Influence of solvent on the spectroscopic properties of cyano complexes of ruthenium(II)

Journal of Physical Chemistry

Volumn 100, Issue 8, 1996, Pages 2915-2925

  Timpson, Cliff J ^a   Bignozzi, Carlo A ^b   Patrick Sullivan, B ^d   Kober, Edward M ^c   Meyer, Thomas J ^a  

^a University of North Carolina at Chapel Hill   (United States)

^b UNIVERSITY OF FERRARA   (Italy)

^c LOS ALAMOS NATIONAL LABORATORY   (United States)

^d UNIVERSITY OF WYOMING   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ELECTRONIC STRUCTURE; PHYSICAL CHEMISTRY; SOLVENTS; SPECTRUM ANALYSIS;

RUTHENIUM CYANO COMPLEXES; SOLVENT EFFECTS; SPECTROSCOPIC PROPERTIES;

RUTHENIUM COMPOUNDS;

EID: 0030079929     PISSN: 00223654     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp953179m     Document Type: Article

References (96)

1. (a) Weit, S. K.; Grutsch, P. A.; Kutal, C. Inorg. Chem. 1991, 30, 2819.
2. (b) Saleh, A. A.; Crutchley, R. J. Inorg. Chem. 1990, 29, 2132.
3. (c) Kozik, M.; Sutin, N.; Winkler, J. R. Coor. Chem. Rev. 1990, 97, 23.
4. (d) Blackbourn, R. L.; Hupp, J. T. J. Phys. Chem. 1988, 92, 2817.
5. (e) Lay, P. A.; Mcalpine, N. S.; Hupp, J. T.; Weaver, M. J.; Sargeson, A. M. Inorg. Chem. 1990, 29, 4322.
6. (f) McManis, G. E.; Nielson, R. M.; Gochev, A.; Weaver, M. J. J. Am. Chem. Sac. 1989, 111, 5533.
7. (g) Blackbourn, R. L.; Hupp, J. T. J. Phys. Chem. 1988, 92, 2817.
8. (a) Burgess, J. Spectrochim. Acta, Part A 1970, 26A, 1957.
9. (b) Burgess, J. Spectrochim. Acta, Part A 1970, 26A, 1369.
10. 6) as described in: Durham, B.; Walsh, J. L.; Carter, C. L.; Meyer, T. J. Inorg. Chem. 1980, 19, 860.
11. (b) Demas, J. N.; Turner, T. F.; Crosby, G. A. Inorg. Chem. 1969, 8, 674.
12. (c) Bignozzi, C. A.; Chiorboli, C.; Indelli, M. A.; Rampi Scandola, M. A.; Varani, G.; Scandola, F. J. Am. Chem. Soc. 1986, 108, 7872.
13. (d) Sullivan, B. P.; Calvert, J. M.; Meyer, T. J. Inorg. Chem. 1980, 19, 1404.
14. (e) Figard, J. E.; Paukstelis, J. V.; Byrne, E. F.; Petersen, J. D. J. Am. Chem. Soc. 1977, 99, 8417.
15. (a) Fung, E. Y.; Chua, A. C. M.; Curtis, J. C. Inorg. Chem. 1988, 27, 1294.
16. (b) Bignozzi, C. A.; Scandola, F. Inorg. Chem. 1984, 23, 1540.
17. (c) Bessler, P.; Zelewsky, A.; Juris, A.; Barigelletti, F.; Balzani, V. Gazz. Chim. Ital. 1985, 115, 723.
18. (d) Kato, M.; Yamauchi, S.; Hirota, N. J. Phys. Chem. 1989, 93, 3422.
19. (e) Kitamura, N.; Kim, H.-B.; Kawanishi, Y.; Obata, R.; Tazuke, S. J. Phys. Chem. 1986, 90, 1488.
20. (a) Curtis, J. C.; Sullivan, B. P.; Meyer, T. J. Inorg. Chem. 1983, 22, 224.
21. (b) Blackbourn, R. L.; Hupp, J. T. Inorg. Chem. 1989, 28, 3786.
22. (a) Caspar, J. V.; Meyer, T. J. Inorg. Chem. 1983, 33, 3444.
23. (b) Caspar, J. V.; Meyer, T. J. J. Am. Chem. Soc. 1983, 105, 5583.
24. (c) Kober, E. M.; Caspar, J. V.; Lumpkin, R. S.; Meyer, T. J. J. Phys. Chem. 1986, 90, 3722.
25. (a) Kober, E. M.; Meyer, T. J. Inorg. Chem. 1982, 21, 3967.
26. (b) Meyer, T. J. Pure Appl. Chem. 1986, 58, 1193.
27. (c) Juris, A.; Barigelletti, F.; Balzani, V.; Campagna, S.; Belser, P.; von Zelewsky, A. Coord. Chem. Rev. 1988, 84, 85.
28. (a) Gutmann, V. The Donor - Acceptor Approach to Molecular Interactions; Plenum: New York, 1980.
29. (b) Gutmann, V.; Resch, G.; Linert, W. Coord. Chem. Rev. 1982, 43, 133.
30. 5 and the solvent in 1,2-dichloroethane.
31. Bard, A. J.; Faulkner, L. F. Electrochemical Methods. Fundamentals and Applications; John Wiley and Sons: New York, 1980.
32. Schilt, A. A. Inorg. Chem. 1964, 3, 1323.
33. (a) Sullivan, B. P. J. Phys. Chem. 1989, 93, 24.
34. (b) Creutz, C. Inorg. Chem. 1987, 26, 2995.
35. Kober, E. M.; Sullivan, B. P.; Meyer, T. J. Inorg. Chem. 1984, 23, 2098.
36. (a) Creutz, C. Prog. Inorg. Chem. 1983, 30, 1.
37. Goldsby, K. A.; Meyer, T. J. Inorg. Chem. 1984, 23, 3002.
38. (b) Sullivan, B. P.; Curtis, J. C.; Kober, E. M.; Meyer, T. J. Nouv. J. Chim. 1980, 4, 643.
39. (c) Powers, M. J.; Meyer, T. J. J. Am. Chem. Soc. 1980, 102, 1289.
40. (d) Callahan, R. W.; Keene, F. R.; Meyer, T. J.; Salmon, D. J. J. Am. Chem. Soc. 1977, 99, 1064.
41. (e) Powers, M. J.; Callahan, R. W.; Salmon, D. J.; Meyer, T. J. Inorg. Chem. 1976, 75, 1457.
42. (f) Sullivan, B. P.; Meyer, T. J. Inorg. Chem. 1980, 19, 752.
43. (a) Kolling, O. W. J. Phys. Chem. 1991, 95, 3950.
44. (b) Suppan, P. J. Photochem. Photobiol, A: Chem. 1990, 50, 293.
45. (c) Marcus, R. A. J. Chem. Phys. 1965, 43, 1261.
46. (d) Onsager, L. J. Am. Chem. Soc. 1934, 58, 1486.
47. (e) Kirkwood, J. G. Chem. Phys. 1934, 2, 351.
48. Hupp, J. T.; Neyhart, G. A.; Meyer, T. J.; Kober, E. M. J. Phys. Chem. 1992, 96, 10820.
49. Hupp, J. T.; Kober, E. M.; Neyhart, G. A.; Meyer, T. J. In Mixed Valency Systems: Applications in Chemistry, Physics and Biology; Prassides, K., Ed.; Kluwer Academic: Dordrecht, 1991; pp 51-56.
50. Marcus, R. A.; Sutin, N. Comments Inorg. Chem. 1986, 5, 119.
51. Brunschwig, B. S.; Ehrenson, S.; Sutin, N. J. Phys. Chem. 1987, 91, 4714.
52. McRae, E. G. J. Phys. Chem. 1957, 61, 562.
53. 1/2 values were measured directly in a limited number of solvents vs the ferrocene/ferricinium couple.
54. (a) Caspar, J. V.; Meyer, .T. J. J. Am. Chem. Soc. 1983, 105, 5583.
55. (b) Caspar, J. V.; Westmoreland, T. D.; Allen, G. H.; Bradley, P. G.; Meyer, T. J.; Woodruff, W. H. J. Am. Chem. Soc. 1984, 106, 3492.
56. (c) Oh, D. H.; Boxer, S. G. J. Am. Chem. Soc. 1989, 111, 130.
57. (d) Milder, S. J. Inorg. Chem. 1989, 28, 868.
58. (e) Dodsworth, E. S.; Lever, A. B. P. Coord. Chem. Rev. 1990, 97, 271.
59. 2+ that selected vibrations that contribute to the internal reorganizational energy are modulated significantly by specific ammine-solvent hydrogen bonding interactions. Similar effects may exist for the cyano complexes.
60. S-T is relatively independent of solvent.
61. (a) Yersin, H.; Huber, P.; Wiedenhofer, H. Coord. Chem. Rev. 1994, 132, 35.
62. (b) Yersin, H.; Braun, D.; Hensler, G.; Gallhuber, E. Nato ASI Ser., Ser C 1989, 288, 195.
63. (c) Yersin, H.; Gallhuber, E.; Hensler, G.; Schweitzer, D. Chem. Phys. Lett. 1989, 161, 315.
64. (d) Yersin, H.; Gallhuber, E.; Hensler, G. Chem. Phys. Lett. 1987, 140, 157.
65. (d) Yersin, H.; Hensler, G.; Galhuber, E. Inorg. Chem. Acta 1987, 132, 187.
66. (f) Hensler, G.; Gallhuber, E.; Yersin, H. Inorg. Chem. Acta 1986, 113 (2), 91.
67. Bradley, P. G.; Kress, N.; Hornberger, B. A.; Dallinger, R. F.; Woodruff, W. H. J. Am. Chem. Soc. 1981, 103, 7441.
68. Dallinger, R. F.; Woodruff, W. H. J. Am. Chem. Soc. 1979, 101, 4391.
69. Strommen, D. P.; Mallick, P. K.; Danzer, G. D.; Lumpkin, R. S.; Kincaid, J. R. J. Phys. Chem. 1990, 94, 1357.
70. Mallick, P. K.; Strommen, D. P.; Kincaid, J. R. J. Am. Chem. Soc. 1990, 112, 1686.
71. Mabrouk, P. A.; Wrighton, M. S. Inorg. Chem. 1986, 25, 526.
72. Smothers, W. K.; Wrighton, M. S. J. Am. Chem. Soc. 1983, 105, 1067.
73. Chang, X. J.; Xu, X.; Yabe, T.; Yu, S.-C.; Anderson, D. R.; Orman, L. K.; Hopkins, J. B. J. Phys. Chem. 1990, 94, 729.
74. Kjaer, A. M.; Ulstrup, J. J. Am. Chem. Soc. 1988, 110, 3874.
75. Kjaer, A. M.; Ulstrup, J. J. Am. Chem. Soc. 1987, 109, 1934.
76. (a) Kober, E. M.; Meyer, T. J. Inorg. Chem. 1985, 24, 106.
77. (b) Kober, E. M.; Marshall, J. L.; Dressick, W. J.; Sullivan, B. P.; Caspar, J. V.; Meyer, T. J. Inorg. Chem. 1985, 24, 2755.
78. (c) Kober, E. M.; Caspar, J. V.; Lumpkin, R. S.; Meyer, T. J. J. Phys. Chem. 1986, 90, 3722.
79. (d) Johnson, R. S.; Westmoreland, D. A.; Caspar, J. V.; Barqawi, K. R.; Meyer, T. J. Inorg. Chem. 1988, 27, 3195.
80. Worl, L. A.; Duesing, R.; Chen, P.; Dellaciana, L.; Meyer, T. J. J. Chem. Soc., Dalton Trans. 1991, 849.
81. em" for the v* = 0 → v = 0 vibronic components.
82. (a) Peterson, S. H.; Demas, J. N. J. Am. Chem. Soc. 1976, 98, 7880.
83. (b) Peterson, S. H.; Demas, J. N. J. Am. Chem. Soc. 1979, 101, 6571.
84. (c) Indelli, M. T.; Bignozzi, C. A.; Marconi, A.; Scandola, F. In Photochemistry and Photophysics of Coordination Compounds; Yersin, H., Vogler, A., Eds.; Springer-Verlag: Berlin, 1987; p 159.
85. (d) Davila, J.; Bignozzi, C. A.; Scandola, F. J. Phys. Chem. 1989, 93, 1373.
86. (a) Doom, S. K.; Hupp, J. T. J. Am. Chem. Soc. 1989, 111, 4704.
87. (b) Mines, G. A.; Roberts, J. A.; Hupp, J. T. Inorg. Chem. 1992, 31, 125.
88. (c) Roberts, J. A.; Hupp, J. T. Inorg. Chem. 1992, 31, 157.
89. (a) Zeng, J.; Hush, N. S.; Reimers, J. R. J. Phys. Chem. 1994, 98, 11075.
90. (b) Broo, A.; Larsen, S. Chem. Phys. 1992, 161, 363.
91. (c) Zhang, L.-T.; Ondrechen, M. J. Inorg. Chim. Acta 1994, 226, 43.
92. (d) Stavrev, K. K.; Zerner, M. C.; Meyer, T. J. J. Am. Chem. Soc., in press.
93. (a) Hupp, J. T. J. Am. Chem. Soc. 1990, 112, 1563.
94. (b) Ennix, K. S.; McMahon, P. T.; Rosa, R.; Curtis, J. C. Inorg. Chem. 1987, 26, 2600.
95. (c) Chang, J. P.; Fung, E. Y.; Curtis, J. C. Inorg. Chem. 1986, 25, 4233.
96. (d) Curtis, J. C.; Blackbourne, R. L.; Ennix, K. S.; Hu, S.; Roberts, J. A.; Hupp, J. T. Inorg. Chem. 1989, 28, 3791.