Comparison of V values for some nitrogen- and metal-centered π-bridged mixed-valence compounds

Journal of the American Chemical Society

Volumn 120, Issue 2, 1998, Pages 298-304

  Nelsen, Stephen F ^a   Tran, Hieu Q ^a   Nagy, Mark A ^a  

^a UNIVERSITY OF WISCONSIN MADISON   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CATION; METAL; NITROGEN; RADICAL;

ARTICLE; CONTROLLED STUDY; ELECTRON TRANSPORT; NONHUMAN;

EID: 0032554106     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja972919x     Document Type: Article

References (29)

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10. op if the diabatic energy surfaces are not parabolas.
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13. 6 but direct overlap should be negligible for the cases considered here.
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16. (b) Nelsen, S. F.; Tran, H. Q.; Ismagilov, R. F.; Chen, L.-J.; Powell, D. R. Submitted for publication.
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19. op= 47.2 kcal/mol) in MeCN at RT (not correct, from 13d and Table 1): Cauquis, G.; Delhomme, H.; Jene, D. Tetrahedron Lett. 1972, 1965.
20. op= 47.2 kcal/mol) in MeCN at RT (not correct, from 13d and Table 1): Cauquis, G.; Delhomme, H.; Jene, D. Tetrahedron Lett. 1972, 1965.
21. op= 47.2 kcal/mol) in MeCN at RT (not correct, from 13d and Table 1): Cauquis, G.; Delhomme, H.; Jene, D. Tetrahedron Lett. 1972, 1965.
22. op= 47.2 kcal/mol) in MeCN at RT (not correct, from 13d and Table 1): Cauquis, G.; Delhomme, H.; Jene, D. Tetrahedron Lett. 1972, 1965.
23. op= 47.2 kcal/mol) in MeCN at RT (not correct, from 13d and Table 1): Cauquis, G.; Delhomme, H.; Jene, D. Tetrahedron Lett. 1972, 1965.
24. Brouwer, A. M.; Wiering, P. G.; Zwier, J. M.; Langkilde, F. W.; Wilbrandt, R. Acta Chem. Scand. 1997, 57, 217.
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26. (a) Closs, G. L.; Miller, J. R. Science 1988, 240,440.
27. 2 when V is small. We shall retain this factor of 2 to enable easier comparison with literature values.
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