Charge-localized p-phenylenedihydrazine radical cations: ESR and optical studies of intramolecular electron transfer rates

Journal of the American Chemical Society

Volumn 119, Issue 42, 1997, Pages 10213-10222

  Nelsen, Stephen F ^a   Ismagilov, Rustem F ^a   Powell, Douglas R ^a  

^a UNIVERSITY OF WISCONSIN MADISON   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CATION; HYDRAZINE DERIVATIVE; PHENYLENEDIHYDRAZINE DERIVATIVE; RADICAL; UNCLASSIFIED DRUG;

ARTICLE; CALCULATION; CHEMICAL MODIFICATION; CRYSTAL STRUCTURE; ELECTRON SPIN RESONANCE; ELECTRON TRANSPORT; STEREOCHEMISTRY; THERMODYNAMICS;

EID: 0030664272     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja9720321     Document Type: Article

References (40)

1. Nelsen, S. F.; Ismagilov, R. F.; Powell, D. R. J. Am. Chem. Soc. 1996, 118, 6313.
2. Suzuki, H.; Nakamura, K.; Goto, R. Bull. Chem. Soc. Jpn. 1966, 39, 128.
3. Platt, K. L.; Setiabudi, F. J. Chem. Soc., Perkin Trans. 1 1992, 2005.
4. Creutz, C. Prog. Inorg. Chem. 1983, 30, 1.
5. Kreilick. R. W. NMR of Paramagnetic Molecules; La Mar, G. N. Horrocks, W. DeW., Jr; Holm, R. H., Eds.; Academic Press: New York, 1973; Chapter 15, p 595.
6. (a) Petillo, P. A.; De Felipppis, J.; Nelsen, S. F. J. Org. Chem. 1991, 56, 6496.
7. (b) Nelsen, S. F.; Petillo, P. A.; De Felipppis, J.; Wang, Y.; Chen, L.-J.; Yunta, M. J. R.; Neugebauer, F. J. Am. Chem. Soc. 1993, 115, 5608.
8. Gerson, F.; Gescheidt, G.; Nelsen, S. F.; Raquette, L. A.; Teasley, M. F.; Waykole, L. J. Am. Chem. Sac. 1989, 111, 5518.
9. Nelsen, S. F.; Wolff, J. J.; Chang, H.; Powell, D. R. J. Am. Chem. Soc. 1991, 113, 7882.
10. (a) Hirota, N.; Weissman, S. I. J. Am. Chem. Soc. 1964, 86, 2538.
11. (b) Dvolaitzky, M.; Chiarelli, R.; Rassat, A. Angew. Chem., Int. Ed. Engl. 1992, 31, 180.
12. The standard ET theory reviews remain: (a) Marcus, R. A.; Sutin, N. Biochim. Biophys. Acta 1985, 811, 265. (b) Sutin, N. Prog. Inorg. Chem. 1983, 30, 441.
13. The standard ET theory reviews remain: (a) Marcus, R. A.; Sutin, N. Biochim. Biophys. Acta 1985, 811, 265. (b) Sutin, N. Prog. Inorg. Chem. 1983, 30, 441.
14. (a) Hush, N. S. Prog. Inorg. Chem. 1967, 8, 391.
15. (b) Hush, N. S. Coord. Chem. Rev. 1985, 64, 135.
16. (a) Mulliken, R. S. J. Am. Chem. Soc. 1952, 64, 811.
17. (b) Mulliken, R. S.; Person, W. B. Molecular Complexes; Wiley: New York, 1969.
18. Creutz, C.; Newton, M. D.; Sutin, N. J. Photochem. Photobiol. A.: Chem. 1994, 52, 47.
19. (a) Jortner, J.; Ulstrup, J. J. Chem. Phys. 1975, 63, 4358.
20. (b) Jortner, J.; Bixon, M.-J. Chem. Phys. 1988, 88, 167.
21. (c) Cortes, J.; Heitele, H.; Jortner, J. J. Phys. Chem. 1994. 98, 2527.
22. Gould, I. R.; Noukakis, D.; Gomez-Jahn, L.; Young, R. H.; Goodman, J. L.; Farid, S. Chem. Phys. 1993, 176, 439.
23. (a) Nelsen, S. F.; Ramm, M. T.; Powell, D. R. J. Am. Chem. Soc. 1997, 119, 6863.
24. (b) Nelsen, S. F.; Trieber, D. A., II; Powell, D. R. J. Am. Chem. Soc. 1997, 119, 6873.
25. Brouwer, A. M.; Wiering, P. G.; Zwier, J. M.; Langkilde, F. W.; Wilbrandt, R. Acta Chem. Scand. 1997, 51, 217.
26. Winkler, J. R.; Netzel, T. L.; Creutz, C.; Sutin, N. J. Am. Chem. Soc. 1987, 109, 2381.
27. (a) Dunn, B. M. Int. J. Chem. Kinet. 1974, 6, 143.
28. (b) le Noble, W. J. Miller A. R.; Harmann, S. D. J. Org, Chem. 1977, 42, 338.
29. (c) Guthrie, J. P. Can. J. Chem. 1990, 68, 1643.
30. (d) Guthrie, J. P. J. Am. Chem. Soc. 1996, 118/12878, 12886.
31. Nelsen, S. F.; Frigo, T. B.; Kim, Y. J. Am. Chem. Soc. 1989, 111, 5387.
32. (a) Brunschwig, B. S.; Ehrenson, S.; Sutin, N. J. J. Phys. Chem. 1986, 90, 3657.
33. (b) Barbara, P. F; Meyer, T. J.; Ratner, M. A. J. Phys. Chem. 1996, 100, 13148.
34. x-ray of 4.32 Å, and the d values necessary to obtain such r values using the traditional expression are 3.08 and 3,22 Å, respectively.
35. (a) Nelsen, S. F.; Kim, Y.; Blackstock. S. C. J. Am. Chem. Soc. 1988, 111, 2049.
36. (b) Nelsen, S. F.; Wang, Y. J. Org. Chem. 1994, 59, 1655.
37. (a) Nelsen, S. F.; Adamus, J.; Wolff, J. J. J. Am. Chem. Soc. 1994, 116, 1589,
38. (b) Nelsen, S. F. J. Am. Chem. Soc. 1996, 118, 2047.
39. 24b
40. Nelsen, S. F.; Ismagilov, R. F.; Trieber, D. W. Submitted for publication.