메뉴 건너뛰기




Volumn 6, Issue 4, 2000, Pages 581-588

"Almost Delocalized" Intervalence Compounds

Author keywords

Electron transfer; Hush theory; Intervalence compounds; Radical ions

Indexed keywords

COORDINATION COMPOUND; METAL COMPLEX;

EID: 0034681578     PISSN: 09476539     EISSN: None     Source Type: Journal    
DOI: 10.1002/(sici)1521-3765(20000218)6:4<581::aid-chem581>3.0.co;2-e     Document Type: Article
Times cited : (302)

References (40)
  • 3
    • 25544476512 scopus 로고
    • b) N. S. Hush, Electrochim. Acta 1968, 13, 1005-1023; N. S. Hush, Coord. Chem. Rev. 1985, 64, 135-157.
    • (1968) Electrochim. Acta , vol.13 , pp. 1005-1023
    • Hush, N.S.1
  • 4
    • 33749130604 scopus 로고
    • b) N. S. Hush, Electrochim. Acta 1968, 13, 1005-1023; N. S. Hush, Coord. Chem. Rev. 1985, 64, 135-157.
    • (1985) Coord. Chem. Rev. , vol.64 , pp. 135-157
    • Hush, N.S.1
  • 5
    • 0022004980 scopus 로고
    • For reviews of Marcus theory see : a) R. A. Marcus, N. Sutin, Biochim. Biophys. Acta 1985, 811, 265-322; b) N. Sutin, Prog, Inorg. Chem. 1983, 30, 441-99;
    • (1985) Biochim. Biophys. Acta , vol.811 , pp. 265-322
    • Marcus, R.A.1    Sutin, N.2
  • 6
    • 0022004980 scopus 로고
    • For reviews of Marcus theory see : a) R. A. Marcus, N. Sutin, Biochim. Biophys. Acta 1985, 811, 265-322; b) N. Sutin, Prog, Inorg. Chem. 1983, 30, 441-99;
    • (1983) Prog, Inorg. Chem. , vol.30 , pp. 441-499
    • Sutin, N.1
  • 10
    • 85087228203 scopus 로고    scopus 로고
    • note
    • max.
  • 26
    • 0000552779 scopus 로고    scopus 로고
    • a) C. Lambert, G. Nöll, Angew. Chem. 1998, 110, 2239; Angew. Chem. Int. Ed. 1998, 37, 2107;
    • (1998) Angew. Chem. , vol.110 , pp. 2239
    • Lambert, C.1    Nöll, G.2
  • 27
    • 0037931820 scopus 로고    scopus 로고
    • a) C. Lambert, G. Nöll, Angew. Chem. 1998, 110, 2239; Angew. Chem. Int. Ed. 1998, 37, 2107;
    • (1998) Angew. Chem. Int. Ed. , vol.37 , pp. 2107
  • 30
    • 0346297946 scopus 로고    scopus 로고
    • Lambert and Nöll include both the F expression and the cutoff in ref. [18]
    • Lambert and Nöll include both the F expression and the cutoff in ref. [18].
  • 31
    • 0348188726 scopus 로고    scopus 로고
    • note
    • CV rises {average 0.8, range 0.56-1.06), so the effective d would have to increase as F decreases if allowing d to vary is to improve fit.
  • 33
    • 85087228721 scopus 로고    scopus 로고
    • note
    • [19, 22a] but the changes in band shape are quite small compared to cutoff effects near the II/III borderline that are discussed here.
  • 38
    • 0348188720 scopus 로고    scopus 로고
    • note
    • 3 bands occuring in the same region as the IT band. This would make these compounds (at least) three-state systems, to which the two-state Hush model would not apply quantitatively.
  • 39
    • 85087227563 scopus 로고    scopus 로고
    • note
    • [17]


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.