Solvent-induced electron transfer and delocalization in mixed-valence complexes. Electrochemistry

Journal of the American Chemical Society

Volumn 118, Issue 15, 1996, Pages 3724-3729

  Neyhart, Gregory A ^a   Hupp, Joseph T ^a,b   Curtis, Jeff C ^a,c   Timpson, Cliff J ^a   Meyer, Thomas J ^a  

^a University of North Carolina at Chapel Hill   (United States)

^b NORTHWESTERN UNIVERSITY   (United States)

^c UNIVERSITY OF SAN FRANCISCO   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

RUTHENIUM COMPLEX;

ARTICLE; ELECTROCHEMISTRY; THERMODYNAMICS;

EID: 0029998286     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja953566+     Document Type: Article

References (82)

1. (a) Foster, R. Organic Change-Transfer Complexes; Academic Press: New York, 1969.
2. (b) Kober, E M.; Sullivan, B. P.; Meyer, T. J. Inorg. Chem. 1984, 23, 2098.
3. (c) Sullivan, B. P.; Curtis, J. C.; Kober, E M.; Meyer, T J. Nouv. J. Chim. 1980, 4, 643.
4. (d) Sullivan, B. P. J. Phys. Chem. 1989, 93, 24.
5. (e) Buncel, E.; Rajagopal, S. Acc. Chem. Res. 1990, 23, 226.
6. (f) Fung, E. Y.; Chua, A C. M.; Curtis, J. C. Inorg. Chem. 1988, 27, 1294.
7. (g) Brunschwig, B. S.; Ehrenson, S.; Sutin, N. S. J. Phys. Chem. 1987, 91, 4714.
8. (h) Marcus, R. A J. Phys. Chem. 1989, 93, 3078.
9. (i) Suppan, P. J. Photochem. Photobiol., A: Chemistry 1990, 50, 293
10. Creutz, C. Prog. Inorg. Chem. 1983, 30, 1.
11. (a) Kestner, N. R.; Logan, J., Jortner, J. J. Phys. Chem. 1974, 78, 2148.
12. (b) Jortner, J. J. Chem. Phys. 1976, 64, 4860.
13. (c) Newton, M. D.; Sutin, N. Annu. Rev. Phys. Chem. 1984, 35, 437.
14. (d) Ulstrup, J. Charge Transfer Processes in Condensed Media; Springer-Verlag: Berlin, 1979.
15. (e) Sutin, N. Prog. Inorg. Chem. 1983, 30, 441.
16. (f) McLendon, G. Acc. Chem. Res. 1988, 21, 160.
17. (a) Weaver, M. J. Chem. Rev. 1992, 92, 463.
18. (b) Weaver, M. J.; McManis, G. E., III Acc. Chem. Res. 1990, 23, 294.
19. (c) Maroncelli, M.; MacInnis, J.; Fleming, G. R. Science 1989, 243, 1674.
20. (d) Barbara, P. F.; Walker, G. C.; Smith, T. P. Science 1992, 256, 975.
21. (e) Zhang, H.; Murray, R. W. J. Am. Chem. Soc. 1991, 113, 5183.
22. (f) Bixon, M.; Jortner, J. Chem. Phys. 1993, 176, 467.
23. (a) McManis, G. E.; Gochev, A.; Nielson, R. M.; Weaver, M. J. J. Phys. Chem. 1989, 93, 7733
24. (b) Ulstrup, J. J. Phys. Chem. 1987, 91, 5153.
25. (c) Blackbourn, R. L.; Hupp, J. T. J. Phys. Chem. 1990, 94, 1788.
26. (d) Chang, J. P.; Fung, E. Y.; Curtis, J. C. Inorg. Chem. 1986, 25, 4233.
27. (e) Brunschwig, B. S.; Ehrenson, S.; Sutin, N. S. J. Phys. Chem. 1986, 90, 3657.
28. (f) Chou, M. H.; Creutz, C.; Sutin, N. Inorg. Chem. 1992, 31, 2318.
29. (a) Hupp, J. T.; Meyer, T. J. J. Phys. Chem. 1987, 91, 1001
30. (b) Powers, M. S.; Meyer, T. J. J. Am. Chem. Soc. 1980, 102, 1289.
31. (c) Callahan, R. W.; Brown, G. M.; Meyer, T. J. Inorg. Chem. 1975, 14, 1443.
32. (d) Hupp, J. T.; Neyhart, G. A.; Meyer, T. J.; Kober, E. M. J. Phys. Chem. 1992, 96, 10820.
33. (e) Lau, K. W.; Hu, A. M.-H.; Yen, M. H.-J.; Fung, E. Y.; Grzybicki, S.; Matamoros, R.; Curtis, J. C. Inorg. Chim. Acta. 1994, 226, 137.
34. (a) Marcus, R. A. J. Phys. Chem. 1965, 43, 679.
35. (b) Marcus, R. A. In Special Topics in Electrochemistry; Rock, P. A., Ed.; Elsevier: New York, 1977; p 161.
36. (c) Marcus, R. A. Rev. Mod. Phys. 1993, 65, 599.
37. (d) Hush, N. S. Trans. Faraday Soc. 1961, 57, 557.
38. (e) Hush, N. S. Prog. Inorg. Chem. 1967, 8, 391.
39. (f) Hush, N. S. Electrochim. Acta 1968, 13, 1005.
40. (g) Hush, N. S. Coord. Chem. Rev. 1985, 64, 135.
41. (a) Sahami, S.; Weaver, M. J. J. Electroanal. Chem. 1981, 122, 155, 171.
42. (b) Hupp, J. T.; Weaver, M. J. J. Phys. Chem. 1985, 89, 1601.
43. (a) Curtis, J. C.; Sullivan, B. P.; Meyer, T. J. Inorg. Chem. 1983, 22, 224.
44. (b) Curtis, J. C. Ph.D. Dissertation, University of North Carolina at Chapel Hill, 1980.
45. (a) Blackbourn, R. L.; Hupp, J. T. Inorg. Chem. 1989, 28, 3786.
46. (b) Mines, G. A.; Roberts, J. A.; Hupp, J. T Inorg. Chem. 1992, 31, 125.
47. (c) Creutz, C.; Chou, M. H. Inorg. Chem. 1987, 26, 2995.
48. (a) Hupp, J. T.; Neyhart, G. A.; Meyer, T. J. J. Am. Chem. Soc. 1986, 108, 5349.
49. (b) Hupp, J. T.; Kober, E. M.; Neyhart, G. A.; Meyer, T. J. In Mixed-Valency Systems: Applications in Chemistry, Physics and Biology; Prassides, K., Ed.; Kluwar Academic: Dordrecht, The Netherlands, 1991; p 51.
50. (a) Ennix, K. S.; McMahon, P. T.; de la Rosa, R.; Curtis, J. C. Inorg. Chem. 1987 26, 2660.
51. (b) Roberts, J. A.; Hupp, J. T. Inorg. Chem. 1992, 31, 157.
52. (c) Hupp, J. T.; Weydert, J. Inorg. Chem. 1987, 26, 2657.
53. (d) Curtis, J. C.; Blackbourn, R. L.; Ennix, K. S.; Hu, S.; Roberts, J. A.; Hupp, J. T. Inorg. Chem. 1989, 28, 3791.
54. (a) de la Rosa, R.; Chang, P. J.; Salaymeh, F.; Curtis, J. C. Inorg. Chem. 1985, 24, 4229.
55. (b) Dong, Y.; Hupp, J. T. Inorg. Chem. 1992, 31, 3170.
56. (c) Saleymeh, F.; Berhane, S.; Yusof, R., de la Rosa, R.; Fung, E. Y., Matamoros, R.; Lau, K. W ; Zheng, Q.; Kober, E. M.; Curtis, J. C. Inorg. Chem, 1993, 32, 3895.
57. Curtis, J. C.; Roberts, J. A.; Blackbourn, R. L.; Dong, Y.; Massum, M., Johnson, C. S.; Hupp, J. T. Inorg. Chem. 1991, 30, 3856
58. Calvert, J. M.; Meyer, T. J. Inorg. Chem. 1982, 29, 3978.
59. Kober, E. M.; Caspar, J. V.; Sullivan, B. P., Meyer, T. J. Inorg. Chem. 1988, 27, 4587.
60. Curtis, J. C. Unpublished results.
61. (a) Sahami, S , Weaver, M J J. Solution Chem. 1981, 10, 199.
62. (b) Diggle, J. W.; Parker, A. J. Electrochim. Acta 1973, 18, 975.
63. Neyhart, G. A. Ph D. Dissertation, University of North Carolina at Chapel Hill, 1988.
64. -3 M solution of dichloroethane.
65. (b) Gutmann, V The Donor-Acceptor Approach to Molecular Interactions; Plenum Press: New York, 1978.
66. (c) Gutmann, V. Electrochim. Acta 1976, 21, 661.
67. (d) Gutmann, V. Coordination Chemistry in Non-Aqueous Solutions, Springer-Verlag New York, 1968.
68. Neyhart, G. A., Hupp, J. T., Timpson, C. J , Bates, W D.; Meyer, T. J. J. Am. Chem. Soc. Following paper in this issue
69. (a) Richardson, D. E., Taube, H. Inorg. Chem. 1981, 20, 1278.
70. (b) Sutton, J E.; Taube, H. Inorg. Chem. 1981, 20, 3125.
71. 4+ ΔG° for eq 3 is 1/2 this value.
72. Marcus, R. A.; Sutin, N. Comments Inorg. Chem. 1986, 5, 119.
73. Richardson, D. E.; Taube, H. Coord. Chem. Rev. 1984, 60, 107
74. Creutz, C.; Taube, H. J. Am. Chem. Soc. 1973, 95, 1086.
75. Johnson, E. C.; Callahan, R. W.; Eckberg, R. P.; Hatfield, W. E., Meyer, T. J. Inorg. Chem. 1979, 18, 618.
76. Kober, E. M. Ph.D. Dissertation, University of North Carolina at Chapel Hill, 1982
77. Richardson, D. E.; Taube, H. J. Am. Chem. Soc. 1983, 105, 40.
78. Hupp, J. T. J. Am. Chem. Soc. 1990, 112, 1563.
79. (a) Bertrand, P. Chem. Phys. Lett. 1987, 140, 57.
80. (b) Ondrechen, M. J., Ko, J.; Zhang, L.-T. J. Am. Chem. Soc. 1987, 109, 1672.
81. (c) Piepho, S. B. J. Am. Chem. Soc. 1990, 112, 4197.
82. (d) Creutz, C., Chou, M. H. Inorg. Chem. 1987, 26, 2995.