus, R. A. Rev. Mod. Phys. 1993, 65, 599.
102. (g) Hush, N. Coord. Chem. Rev. 1985, 64, 135.
103. (h) Barbara, P. F.; Meyer, T. J.; Ratner, M. A. J. Phys. Chem. 1996, 100, 13148.
104. -1, for 4, which is also too slow to be consistent with the time scale marker. This assignment is also consistent with the energy relationships in Figure 6 if bands II and III are assigned as the dπ → dπ transitions.
105. 56
106. Demadis, K. D., Meyer, T. J.; White, P. S. Unpublished results.
107. (a) Ito, T.; Hamaguchi, T.; Nagino, H.: Yamaguchi, T.; Washington. J.: Kubiak. C. P. Science 1997, 277, 660.
108. (b) Kubiak, C. P. Personal communication.