Electron transfer on the infrared vibrational time scale in the mixed valence state of 1,4-pyrazine- and 4,4'-bipyridine-bridged ruthenium cluster complexes

Journal of the American Chemical Society

Volumn 121, Issue 19, 1999, Pages 4625-4632

  Ito, Tasuku ^c   Hamaguchi, Tomohiko ^c   Nagino, Haruko ^c   Yamaguchi, Tadashi ^c   Kido, Hiroaki ^a   Zavarine, Igor S ^d   Richmond, Todd ^d   Washington, John ^d   Kubiak, Clifford P ^b,d  

^a NIHON UNIVERSITY   (Japan)

^b UNIVERSITY OF CALIFORNIA   (United States)

^c TOHOKU UNIVERSITY   (Japan)

^d PURDUE UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

RUTHENIUM COMPLEX;

ARTICLE; CHEMICAL REACTION KINETICS; DYNAMICS; ELECTRON TRANSPORT; INFRARED SPECTROSCOPY; POTENTIOMETRY; SURFACE CHARGE; VIBRATION;

EID: 0033583759     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja984000z     Document Type: Article

References (36)

1. Wood, K. A.; Strauss, H. L. J. Phys. Chem. 1990, 94, 5677.
2. Hsiao, J.-S.; Krueger, B. P.; Wagner, R. W.; Johnson, T. E.; Delaney, J. K.; Mauzerall, D. C.; Fleming, G. R.; Lindsey, J. S.; Bocian, D. F.; Donohoe, R. J. J. Am. Chem. Soc. 1996, 118, 11181.
3. Sutin, N. S. Prog. Inorg. Chem. 1983, 30, 441.
4. Ito, T.; Hamaguchi, T.; Nagino, H.; Yamaguchi, T.; Washington, J.; Kubiak, C. P. Science 1997, 277, 660.
5. Campagna, S.; Denti, G,; Serroni, S.; Ciano, M.; Balzani, V. Inorg. Chem. 1992, 31, 2982.
6. Kido, H.; Nagino, H.; Ito, T. Chem. Lett. 1996, 745.
7. 3, Z = 1. Details will be reported elsewhere.
8. Abe, M.; Sasaki, Y.; Yamada. Y.; Tsukahara, K.; Yano, S.; Yamaguchi, T.; Tominaga, M.; Taniguchi, I.; Ito, T. Inorg Chem. 1996, 35, 6724.
9. 1/2(+2/0) are systematically shifted toward positive potentials on going from electron-donating dmap in 1 (or 4) to unsubstituted pyridine for 2 (or 5) and then to electron-withdrawing cpy for 3 (or 6).
10. Richardson, D. E.; Taube, H. Coord. Chem. Rev. 1984, 60, 107.
11. Richardson, D. E.; Taube, H. Inorg. Chem. 1981, 20, 1278.
12. Sutton, J. E.; Taube, H. Inorg. Chem. 1981, 20, 3125.
13. de la Rosa, R., Chang, P. J.; Salaymeh, F.; Curtis, J. C. Inorg. Chem. 1985, 24, 4229.
14. Dong, Y.; Hupp, J. T. Inorg. Chem. 1992, 31, 3170.
15. Lacoste, M.; Rabaâ, G.; Astruc, D.; Ardoin, N.; Varret, G.; Saillard, J.-Y.; LeBeuze, A. J. Am. Chem. Soc. 1990, 112, 9548.
16. 1/2(0/-2) = -1.31 (L = dmap), -1.15 (L = py), -0.94 (L = cpy) V vs SSCE.
17. 3) ppm.
18. Baumann, J. A.; Wilson, S. T.; Salmon, D. J.; Hood, P. L.; Meyer, T. J. J. Am. Chem. Soc. 1979, 101, 2916.
19. Hush, N. S. Prog. Inorg. Chem. 1967, 8, 391.
20. Salaymeh, F.; Berhane, S.; Yusof, R.; de la Rosa, R.; Fung, E. Y.; Matamores, R.; Law, K. W.; Zheng, Q.; Kober, E. M.; Curtis, J. C. Inorg. Chem. 1993, 32, 3895.
21. AB for 2, therefore, may be slightly over-estimated and gives the maximum limit.
22. Robin, M. B.; Day, P. Adv. Inorg. Chem. Radiochem. 1967, 10, 247.
23. Turner, J. J.; Gordon, C. M.; Howdle, S. M. J. Phys. Chem 1995, 99, 17532.
24. Wood, K. A.; Strauss, H. L. Ber. Bunsen-Ges. Phys. Chem. 1989, 93, 615.
25. Strauss, H. L. J. Am. Chem. Soc. 1992, 114, 905.
26. MacPhail, R. A.; Strauss, H. L. J. Chem. Phys. 1985, 82, 1156.
27. Sandström, J. Dynamic NMR Spectroscopy; Academic Press: London, 1982.
28. Grevels, F.-W.; Jacke, J.; Klotzbücher, W. E.; Krüger, C.; Seevogel, K.; Tsay, Y. H. Angew. Chem., Int. Ed. Engl. 1987, 26, 885.
29. Grevels, F.-W.; Kerpen, K.; Klotzbücher, W. E.; McClung, R. E. D.; Russel, G.; Viotte, M.; Schaffner, K. J. Am. Chem. Soc. 1998, 120, 10423.
30. Wu, R.; Arap Koske, S. K.; White, R. P.; Anson, C. E.; Jayasooriya, U. A.; Cannon, R. D. J. Chem. Soc., Chem. Commun. 1994, 1657.
31. Callahan, R. W.; Keene, F. R.; Meyer, T. J.; Salmon, D. J. J. Am. Chem. Soc. 1977, 99, 1064.
32. Baumann, J. A.; Salmon, D. J.; Wilson, S. T.; Meyer, T. J.; Hatfield, W. E. Inorg. Chem., 1978, 17, 3342.
33. Hornung, F. M.; Baumann, F.; Kaim, W.; Olabe, J. A.; Slep, L. D.; Fiedler, J. Inorg. Chem., 1998, 37, 311-316.
34. Demadis, K. D.; Neyhart, G. A.; Kober, E. M.; Meyer, T. J. J. Am. Chem. Soc. 1998, 120, 7121-7122.
35. Zavarine, I. S.; Richmond,T. A.; Kubiak, C. P. J. Electroanal. Chem. Submitted for publication.
36. Wittrig, R. E.; Kubiak, C. P. J. Electroanal. Chem. 1995, 393, 75.