Charge localization in a dihydrazine analogue of tetramethyl-p-phenylenediamine radical cation

Journal of the American Chemical Society

Volumn 118, Issue 26, 1996, Pages 6313-6314

  Nelsen, Stephen F ^a   Ismagilov, Rustem F ^a   Powell, Douglas R ^a  

^a UNIVERSITY OF WISCONSIN MADISON   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

HYDRAZINE DERIVATIVE; RADICAL;

ARTICLE; DRUG STRUCTURE; ELECTRON SPIN RESONANCE; MOLECULAR DYNAMICS;

EID: 0030037717     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja960500l     Document Type: Article

References (21)

1. For the early history of radical ion studies, see: Roth, H. D. Tetrahedron 1986, 42, 5097.
2. (a) Bruce, C. R.; Norberg, R. E.; Weissman. S. J. Chem. Phys. 1956, 24, 473.
3. (b) Grampp, G.; Jaenicke, W. Ber. Bunsen-Ges. Phys. Chem. 1984, 88, 325.
4. (C) Grampp, G.; Jaenicke, W. Ibid. 1984, 88, 335.
5. (d) Grampp, G.; Jaenicke, W. Ibid. 1991, 95, 904.
6. For reviews of electron transfer theory, see: (a) Sutin, N. Prog. Inorg. Chem. 1983, 30, 441. (b) Marcus, R. A.; Sutin, N. Biochim. Biophys. Acta 1985, 811, 265.
7. For reviews of electron transfer theory, see: (a) Sutin, N. Prog. Inorg. Chem. 1983, 30, 441. (b) Marcus, R. A.; Sutin, N. Biochim. Biophys. Acta 1985, 811, 265.
8. Robin, M.; Day, P. Adv. Inorg. Radiochem. 1967, 10, 247.
9. max = 2 V for Class III complexes, see: (i) Woitelier, S.; Launay, J. P.; Spangler, C. W. Inorg. Chem. 1989, 28, 758. Dong, Y.; Hupp, J. T. Ibid. 1992, 31, 3170. (iii) Reference 10.
10. max = 2 V for Class III complexes, see: (i) Woitelier, S.; Launay, J. P.; Spangler, C. W. Inorg. Chem. 1989, 28, 758. Dong, Y.; Hupp, J. T. Ibid. 1992, 31, 3170. (iii) Reference 10.
11. max = 2 V for Class III complexes, see: (i) Woitelier, S.; Launay, J. P.; Spangler, C. W. Inorg. Chem. 1989, 28, 758. Dong, Y.; Hupp, J. T. Ibid. 1992, 31, 3170. (iii) Reference 10.
12. max = 2 V for Class III complexes, see: (i) Woitelier, S.; Launay, J. P.; Spangler, C. W. Inorg. Chem. 1989, 28, 758. Dong, Y.; Hupp, J. T. Ibid. 1992, 31, 3170. (iii) Reference 10.
13. For a review on the effects of reorganization energy of amino nitrogen compounds upon ET rates, see: Nelsen, S. F. Advances in Electron Transfer Chemistry; Mariano, P. S., Ed.; JAI: Greenwich, CT, 1993; Vol. 3, p 167.
14. Polynitrobenzene radical anions including that from p-dinitrobenzene provided early examples of ion pairing localizing the spin (and charge) on one unit through the study of ESR splitting constants. For a review of this work, see p 200 of the following: Hudson, H.; Luckhurst, G. R. Chem. Rev. 1969, 69, 191.
15. (a) Nelsen, S. F.; Landis, R. T., II J. Am. Chem. Soc. 1974, 96, 1788.
16. (b) Nelsen, S. F.; Chen, L.-J.; Petillo, P. A.; Evans, D. H.; Neugebauer, F. A. J. Am. Chem. Soc: 1993, 115, 10611.
17. Nelsen, S. F.; Kessel, C. R.; Brien, D. J. J. Am. Chem. Soc. 1980, 102, 702.
18. Nelsen, S. F.; Chang, H.; Wolff, J. J.; Adamus, J. J. Am. Chem. Soc. 1993, 115, 12276.
19. Nelsen, S. F.; Adamus, J.; Wolff, J. J. J. Am. Chem. Soc. 1994, 116, 1589.
20. Nelsen, S. F.; Yunta, M. J. R. J. Phys. Org. Chem. 1994, 7, 55.
21. + is clearly localized.