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Volumn 121, Issue 40, 1999, Pages 9343-9351

Transannular effects in dicobalta-superphane complexes on the mixed- valence class II/class III interface: Distinguishing between spin and charge delocalization by electrochemistry, spectroscopy, and ab initio calculations

Author keywords

[No Author keywords available]

Indexed keywords

COBALT DERIVATIVE; CYCLOALKANE DERIVATIVE;

EID: 0033552243     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja9914792     Document Type: Article
Times cited : (62)

References (75)
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    • Cyclophanes I and II
    • Springer-Verlag: Berlin
    • (b) Voegtle, F., Ed. Cyclophanes I and II. Topics in Current Chemistry; Springer-Verlag: Berlin, 1983; Vols. 113 and 115.
    • (1983) Topics in Current Chemistry , vol.113-115
    • Voegtle, F.1
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    • (d) Newton, M. D. Chem. Rev. 1991, 91, 767.
    • (1991) Chem. Rev. , vol.91 , pp. 767
  • 29
    • 0345060758 scopus 로고    scopus 로고
    • note
    • 6].
  • 42
    • 0345492303 scopus 로고    scopus 로고
    • note
    • s for four different solvent systems (see the figure in the Supporting Information). Compare slopes for class II systems in, e.g., ref 32.
  • 44
    • 0038023839 scopus 로고
    • Lippard, S. J., Ed.; John Wiley and Sons: New York
    • See: Creutz, C. In Progress in Inorganic Chemistry; Lippard, S. J., Ed.; John Wiley and Sons: New York, 1983; Vol. 30, p 1.
    • (1983) Progress in Inorganic Chemistry , vol.30 , pp. 1
    • Creutz, C.1
  • 47
  • 52
    • 0022283870 scopus 로고
    • Melson, G. A., Figgis, B. N., Eds.; Marcel Dekker, Inc.: New York
    • (b) Van Dam, H.; Oskam, A. In Transition Metal Chemistry; Melson, G. A., Figgis, B. N., Eds.; Marcel Dekker, Inc.: New York, 1985; Vol 9, p 125.
    • (1985) Transition Metal Chemistry , vol.9 , pp. 125
    • Van Dam, H.1    Oskam, A.2
  • 58
    • 26344442313 scopus 로고
    • (g) Boehm, M. C.; Gleiter, R. Chem. Phys. Lett. 1986, 123, 87; Theor. Chim. Acta 1980, 57, 315.
    • (1980) Theor. Chim. Acta , vol.57 , pp. 315
  • 67
    • 0345492297 scopus 로고    scopus 로고
    • note
    • l(Koopmans) - Δ(SCF(deloc)) = 12.76 - 8.60 = 4.16 eV.
  • 72
    • 0345060744 scopus 로고    scopus 로고
    • note
    • + under these conditions still had linewidths so great that hyperfine splittings were not visible.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.