Intriguing Optoelectronic Properties of Metal Halide Perovskites

Chemical Reviews

Volumn 116, Issue 21, 2016, Pages 12956-13008

  Manser, Joseph S ^a,b   Christians, Jeffrey A ^a   Kamat, Prashant V ^a,b,c  

^a UNIVERSITY OF NOTRE DAME   (United States)

^b University of Notre Dame   (United States)

^c UNIVERSITY OF NOTRE DAME   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ELECTRONIC STRUCTURE; PEROVSKITE;

HALIDE PEROVSKITES; HYBRID ORGANIC-INORGANIC; OPTOELECTRONIC APPLICATIONS; OPTOELECTRONIC PROPERTIES; OPTOELECTRONIC TECHNOLOGY; PHOTOPHYSICAL PROCESS; PHOTOPHYSICAL PROPERTIES; SOLUTION-PROCESSED;

METAL HALIDES;

EID: 84992175884     PISSN: 00092665     EISSN: 15206890     Source Type: Journal    
DOI: 10.1021/acs.chemrev.6b00136     Document Type: Review

References (376)

1. Rose, G. De Perowskite, Fossili Novo. In De Novis Quibusdam Fossilibus Quae In Montibus Uraliis Inveniuntur; AG Schade: Berlin, 1839; pp 3-5.
2. Wells, H. L. Über Die Cäsium- Und Kalium-Bleihalogenide Zeitschrift für Anorg. Chemie 1893, 3, 195-210 10.1002/zaac.18930030124
3. Møller, C. K. A Phase Transition in Cæsium Plumbochloride Nature 1957, 180, 981-982 10.1038/180981a0
4. Møller, C. K. Crystal Structure and Photoconductivity of Cæsium Plumbohalides Nature 1958, 182, 1436-1436 10.1038/1821436a0
5. Bowman, H. L. On the Structure of Perovskite from the Burgumer Alp, Pfitschthal, Tyrol Mineral. Mag. 1908, 15, 156-176 10.1180/minmag.1908.015.69.07
6. Goldschmidt, V. M. Titanium Pigment and Process of Producing the Same. US1436164 A, 1922.
7. Wainer, E. High Titania Dielectrics Trans. Electrochem. Soc. 1946, 89, 331 10.1149/1.3071718
8. 3 J. Phys. Soc. Jpn. 1946, 1, 32-33 10.1143/JPSJ.1.32
9. Gray, R. B. Transducer and Method of Making the Same. US2486560 A, 1946.
10. Cross, L. E.; Newnham, R. E. History of Ferroelectrics Ceram. Civiliz. 1987, III, 289-305
11. 4 Naturwissenschaften 1953, 40, 241-241 10.1007/BF00591545
12. de Jongh, L. J.; Miedema, A. R. Experiments on Simple Magnetic Model Systems Adv. Phys. 1974, 23, 1-260 10.1080/00018739700101558
13. Willett, R.; Place, H.; Middleton, M. Crystal Structures of Three New Copper(II) Halide Layered Perovskites: Structural, Crystallographic, and Magnetic Correlations J. Am. Chem. Soc. 1988, 110, 8639-8650 10.1021/ja00234a010
14. Mostafa, M.; Willett, R. Magnetic Properties of Ferrous Chloride Complexes with Two-Dimensional Structures Phys. Rev. B 1971, 4, 2213-2215 10.1103/PhysRevB.4.2213
15. Geick, R.; Strobel, K. Phonons in Perovskite-Type Layer Structures J. Phys. C: Solid State Phys. 1979, 12, 27-39 10.1088/0022-3719/12/1/016
16. 4 Solid State Commun. 1989, 69, 933-936 10.1016/0038-1098(89)90935-6
17. 4 Solid State Commun. 1991, 77, 923-926 10.1016/0038-1098(91)90347-X
18. 4 Solid State Commun. 1991, 79, 245-248 10.1016/0038-1098(91)90643-A
19. 4-Based Layered Semiconductors Phys. Rev. B: Condens. Matter Mater. Phys. 1992, 45, 6961-6964 10.1103/PhysRevB.45.6961
20. 4 Solid State Commun. 1993, 86, 479-483 10.1016/0038-1098(93)90092-2
21. 4 Solid State Commun. 1994, 91, 695-698 10.1016/0038-1098(94)00435-8
22. 4-Based Two-Dimensional Semiconductor Structures Surf. Sci. 1992, 267, 323-326 10.1016/0039-6028(92)91147-4
23. Hanamura, E.; Nagaosa, N.; Kumagai, M.; Takagahara, T. Quantum Wells with Enhanced Exciton Effects and Optical Non-Linearity Mater. Sci. Eng., B 1988, 1, 255-258 10.1016/0921-5107(88)90006-2
24. Mitzi, D. B.; Feild, C. A.; Harrison, W. T. A.; Guloy, A. M. Conducting Tin Halides with a Layered Organic-Based Perovskite Structure Nature 1994, 369, 467-469 10.1038/369467a0
25. Mitzi, D. B.; Wang, S.; Feild, C. A.; Chess, C. A.; Guloy, A. M. Conducting Layered Organic-Inorganic Halides Containing < 110>-Oriented Perovskite Sheets Science 1995, 267, 1473-1476 10.1126/science.267.5203.1473
26. 4 as an Emitter Synth. Met. 1995, 71, 2013-2014 10.1016/0379-6779(94)03142-S
27. Hattori, T.; Taira, T.; Era, M.; Tsutsui, T.; Saito, S. Highly Efficient Electroluminescence from a Heterostructure Device Combined with Emissive Layered-Perovskite and an Electron-Transporting Organic Compound Chem. Phys. Lett. 1996, 254, 103-108 10.1016/0009-2614(96)00310-7
28. Chondroudis, K.; Mitzi, D. B. Electroluminescence from an Organic-Inorganic Perovskite Incorporating a Quaterthiophene Dye within Lead Halide Perovskite Layers Chem. Mater. 1999, 11, 3028-3030 10.1021/cm990561t
29. Kagan, C. R.; Mitzi, D. B.; Dimitrakopoulos, C. D. Organic-Inorganic Hybrid Materials as Semiconducting Channels in Thin-Film Field-Effect Transistors Science 1999, 286, 945-947 10.1126/science.286.5441.945
30. Mitzi, D. B.; Dimitrakopoulos, C. D.; Kosbar, L. L. Structurally Tailored Organic-Inorganic Perovskites: Optical Properties and Solution-Processed Channel Materials for Thin-Film Transistors Chem. Mater. 2001, 13, 3728-3740 10.1021/cm010105g
31. Mitzi, D. B.; Dimitrakopoulos, C. D.; Rosner, J.; Medeiros, D. R.; Xu, Z.; Noyan, C. Hybrid Field-Effect Transistor Based on a Low-Temperature Melt-Processed Channel Layer Adv. Mater. 2002, 14, 1772-1776 10.1002/1521-4095(20021203)14:23<1772::AID-ADMA1772>3.0.CO;2-Y
32. Pankove, J. I. Optical Processes in Semiconductors; Dover Publications, Inc.: New York, 1971.
33. Pelant, I.; Valenta, J. Luminescence Spectroscopy of Semiconductors; Oxford University Press: New York, 2012.
34. Sze, S. M.; Ng, K. K. Physics of Semiconductor Devices, 3 rd ed.; Wiley-Interscience: Hoboken, 2007.
35. Shah, J. Ultrafast Spectroscopy of Semiconductors and Semiconductor Nanostructures; Springer: Heidelberg, 1996.
36. Lin, C. C.; Meijerink, A.; Liu, R.-S. Critical Red Components for Next-Generation White LEDs J. Phys. Chem. Lett. 2016, 7, 495-503 10.1021/acs.jpclett.5b02433
37. Zhang, X.; Lin, H.; Huang, H.; Reckmeier, C.; Zhang, Y.; Choy, W. C. H.; Rogach, A. L. Enhancing the Brightness of Cesium Lead Halide Perovskite Nanocrystal Based Green Light-Emitting Devices through the Interface Engineering with Perfluorinated Ionomer Nano Lett. 2016, 16, 1415-1420 10.1021/acs.nanolett.5b04959
38. Ling, Y.; Yuan, Z.; Tian, Y.; Wang, X.; Wang, J. C.; Xin, Y.; Hanson, K.; Ma, B.; Gao, H. Bright Light-Emitting Diodes Based on Organometal Halide Perovskite Nanoplatelets Adv. Mater. 2016, 28, 305-311 10.1002/adma.201503954
39. Pathak, S.; Sakai, N.; Wisnivesky Rocca Rivarola, F.; Stranks, S. D.; Liu, J.; Eperon, G. E.; Ducati, C.; Wojciechowski, K.; Griffiths, J. T.; Haghighirad, A. A. et al. Perovskite Crystals for Tunable White Light Emission Chem. Mater. 2015, 27, 8066-8075 10.1021/acs.chemmater.5b03769
40. Tan, Z.-K.; Moghaddam, R. S.; Lai, M. L.; Docampo, P.; Higler, R.; Deschler, F.; Price, M.; Sadhanala, A.; Pazos, L. M.; Credgington, D. et al. Bright Light-Emitting Diodes Based on Organometal Halide Perovskite Nat. Nanotechnol. 2014, 9, 687-692 10.1038/nnano.2014.149
41. Chin, X. Y.; Cortecchia, D.; Yin, J.; Bruno, A.; Soci, C. Lead Iodide Perovskite Light-Emitting Field-Effect Transistor Nat. Commun. 2015, 6, 7383 10.1038/ncomms8383
42. McMeekin, D. P.; Sadoughi, G.; Rehman, W.; Eperon, G. E.; Saliba, M.; Horantner, M. T.; Haghighirad, A.; Sakai, N.; Korte, L.; Rech, B. et al. A Mixed-Cation Lead Mixed-Halide Perovskite Absorber for Tandem Solar Cells Science 2016, 351, 151-155 10.1126/science.aad5845
43. Bailie, C. D.; Christoforo, M. G.; Mailoa, J. P.; Bowring, A. R.; Unger, E. L.; Nguyen, W. H.; Burschka, J.; Pellet, N.; Lee, J. Z.; Grätzel, M. et al. Semi-Transparent Perovskite Solar Cells for Tandems with Silicon and CIGS Energy Environ. Sci. 2015, 8, 956-963 10.1039/C4EE03322A
44. 2 J. Phys. Chem. Lett. 2016, 7, 161-166 10.1021/acs.jpclett.5b02686
45. 4 Tandem Assembly for Photolytic Solar Fuels Production J. Am. Chem. Soc. 2015, 137, 974-981 10.1021/ja511739y
46. Luo, J.; Im, J.-H.; Mayer, M. T.; Schreier, M.; Nazeeruddin, M. K.; Park, N.-G.; Tilley, S. D.; Fan, H. J.; Grätzel, M. Water Photolysis at 12.3% Efficiency via Perovskite Photovoltaics and Earth-Abundant Catalysts Science 2014, 345, 1593-1596 10.1126/science.1258307
47. Gurudayal; Sabba, D.; Kumar, M. H.; Wong, L. H.; Barber, J.; Grätzel, M.; Mathews, N. Perovskite-Hematite Tandem Cells for Efficient Overall Solar Driven Water Splitting Nano Lett. 2015, 15, 3833-3839 10.1021/acs.nanolett.5b00616
48. 3 Single Crystals: Inverse Temperature Crystallization and Visible-Blind UV-Photodetector J. Phys. Chem. Lett. 2015, 6, 3781-3786 10.1021/acs.jpclett.5b01666
49. Lin, Q.; Armin, A.; Burn, P. L.; Meredith, P. Filterless Narrowband Visible Photodetectors Nat. Photonics 2015, 9, 687-694 10.1038/nphoton.2015.175
50. 2 Blocking Layer under Reverse Bias J. Phys. Chem. Lett. 2014, 5, 3931-3936 10.1021/jz502039k
51. Xing, G.; Mathews, N.; Lim, S. S.; Yantara, N.; Liu, X.; Sabba, D.; Grätzel, M.; Mhaisalkar, S.; Sum, T. C. Low-Temperature Solution-Processed Wavelength-Tunable Perovskites for Lasing Nat. Mater. 2014, 13, 476-480 10.1038/nmat3911
52. Deschler, F.; Price, M.; Pathak, S.; Klintberg, L. E.; Jarausch, D. D.; Higler, R.; Hüttner, S.; Leijtens, T.; Stranks, S. D.; Snaith, H. J. et al. High Photoluminescence Efficiency and Optically Pumped Lasing in Solution-Processed Mixed Halide Perovskite Semiconductors J. Phys. Chem. Lett. 2014, 5, 1421-1426 10.1021/jz5005285
53. Fu, Y.; Zhu, H.; Schrader, A. W.; Liang, D.; Ding, Q.; Joshi, P.; Hwang, L.; Zhu, X.-Y.; Jin, S. Nanowire Lasers of Formamidinium Lead Halide Perovskites and Their Stabilized Alloys with Improved Stability Nano Lett. 2016, 16, 1000-1008 10.1021/acs.nanolett.5b04053
54. Zhu, H.; Fu, Y.; Meng, F.; Wu, X.; Gong, Z.; Ding, Q.; Gustafsson, M. V.; Trinh, M. T.; Jin, S.; Zhu, X.-Y. Lead Halide Perovskite Nanowire Lasers with Low Lasing Thresholds and High Quality Factors Nat. Mater. 2015, 14, 636-642 10.1038/nmat4271
55. Sutherland, B. R.; Hoogland, S.; Adachi, M. M.; Wong, C. T. O.; Sargent, E. H. Conformal Organohalide Perovskites Enable Lasing on Spherical Resonators ACS Nano 2014, 8, 10947-10952 10.1021/nn504856g
56. Yakunin, S.; Protesescu, L.; Krieg, F.; Bodnarchuk, M. I.; Nedelcu, G.; Humer, M.; De Luca, G.; Fiebig, M.; Heiss, W.; Kovalenko, M. V. Low-Threshold Amplified Spontaneous Emission and Lasing from Colloidal Nanocrystals of Caesium Lead Halide Perovskites Nat. Commun. 2015, 6, 8056 10.1038/ncomms9056
57. 3 Perovskite Single Crystal Nat. Commun. 2015, 6, 7961 10.1038/ncomms8961
58. Yang, Y.; Ostrowski, D. P.; France, R. M.; Zhu, K.; van de Lagemaat, J.; Luther, J. M.; Beard, M. C. Observation of a Hot-Phonon Bottleneck in Lead-Iodide Perovskites Nat. Photonics 2015, 10, 53-59 10.1038/nphoton.2015.213
59. Shi, D.; Adinolfi, V.; Comin, R.; Yuan, M.; Alarousu, E.; Buin, A.; Chen, Y.; Hoogland, S.; Rothenberger, A.; Katsiev, K. et al. Low Trap-State Density and Long Carrier Diffusion in Organolead Trihalide Perovskite Single Crystals Science 2015, 347, 519-522 10.1126/science.aaa2725
60. Brenner, T. M.; Egger, D. A.; Kronik, L.; Hodes, G.; Cahen, D. Hybrid Organic-Inorganic Perovskites: Low-Cost Semiconductors with Intriguing Charge-Transport Properties Nat. Rev. Mater. 2016, 1, 15007 10.1038/natrevmats.2015.7
61. Mitzi, D. B. Templating and Structural Engineering in Organic-Inorganic Perovskites J. Chem. Soc. Dalt. Trans. 2001, 1-12 10.1039/b007070j
62. Abdelhady, A. L.; Saidaminov, M. I.; Murali, B.; Adinolfi, V.; Voznyy, O.; Katsiev, K.; Alarousu, E.; Comin, R.; Dursun, I.; Sinatra, L. et al. Heterovalent Dopant Incorporation for Bandgap and Type Engineering of Perovskite Crystals J. Phys. Chem. Lett. 2016, 7, 295-301 10.1021/acs.jpclett.5b02681
63. Mei, A.; Li, X.; Liu, L.; Ku, Z.; Liu, T.; Rong, Y.; Xu, M.; Hu, M.; Chen, J.; Yang, Y. et al. A Hole-Conductor-Free, Fully Printable Mesoscopic Perovskite Solar Cell with High Stability Science 2014, 345, 295-298 10.1126/science.1254763
64. Saparov, B.; Mitzi, D. B. Organic-Inorganic Perovskites: Structural Versatility for Functional Materials Design Chem. Rev. 2016, 116, 4558-4596 10.1021/acs.chemrev.5b00715
65. 3 (X = F, Cl, Br, I) Halide Perovskites Acta Crystallogr., Sect. B: Struct. Sci. 2008, 64, 702-707 10.1107/S0108768108032734
66. Kieslich, G.; Sun, S.; Cheetham, T. Solid-State Principles Applied to Organic-Inorganic Perovskites: New Tricks for an Old Dog Chem. Sci. 2014, 5, 4712-4715 10.1039/C4SC02211D
67. Kieslich, G.; Sun, S.; Cheetham, T. An Extended Tolerance Factor Approach for Organic-Inorganic Perovskites Chem. Sci. 2015, 6, 3430-3433 10.1039/C5SC00961H
68. Travis, W.; Glover, E. N. K.; Bronstein, H.; Scanlon, D. O.; Palgrave, R. G. On the Application of the Tolerance Factor to Inorganic and Hybrid Halide Perovskites: A Revised System. Chem. Sci. 2016, DOI: 10.1039/C5SC04845A.
69. Goldschmidt, V. M. Die Gesetze Der Krystallochemie Naturwissenschaften 1926, 14, 477-485 10.1007/BF01507527
70. Stoumpos, C. C.; Kanatzidis, M. G. The Renaissance of Halide Perovskites and Their Evolution as Emerging Semiconductors Acc. Chem. Res. 2015, 48, 2791-2802 10.1021/acs.accounts.5b00229
71. Shannon, R. D. Revised Effective Ionic Radii and Systematic Studies of Interatomic Distances in Halides and Chalcogenides Acta Crystallogr., Sect. A: Cryst. Phys., Diffr., Theor. Gen. Crystallogr. 1976, 32, 751-767 10.1107/S0567739476001551
72. Cohen, B. N.; Labarca, C.; Davidson, N.; Lester, H. A. Mutations in M2 Alter the Selectivity of the Mouse Nicotinic Acetylcholine Receptor for Organic and Alkali Metal Cations J. Gen. Physiol. 1992, 100, 373-400 10.1085/jgp.100.3.373
73. Salje, E. Characteristics of Perovskite-Related Materials [and Discussion] Philos. Trans. R. Soc., A 1989, 328, 409-416 10.1098/rsta.1989.0044
74. Glazer, A. M. Simple Ways of Determining Perovskite Structures Acta Crystallogr., Sect. A: Cryst. Phys., Diffr., Theor. Gen. Crystallogr. 1975, 31, 756-762 10.1107/S0567739475001635
75. Stoumpos, C. C.; Malliakas, C. D.; Kanatzidis, M. G. Semiconducting Tin and Lead Iodide Perovskites with Organic Cations: Phase Transitions, High Mobilities, and Near-Infrared Photoluminescent Properties Inorg. Chem. 2013, 52, 9019-9038 10.1021/ic401215x
76. Li, Z.; Yang, M.; Park, J.-S.; Wei, S.-H.; Berry, J. J.; Zhu, K. Stabilizing Perovskite Structures by Tuning Tolerance Factor: Formation of Formamidinium and Cesium Lead Iodide Solid-State Alloys Chem. Mater. 2016, 28, 284-292 10.1021/acs.chemmater.5b04107
77. Filip, M. R.; Eperon, G. E.; Snaith, H. J.; Giustino, F. Steric Engineering of Metal-Halide Perovskites with Tunable Optical Band Gaps Nat. Commun. 2014, 5, 5757 10.1038/ncomms6757
78. Goodyear, J.; Ali, E. M.; Steigmann, G. A. Rubidium Tetrachloromanganate Acta Crystallogr., Sect. B: Struct. Crystallogr. Cryst. Chem. 1977, 33, 2932-2933 10.1107/S0567740877009868
79. Mitzi, D. B.; Chondroudis, K.; Kagan, C. R. Organic-Inorganic Electronics IBM J. Res. Dev. 2001, 45, 29-45 10.1147/rd.451.0029
80. Noh, J. H.; Im, S. H.; Heo, J. H.; Mandal, T. N.; Seok, S. Il. Chemical Management for Colorful, Efficient, and Stable Inorganic-Organic Hybrid Nanostructured Solar Cells Nano Lett. 2013, 13, 1764-1769 10.1021/nl400349b
81. 3, X = Cl, Br, and I): Novel Optoelectronic Materials Showing Bright Emission with Wide Color Gamut Nano Lett. 2015, 15, 3692-3696 10.1021/nl5048779
82. 3, X = Cl, Br, I) Nano Lett. 2015, 15, 5635-5640 10.1021/acs.nanolett.5b02404
83. Li, G.; Ho, J. Y.-L.; Wong, M.; Kwok, H. S. Reversible Anion Exchange Reaction in Solid Halide Perovskites and Its Implication in Photovoltaics J. Phys. Chem. C 2015, 119, 26883-26888 10.1021/acs.jpcc.5b09300
84. Pellet, N.; Teuscher, J.; Maier, J.; Grätzel, M. Transforming Hybrid Organic Inorganic Perovskites by Rapid Halide Exchange Chem. Mater. 2015, 27, 2181-2188 10.1021/acs.chemmater.5b00281
85. Akkerman, Q. a.; D'Innocenzo, V.; Accornero, S.; Scarpellini, A.; Petrozza, A.; Prato, M.; Manna, L. Tuning the Optical Properties of Cesium Lead Halide Perovskite Nanocrystals by Anion Exchange Reactions J. Am. Chem. Soc. 2015, 137, 10276-10281 10.1021/jacs.5b05602
86. Solis-Ibarra, D.; Smith, I. C.; Karunadasa, H. I. Post-Synthetic Halide Conversion and Selective Halogen Capture in Hybrid Perovskites Chem. Sci. 2015, 6, 4054-4059 10.1039/C5SC01135C
87. Eperon, G. E.; Beck, C. E.; Snaith, H. J. Cation Exchange for Thin Film Lead Iodide Perovskite Interconversion Mater. Horiz. 2016, 3, 63-71 10.1039/C5MH00170F
88. x" Perovskite Adv. Funct. Mater. 2014, 24, 7102-7108 10.1002/adfm.201401872
89. x Mixed Halide Perovskite for Hybrid Solar Cells: The Role of Chloride as Dopant on the Transport and Structural Properties Chem. Mater. 2013, 25, 4613-4618 10.1021/cm402919x
90. Unger, E. L.; Bowring, A. R.; Tassone, C. J.; Pool, V. L.; Gold-Parker, A.; Cheacharoen, R.; Stone, K. H.; Hoke, E. T.; Toney, M. F.; McGehee, M. D. Chloride in Lead Chloride-Derived Organo-Metal Halides for Perovskite-Absorber Solar Cells Chem. Mater. 2014, 26, 7158-7165 10.1021/cm503828b
91. Pistor, P.; Borchert, J.; Fränzel, W.; Csuk, R.; Scheer, R. Monitoring the Phase Formation of Coevaporated Lead Halide Perovskite Thin Films by in Situ X-Ray Diffraction J. Phys. Chem. Lett. 2014, 5, 3308-3312 10.1021/jz5017312
92. Williams, S. T.; Zuo, F.; Chueh, C.-C.; Liao, C.-Y.; Liang, P.-W.; Jen, A. K.-Y. Role of Chloride in the Morphological Evolution of Organo-Lead Halide Perovskite Thin Films ACS Nano 2014, 8, 10640-10654 10.1021/nn5041922
93. Williams, S. T.; Chueh, C.; Jen, A. K.-Y. Navigating Organo-Lead Halide Perovskite Phase Space via Nucleation Kinetics toward a Deeper Understanding of Perovskite Phase Transformations and Structure-Property Relationships Small 2015, 11, 3088-3096 10.1002/smll.201403651
94. Nenon, D. P.; Christians, J. A.; Wheeler, L. M.; Blackburn, J. L.; Sanehira, E. M.; Dou, B.; Olsen, M. L.; Zhu, K.; Berry, J. J.; Luther, J. M. Structural and Chemical Evolution of Methylammonium Lead Halide Perovskites during Thermal Processing from Solution Energy Environ. Sci. 2016, 10.1039/C6EE01047D
95. 4 and Similar Compounds with a Layered Perovskite Structure J. Mater. Chem. 2000, 10, 515-518 10.1039/a906161d
96. Dohner, E. R.; Jaffe, A.; Bradshaw, L. R.; Karunadasa, H. I. Intrinsic White-Light Emission from Layered Hybrid Perovskites J. Am. Chem. Soc. 2014, 136, 13154-13157 10.1021/ja507086b
97. II = Ge, Sn, Pb; X = Cl, Br, I) J. Mater. Chem. 1995, 5, 1813-1818 10.1039/jm9950501813
98. Hao, F.; Stoumpos, C. C.; Chang, R. P. H.; Kanatzidis, M. G. Anomalous Band Gap Behavior in Mixed Sn and Pb Perovskites Enables Broadening of Absorption Spectrum in Solar Cells J. Am. Chem. Soc. 2014, 136, 8094-8099 10.1021/ja5033259
99. 3 Perovskite Solar Cells Covering up to 1060 nm J. Phys. Chem. Lett. 2014, 5, 1004-1011 10.1021/jz5002117
100. 3) for Efficient Solar Cell Applications RSC Adv. 2015, 5, 107497-107502 10.1039/C5RA19778C
101. 2+ Nanoscale 2015, 7, 6216-6229 10.1039/C5NR00041F
102. Giorgi, G.; Fujisawa, J.; Segawa, H.; Yamashita, K. The Cation Role in Structural and Electronic Properties of 3D Organic-Inorganic Perovskite Halides: A DFT Analysis J. Phys. Chem. C 2014, 118, 12176-12183 10.1021/jp504479c
103. Choi, H.; Jeong, J.; Kim, H.-B.; Kim, S.; Walker, B.; Kim, G.-H.; Kim, J. Y. Cesium-Doped Methylammonium Lead Iodide Perovskite Light Absorber for Hybrid Solar Cells Nano Energy 2014, 7, 80-85 10.1016/j.nanoen.2014.04.017
104. Pellet, N.; Gao, P.; Gregori, G.; Yang, T.-Y.; Nazeeruddin, M. K.; Maier, J.; Grätzel, M. Mixed-Organic-Cation Perovskite Photovoltaics for Enhanced Solar-Light Harvesting Angew. Chem., Int. Ed. 2014, 53, 3151-3157 10.1002/anie.201309361
105. Jeon, N. J.; Noh, J. H.; Yang, W. S.; Kim, Y. C.; Ryu, S.; Seo, J.; Seok, S. Il. Compositional Engineering of Perovskite Materials for High-Performance Solar Cells Nature 2015, 517, 476-480 10.1038/nature14133
106. Yang, W. S.; Noh, J. H.; Jeon, N. J.; Kim, Y. C.; Ryu, S.; Seo, J.; Seok, S. I. High-Performance Photovoltaic Perovskite Layers Fabricated through Intramolecular Exchange Science 2015, 348, 1234-1237 10.1126/science.aaa9272
107. 3 Adv. Mater. 2014, 26, 4991-4998 10.1002/adma.201401137
108. Binek, A.; Hanusch, F. C.; Docampo, P.; Bein, T. Stabilization of the Trigonal High-Temperature Phase of Formamidinium Lead Iodide J. Phys. Chem. Lett. 2015, 6, 1249-1253 10.1021/acs.jpclett.5b00380
109. Smith, I. C.; Hoke, E. T.; Solis-Ibarra, D.; McGehee, M. D.; Karunadasa, H. I. A Layered Hybrid Perovskite Solar-Cell Absorber with Enhanced Moisture Stability Angew. Chem. 2014, 126, 11414-11417 10.1002/ange.201406466
110. Hachmann, J.; Olivares-Amaya, R.; Atahan-Evrenk, S.; Amador-Bedolla, C.; Sánchez-Carrera, R. S.; Gold-Parker, A.; Vogt, L.; Brockway, A. M.; Aspuru-Guzik, A. The Harvard Clean Energy Project: Large-Scale Computational Screening and Design of Organic Photovoltaics on the World Community Grid J. Phys. Chem. Lett. 2011, 2, 2241-2251 10.1021/jz200866s
111. Ungersboeck, E.; Dhar, S.; Karlowatz, G.; Sverdlov, V.; Kosina, H.; Selberherr, S. The Effect of General Strain on the Band Structure and Electron Mobility of Silicon IEEE Trans. Electron Devices 2007, 54, 2183-2190 10.1109/TED.2007.902880
112. Fröhlich, D.; Heidrich, K.; Künzel, H.; Trendel, G.; Treusch, J. Cesium-Trihalogen-Plumbates a New Class of Ionic Semiconductors J. Lumin. 1979, 18-19, 385-388 10.1016/0022-2313(79)90146-7
113. Koutselas, I. B.; Ducasse, L.; Papavassiliou, G. C. Electronic Properties of Three- and Low-Dimensional Semiconducting Materials with Pb Halide and Sn Halide Units J. Phys.: Condens. Matter 1996, 8, 1217-1227 10.1088/0953-8984/8/9/012
114. Parry, D. E.; Tricker, M. J.; Donaldson, J. D. The Electronic Structure of CsSnBr3 and Related Trihalides; Studies Using XPS and Band Theory J. Solid State Chem. 1979, 28, 401-408 10.1016/0022-4596(79)90092-6
115. Lefebvre, I.; Lippens, P. E.; Lannoo, M.; Allan, G. Band Structure of CsSnBr3 Phys. Rev. B: Condens. Matter Mater. Phys. 1990, 42, 9174-9177 10.1103/PhysRevB.42.9174
116. 3 Phys. Rev. B: Condens. Matter Mater. Phys. 2013, 88, 165203 10.1103/PhysRevB.88.165203
117. 3 Perovskites for Solar Cell Applications Sci. Rep. 2014, 4, 4467 10.1038/srep04467
118. Brivio, F.; Butler, K. T.; Walsh, A.; van Schilfgaarde, M. Relativistic Quasiparticle Self-Consistent Electronic Structure of Hybrid Halide Perovskite Photovoltaic Absorbers Phys. Rev. B: Condens. Matter Mater. Phys. 2014, 89, 155204 10.1103/PhysRevB.89.155204
119. 3 Thin Films (X = Cl,Br) Phys. Rev. B: Condens. Matter Mater. Phys. 2008, 77, 045129 10.1103/PhysRevB.77.045129
120. Kepenekian, M.; Robles, R.; Katan, C.; Sapori, D.; Pedesseau, L.; Even, J. Rashba and Dresselhaus Effects in Hybrid Organic-Inorganic Perovskites: From Basics to Devices ACS Nano 2015, 9, 11557-11567 10.1021/acsnano.5b04409
121. Kim, M.; Im, J.; Freeman, A. J.; Ihm, J.; Jin, H. Switchable S = 1/2 and J = 1/2 Rashba Bands in Ferroelectric Halide Perovskites Proc. Natl. Acad. Sci. U. S. A. 2014, 111, 6900-6904 10.1073/pnas.1405780111
122. Even, J. Pedestrian Guide to Symmetry Properties of the Reference Cubic Structure of 3D All-Inorganic and Hybrid Perovskites J. Phys. Chem. Lett. 2015, 6, 2238-2242 10.1021/acs.jpclett.5b00905
123. Amat, A.; Mosconi, E.; Ronca, E.; Quarti, C.; Umari, P.; Nazeeruddin, M. K.; Grätzel, M.; De Angelis, F. Cation-Induced Band-Gap Tuning in Organohalide Perovskites: Interplay of Spin-Orbit Coupling and Octahedra Tilting Nano Lett. 2014, 14, 3608-3616 10.1021/nl5012992
124. Even, J.; Pedesseau, L.; Jancu, J. M.; Katan, C. DFT and k·p Modelling of the Phase Transitions of Lead and Tin Halide Perovskites for Photovoltaic Cells Phys. Status Solidi RRL 2014, 8, 31-35 10.1002/pssr.201308183
125. Stroppa, A.; Di Sante, D.; Barone, P.; Bokdam, M.; Kresse, G.; Franchini, C.; Whangbo, M.-H.; Picozzi, S. Tunable Ferroelectric Polarization and Its Interplay with Spin-orbit Coupling in Tin Iodide Perovskites Nat. Commun. 2014, 5, 5900 10.1038/ncomms6900
126. Umebayashi, T.; Asai, K.; Kondo, T.; Nakao, A. Electronic Structures of Lead Iodide Based Low-Dimensional Crystals Phys. Rev. B: Condens. Matter Mater. Phys. 2003, 67, 155405 10.1103/PhysRevB.67.155405
127. Brivio, F.; Walker, A. B.; Walsh, A. Structural and Electronic Properties of Hybrid Perovskites for High-Efficiency Thin-Film Photovoltaics from First-Principles APL Mater. 2013, 1, 042111 10.1063/1.4824147
128. 3 (X = Cl, Br, I) J. Korean Phys. Soc. 2004, 44, 889-893
129. Borriello, I.; Cantele, G.; Ninno, D. Ab Initio Investigation of Hybrid Organic-Inorganic Perovskites Based on Tin Halides Phys. Rev. B: Condens. Matter Mater. Phys. 2008, 77, 235214 10.1103/PhysRevB.77.235214
130. 2O Can. J. Chem. 1987, 65, 1042-1046 10.1139/v87-176
131. Matsuishi, K.; Ishihara, T.; Onari, S.; Chang, Y. H.; Park, C. H. Optical Properties and Structural Phase Transitions of Lead-Halide Based Inorganic-Organic 3D and 2D Perovskite Semiconductors under High Pressure Phys. Status Solidi B 2004, 241, 3328-3333 10.1002/pssb.200405229
132. Knutson, J. L.; Martin, J. D.; Mitzi, D. B. Tuning the Band Gap in Hybrid Tin Iodide Perovskite Semiconductors Using Structural Templating Inorg. Chem. 2005, 44, 4699-4705 10.1021/ic050244q
133. Stoumpos, C. C.; Frazer, L.; Clark, D. J.; Kim, Y. S.; Rhim, S. H.; Freeman, A. J.; Ketterson, J. B.; Jang, J. I.; Kanatzidis, M. G. Hybrid Germanium Iodide Perovskite Semiconductors: Active Lone Pairs, Structural Distortions, Direct and Indirect Energy Gaps, and Strong Nonlinear Optical Properties J. Am. Chem. Soc. 2015, 137, 6804-6819 10.1021/jacs.5b01025
134. 3 Nat. Commun. 2015, 6, 7026 10.1038/ncomms8026
135. Miyata, A.; Mitioglu, A.; Plochocka, P.; Portugall, O.; Wang, J. T.-W.; Stranks, S. D.; Snaith, H. J.; Nicholas, R. J. Direct Measurement of the Exciton Binding Energy and Effective Masses for Charge Carriers in Organic-Inorganic Tri-Halide Perovskites Nat. Phys. 2015, 11, 582-587 10.1038/nphys3357
136. 3: Evidence for a Doped Semiconductor J. Solid State Chem. 2013, 205, 39-43 10.1016/j.jssc.2013.07.008
137. 3 J. Solid State Chem. 1995, 114, 159-163 10.1006/jssc.1995.1023
138. 3 Science 2013, 342, 344-347 10.1126/science.1243167
139. Stranks, S. D.; Eperon, G. E.; Grancini, G.; Menelaou, C.; Alcocer, M. J. P.; Leijtens, T.; Herz, L. M.; Petrozza, A.; Snaith, H. J. Electron-Hole Diffusion Lengths Exceeding 1 Micrometer in an Organometal Trihalide Perovskite Absorber Science 2013, 342, 341-344 10.1126/science.1243982
140. Wen, X.; Ho-Baillie, A.; Huang, S.; Sheng, R.; Chen, S.; Ko, H.; Green, M. A. Mobile Charge-Induced Fluorescence Intermittency in Methylammonium Lead Bromide Perovskite Nano Lett. 2015, 15, 4644-4649 10.1021/acs.nanolett.5b01405
141. Edri, E.; Kirmayer, S.; Henning, A.; Mukhopadhyay, S.; Gartsman, K.; Rosenwaks, Y.; Hodes, G.; Cahen, D. Why Lead Methylammonium Tri-Iodide Perovskite-Based Solar Cells Require a Mesoporous Electron Transporting Scaffold (but Not Necessarily a Hole Conductor) Nano Lett. 2014, 14, 1000-1004 10.1021/nl404454h
142. x Perovskite Solar Cells Nat. Commun. 2014, 5, 3461 10.1038/ncomms4461
143. Samiee, M.; Konduri, S.; Ganapathy, B.; Kottokkaran, R.; Abbas, H. A.; Kitahara, A.; Joshi, P.; Zhang, L.; Noack, M.; Dalal, V. Defect Density and Dielectric Constant in Perovskite Solar Cells Appl. Phys. Lett. 2014, 105, 153502 10.1063/1.4897329
144. Lee, M. M.; Teuscher, J.; Miyasaka, T.; Murakami, T. N.; Snaith, H. J. Efficient Hybrid Solar Cells Based on Meso-Superstructured Organometal Halide Perovskites Science 2012, 338, 643-647 10.1126/science.1228604
145. Ke, W.; Fang, G.; Wan, J.; Tao, H.; Liu, Q.; Xiong, L.; Qin, P.; Wang, J.; Lei, H.; Yang, G. et al. Efficient Hole-Blocking Layer-Free Planar Halide Perovskite Thin-Film Solar Cells Nat. Commun. 2015, 6, 6700 10.1038/ncomms7700
146. Seo, J.; Park, S.; Chan Kim, Y.; Jeon, N. J.; Noh, J. H.; Yoon, S. C.; Seok, S. Il. Benefits of Very Thin PCBM and LiF Layers for Solution-Processed p-i-n Perovskite Solar Cells Energy Environ. Sci. 2014, 7, 2642-2646 10.1039/C4EE01216J
147. Yin, W.-J.; Yang, J.-H.; Kang, J.; Yan, Y.; Wei, S.-H. Halide Perovskite Materials for Solar Cells: A Theoretical Review J. Mater. Chem. A 2015, 3, 8926-8942 10.1039/C4TA05033A
148. Even, J.; Pedesseau, L.; Dupertuis, M.-A.; Jancu, J.-M.; Katan, C. Electronic Model for Self-Assembled Hybrid Organic/perovskite Semiconductors: Reverse Band Edge Electronic States Ordering and Spin-Orbit Coupling Phys. Rev. B: Condens. Matter Mater. Phys. 2012, 86, 205301 10.1103/PhysRevB.86.205301
149. Gray, A. X.; Papp, C.; Ueda, S.; Balke, B.; Yamashita, Y.; Plucinski, L.; Minár, J.; Braun, J.; Ylvisaker, E. R.; Schneider, C. M. et al. Probing Bulk Electronic Structure with Hard X-Ray Angle-Resolved Photoemission Nat. Mater. 2011, 10, 759-764 10.1038/nmat3089
150. Yan, Y.; Wang, Q.; Shu, W.; Jia, Z.; Ren, X.; Zhang, X.; Huang, Y. First-Principle Study of the Electronic and Optical Properties of BInGaAs Quaternary Alloy Lattice-Matched to GaAs Phys. B 2012, 407, 4570-4573 10.1016/j.physb.2012.08.021
151. Bardeen, J.; Shockley, W. Deformation Potentials and Mobilities in Non-Polar Crystals Phys. Rev. 1950, 80, 72-80 10.1103/PhysRev.80.72
152. Frost, J. M.; Butler, K. T.; Brivio, F.; Hendon, C. H.; van Schilfgaarde, M.; Walsh, A. Atomistic Origins of High-Performance in Hybrid Halide Perovskite Solar Cells Nano Lett. 2014, 14, 2584-2590 10.1021/nl500390f
153. 3 Stabilized with PMMA: A Modulated Surface Photovoltage Study J. Phys. Chem. C 2015, 119, 23968-23972 10.1021/acs.jpcc.5b07132
154. Maintz, S.; Deringer, V. L.; Tchougréeff, A. L.; Dronskowski, R. Analytic Projection from Plane-Wave and PAW Wavefunctions and Application to Chemical-Bonding Analysis in Solids J. Comput. Chem. 2013, 34, 2557-2567 10.1002/jcc.23424
155. 3 J. Appl. Phys. 2011, 110, 063526 10.1063/1.3638699
156. Walsh, A.; Payne, D. J.; Egdell, R. G.; Watson, G. W. Stereochemistry of Post-Transition Metal Oxides: Revision of the Classical Lone Pair Model Chem. Soc. Rev. 2011, 40, 4455-4463 10.1039/c1cs15098g
157. Pyykko, P. Relativistic Effects in Structural Chemistry Chem. Rev. 1988, 88, 563-594 10.1021/cr00085a006
158. Gillespie, R. J.; Nyholm, R. S. Inorganic Stereochemistry Q. Rev., Chem. Soc. 1957, 11, 339-380 10.1039/qr9571100339
159. 5 (M = Sn, Pb): Stereochemical Activity in Divalent Tin and Lead Halides Containing Single [110] Perovskite Sheets J. Am. Chem. Soc. 1995, 117, 5297-5302 10.1021/ja00124a012
160. 3 Acta Crystallogr., Sect. B: Struct. Sci. 2010, 66, 422-429 10.1107/S0108768110014734
161. Fütterer, K.; Depmeier, W.; Petříček, V. The Low-Temperature Phase Transition Sequence of the Halide Perovskite Tetramethylammonium Trichlorogermanate(II) and the Structure of Its Incommensurately Modulated δ-Phase Acta Crystallogr., Sect. B: Struct. Sci. 1995, 51, 768-779 10.1107/S0108768194013303
162. 35Cl NMR Solid State Ionics 1995, 79, 152-157 10.1016/0167-2738(95)00055-B
163. Winkler, B.; Milman, V.; Lee, M.-H. Pressure-Induced Change of the Stereochemical Activity of a Lone Electron Pair J. Chem. Phys. 1998, 108, 5506-5509 10.1063/1.475939
164. 3 Acta Chem. Scand. 1965, 19, 421-428 10.3891/acta.chem.scand.19-0421
165. Papavassiliou, G. C.; Koutselas, I. B. Structural, Optical and Related Properties of Some Natural Three- and Lower-Dimensional Semiconductor Systems Synth. Met. 1995, 71, 1713-1714 10.1016/0379-6779(94)03017-Z
166. Mosconi, E.; Amat, A.; Nazeeruddin, K.; Angelis, F. De; Nazeeruddin, M. K.; Grätzel, M.; De Angelis, F. First-Principles Modeling of Mixed Halide Organometal Perovskites for Photovoltaic Applications J. Phys. Chem. C 2013, 117, 13902-13913 10.1021/jp4048659
167. 3 Perovskite upon Controlled Exposure to Humidified Air J. Am. Chem. Soc. 2015, 137, 1530-1538 10.1021/ja511132a
168. Hong, X.; Ishihara, T.; Nurmikko, A. V. Photoconductivity and Electroluminescence in Lead Iodide Based Natural Quantum Well Structures Solid State Commun. 1992, 84, 657-661 10.1016/0038-1098(92)90210-Z
169. Sichert, J. A.; Tong, Y.; Mutz, N.; Vollmer, M.; Fischer, S.; Milowska, K. Z.; García Cortadella, R.; Nickel, B.; Cardenas-Daw, C.; Stolarczyk, J. K. et al. Quantum Size Effect in Organometal Halide Perovskite Nanoplatelets Nano Lett. 2015, 15, 6521-6527 10.1021/acs.nanolett.5b02985
170. Papavassiliou, G. C. Three- and Low-Dimensional Inorganic Semiconductors Prog. Solid State Chem. 1997, 25, 125-270 10.1016/S0079-6786(97)80886-2
171. Kikuchi, K.; Takeoka, Y.; Rikukawa, M.; Sanui, K. Structure and Optical Properties of Lead Iodide Based Two-Dimensional Perovskite Compounds Containing Fluorophenethylamines Curr. Appl. Phys. 2004, 4, 599-602 10.1016/j.cap.2004.01.027
172. 4] Nanomaterial J. Phys. Chem. C 2009, 113, 19305-19309 10.1021/jp9057934
173. Wulfsberg, G. Inorganic Chemistry; University Science Books: Sausalito, 2000.
174. Ehrenreich, H. Band Structure and Transport Properties of Some 3-5 Compounds J. Appl. Phys. 1961, 32, 2155-2166 10.1063/1.1777035
175. 3 Solid State Commun. 2003, 127, 619-623 10.1016/S0038-1098(03)00566-0
176. Even, J.; Pedesseau, L.; Jancu, J.-M.; Katan, C. Importance of Spin-orbit Coupling in Hybrid Organic/inorganic Perovskites for Photovoltaic Applications J. Phys. Chem. Lett. 2013, 4, 2999-3005 10.1021/jz401532q
177. Galkowski, K.; Mitioglu, A.; Miyata, A.; Plochocka, P.; Portugall, O.; Eperon, G. E.; Wang, J. T.-W.; Stergiopoulos, T.; Stranks, S. D.; Snaith, H. J. et al. Determination of the Exciton Binding Energy and Effective Masses for Methylammonium and Formamidinium Lead Tri-Halide Perovskite Semiconductors Energy Environ. Sci. 2016, 9, 962-970 10.1039/C5EE03435C
178. Glazer, A. M. The Classification of Tilted Octahedra in Perovskites Acta Crystallogr., Sect. B: Struct. Crystallogr. Cryst. Chem. 1972, 28, 3384-3392 10.1107/S0567740872007976
179. Weller, M. T.; Weber, O. J.; Henry, P. F.; Di Pumpo, A. M.; Hansen, T. C. Complete Structure and Cation Orientation in the Perovskite Photovoltaic Methylammonium Lead Iodide between 100 and 352 K Chem. Commun. 2015, 51, 4180-4183 10.1039/C4CC09944C
180. 3 (X = Cl, Br, I) J. Phys. Chem. Solids 1992, 53, 935-939 10.1016/0022-3697(92)90121-S
181. Wehrenfennig, C.; Liu, M.; Snaith, H. J.; Johnston, M. B.; Herz, L. M. Charge Carrier Recombination Channels in the Low-Temperature Phase of Organic-Inorganic Lead Halide Perovskite Thin Films APL Mater. 2014, 2, 081513 10.1063/1.4891595
182. D'Innocenzo, V.; Grancini, G.; Alcocer, M. J. P.; Kandada, A. R. S.; Stranks, S. D.; Lee, M. M.; Lanzani, G.; Snaith, H. J.; Petrozza, A. Excitons versus Free Charges in Organo-Lead Tri-Halide Perovskites Nat. Commun. 2014, 5, 3586 10.1038/ncomms4586
183. Sestu, N.; Cadelano, M.; Sarritzu, V.; Chen, F.; Marongiu, D.; Piras, R.; Mainas, M.; Quochi, F.; Saba, M.; Mura, A. et al. Absorption F-Sum Rule for the Exciton Binding Energy in Methylammonium Lead Halide Perovskites J. Phys. Chem. Lett. 2015, 6, 4566-4572 10.1021/acs.jpclett.5b02099
184. Onoda-Yamamuro, N.; Matsuo, T.; Suga, H. Calorimetric and IR Spectroscopic Studies of Phase Transitions in Methylammonium Trihalogenoplumbates (II) J. Phys. Chem. Solids 1990, 51, 1383-1395 10.1016/0022-3697(90)90021-7
185. Leguy, A. M. A.; Frost, J. M.; McMahon, A. P.; Sakai, V. G.; Kochelmann, W.; Law, C.; Li, X.; Foglia, F.; Walsh, A.; O'Regan, B. C. et al. The Dynamics of Methylammonium Ions in Hybrid organic-Inorganic Perovskite Solar Cells Nat. Commun. 2015, 6, 7124 10.1038/ncomms8124
186. Poglitsch, A.; Weber, D. Dynamic Disorder in Methylammoniumtrihalogenoplumbates (II) Observed by Millimeter-Wave Spectroscopy J. Chem. Phys. 1987, 87, 6373-6378 10.1063/1.453467
187. Bakulin, A. A.; Selig, O.; Bakker, H. J.; Rezus, Y. L. A.; Müller, C.; Glaser, T.; Lovrincic, R.; Sun, Z.; Chen, Z.; Walsh, A. et al. Real-Time Observation of Organic Cation Reorientation in Methylammonium Lead Iodide Perovskites J. Phys. Chem. Lett. 2015, 6, 3663-3669 10.1021/acs.jpclett.5b01555
188. Even, J.; Pedesseau, L.; Katan, C. Analysis of Multivalley and Multibandgap Absorption and Enhancement of Free Carriers Related to Exciton Screening in Hybrid Perovskites J. Phys. Chem. C 2014, 118, 11566-11572 10.1021/jp503337a
189. Kim, H.-S.; Im, S. H.; Park, N. Organolead Halide Perovskite: New Horizons in Solar Cell Research J. Phys. Chem. C 2014, 118, 5615-5625 10.1021/jp409025w
190. 3 Phys. B 1994, 201, 427-430 10.1016/0921-4526(94)91130-4
191. Yin, W.-J.; Shi, T.; Yan, Y. Unique Properties of Halide Perovskites as Possible Origins of the Superior Solar Cell Performance Adv. Mater. 2014, 26, 4653-4658 10.1002/adma.201306281
192. 3 Phys. Rev. Appl. 2016, 5, 014012 10.1103/PhysRevApplied.5.014012
193. Sun, S.; Salim, T.; Mathews, N.; Duchamp, M.; Boothroyd, C.; Xing, G.; Sum, T. C.; Lam, Y. M. The Origin of High Efficiency in Low-Temperature Solution-Processable Bilayer Organometal Halide Hybrid Solar Cells Energy Environ. Sci. 2014, 7, 399-407 10.1039/C3EE43161D
194. Ball, J. M.; Stranks, S. D.; Hörantner, M. T.; Hüttner, S.; Zhang, W.; Crossland, E. J. W.; Ramirez, I.; Riede, M.; Johnston, M. B.; Friend, R. H. et al. Optical Properties and Limiting Photocurrent of Thin-Film Perovskite Solar Cells Energy Environ. Sci. 2015, 8, 602-609 10.1039/C4EE03224A
195. 3 Perovskite Thin Films Determined by Spectroscopic Ellipsometry and Spectrophotometry J. Phys. Chem. Lett. 2015, 6, 66-71 10.1021/jz502471h
196. Lin, Q.; Armin, A.; Nagiri, R. C. R.; Burn, P. L.; Meredith, P. Electro-Optics of Perovskite Solar Cells Nat. Photonics 2014, 9, 106-112 10.1038/nphoton.2014.284
197. 3 Perovskite Single Crystal J. Phys. Chem. Lett. 2015, 6, 4304-4308 10.1021/acs.jpclett.5b01699
198. Casey, H. C.; Sell, D. D.; Wecht, K. W. Concentration Dependence of the Absorption Coefficient for n- and p-type GaAs between 1.3 and 1.6 eV J. Appl. Phys. 1975, 46, 250 10.1063/1.321330
199. 3 in Films, Single Crystals and Solar Cells Chem. Mater. 2015, 27, 3397-3407 10.1021/acs.chemmater.5b00660
200. Manser, J. S.; Saidaminov, M. I.; Christians, J. A.; Bakr, O. M.; Kamat, P. V. Making and Breaking of Lead Halide Perovskites Acc. Chem. Res. 2016, 49, 330-338 10.1021/acs.accounts.5b00455
201. Mosconi, E.; Azpiroz, J. M.; De Angelis, F. Ab Initio Molecular Dynamics Simulations of Methylammonium Lead Iodide Perovskite Degradation by Water Chem. Mater. 2015, 27, 4885-4892 10.1021/acs.chemmater.5b01991
202. Urbach, F. The Long-Wavelength Edge of Photographic Sensitivity and of the Electronic Absorption of Solids Phys. Rev. 1953, 92, 1324 10.1103/PhysRev.92.1324
203. 3 with Sharp Optical Band Edges J. Phys. Chem. Lett. 2014, 5, 2501-2505 10.1021/jz501332v
204. De Wolf, S.; Holovsky, J.; Moon, S.-J.; Löper, P.; Niesen, B.; Ledinsky, M.; Haug, F.-J.; Yum, J.-H.; Ballif, C. Organometallic Halide Perovskites: Sharp Optical Absorption Edge and Its Relation to Photovoltaic Performance J. Phys. Chem. Lett. 2014, 5, 1035-1039 10.1021/jz500279b
205. Eperon, G. E.; Stranks, S. D.; Menelaou, C.; Johnston, M. B.; Herz, L. M.; Snaith, H. J. Formamidinium Lead Trihalide: A Broadly Tunable Perovskite for Efficient Planar Heterojunction Solar Cells Energy Environ. Sci. 2014, 7, 982-988 10.1039/c3ee43822h
206. Rau, U. Reciprocity Relation between Photovoltaic Quantum Efficiency and Electroluminescent Emission of Solar Cells Phys. Rev. B: Condens. Matter Mater. Phys. 2007, 76, 085303 10.1103/PhysRevB.76.085303
207. Tvingstedt, K.; Malinkiewicz, O.; Baumann, A.; Deibel, C.; Snaith, H. J.; Dyakonov, V.; Bolink, H. J. Radiative Efficiency of Lead Iodide Based Perovskite Solar Cells Sci. Rep. 2014, 4, 6071 10.1038/srep06071
208. Sutter-Fella, C. M.; Li, Y.; Amani, M.; Ager, J. W.; Toma, F. M.; Yablonovitch, E.; Sharp, I. D.; Javey, A. High Photoluminescence Quantum Yield in Band Gap Tunable Bromide Containing Mixed Halide Perovskites Nano Lett. 2016, 16, 800-806 10.1021/acs.nanolett.5b04884
209. Miller, O. D.; Yablonovitch, E.; Kurtz, S. R. Strong Internal and External Luminescence as Solar Cells Approach the Shockley-Queisser Limit IEEE J. Photovoltaics 2012, 2, 303-311 10.1109/JPHOTOV.2012.2198434
210. Coutts, T. J.; Emery, K. A.; Ward, J. S. Modeled Performance of Polycrystalline Thin-Film Tandem Solar Cells Prog. Photovoltaics 2002, 10, 195-203 10.1002/pip.419
211. Hoke, E. T.; Slotcavage, D. J.; Dohner, E. R.; Bowring, A. R.; Karunadasa, H. I.; McGehee, M. D. Reversible Photo-Induced Trap Formation in Mixed-Halide Hybrid Perovskites for Photovoltaics Chem. Sci. 2015, 6, 613-617 10.1039/C4SC03141E
212. Rehman, W.; Milot, R. L.; Eperon, G. E.; Wehrenfennig, C.; Boland, J. L.; Snaith, H. J.; Johnston, M. B.; Herz, L. M. Charge-Carrier Dynamics and Mobilities in Formamidinium Lead Mixed-Halide Perovskites Adv. Mater. 2015, 27, 7938-7944 10.1002/adma.201502969
213. Shimizu, M.; Fujisawa, J.-I.; Ishi-Hayase, J. Influence of Dielectric Confinement on Excitonic Nonlinearity in Inorganic-Organic Layered Semiconductors Phys. Rev. B: Condens. Matter Mater. Phys. 2005, 71, 205306 10.1103/PhysRevB.71.205306
214. 4 (n = 1-4) J. Phys. Chem. Solids 2010, 71, 797-802 10.1016/j.jpcs.2010.02.006
215. Kitazawa, N.; Yaemponga, D.; Aono, M.; Watanabe, Y. Optical Properties of Organic-Inorganic Hybrid Films Prepared by the Two-Step Growth Process J. Lumin. 2009, 129, 1036-1041 10.1016/j.jlumin.2009.04.023
216. 4 Japanese J. Appl. Physics, Part 1 Regul. Pap. Short Notes Rev. Pap. 2005, 44, 5923-5932 10.1143/JJAP.44.5923
217. 4 Phys. Rev. B: Condens. Matter Mater. Phys. 2006, 73, 115206 10.1103/PhysRevB.73.115206
218. 4 (n = 4, 5, 7, 8 and 9) J. Phys. Chem. Solids 2011, 72, 1467-1471 10.1016/j.jpcs.2011.08.029
219. 4 Perovskite Opt. Express 2010, 18, 5912-5919 10.1364/OE.18.005912
220. Dou, L.; Wong, A. B.; Yu, Y.; Lai, M.; Kornienko, N.; Ginsberg, N. S.; Wang, L.; Alivisatos, A. P.; Yang, P.; Eaton, S. W. et al. Atomically Thin Two-Dimensional Organic-Inorganic Hybrid Perovskites Science 2015, 349, 1518-1521 10.1126/science.aac7660
221. 4 Solid State Commun. 1998, 105, 253-255 10.1016/S0038-1098(97)10085-0
222. Tanaka, K.; Kondo, T. Bandgap and Exciton Binding Energies in Lead-Iodide-Based Natural Quantum-Well Crystals Sci. Technol. Adv. Mater. 2003, 4, 599-604 10.1016/j.stam.2003.09.019
223. Weisbuch, C.; Benisty, H. Microcavities in Ecole Polytechnique Fédérale de Lausanne, Ecole Polytechnique (France) and Elsewhere: Past, Present and Future Phys. Status Solidi B 2005, 242, 2345-2356 10.1002/pssb.200560972
224. Saba, M.; Cadelano, M.; Marongiu, D.; Chen, F.; Sarritzu, V.; Sestu, N.; Figus, C.; Aresti, M.; Piras, R.; Geddo Lehmann, A. et al. Correlated Electron-hole Plasma in Organometal Perovskites Nat. Commun. 2014, 5, 5049 10.1038/ncomms6049
225. Draguta, S.; Thakur, S.; Morozov, Y. V.; Wang, Y.; Manser, J. S.; Kamat, P. V.; Kuno, M. Spatially Non-Uniform Trap State Densities in Solution-Processed Hybrid Perovskite Thin Films J. Phys. Chem. Lett. 2016, 7, 715-721 10.1021/acs.jpclett.5b02888
226. Tian, Y.; Merdasa, A.; Unger, E.; Abdellah, M.; Zheng, K.; McKibbin, S.; Mikkelsen, A.; Pullerits, T.; Yartsev, A.; Sundström, V. et al. Enhanced Organo-Metal Halide Perovskite Photoluminescence from Nanosized Defect-Free Crystallites and Emitting Sites J. Phys. Chem. Lett. 2015, 6, 4171-4177 10.1021/acs.jpclett.5b02033
227. 3 for Solar Cell Applications J. Am. Chem. Soc. 2014, 136, 11610-11613 10.1021/ja506624n
228. Chung, I.; Song, J. H.; Im, J.; Androulakis, J.; Malliakas, C. D.; Li, H.; Freeman, A. J.; Kenney, J. T.; Kanatzidis, M. G. CsSnI3: Semiconductor or Metal? High Electrical Conductivity and Strong Near-Infrared Photoluminescence from a Single Material. High Hole Mobility and Phase-Transitions J. Am. Chem. Soc. 2012, 134, 8579-8587 10.1021/ja301539s
229. 3 Perovskite Thin Films Adv. Funct. Mater. 2015, 25, 6218-6227 10.1002/adfm.201502340
230. Wu, X.; Trinh, M. T.; Niesner, D.; Zhu, H.; Norman, Z.; Owen, J. S.; Yaffe, O.; Kudisch, B. J.; Zhu, X.-Y. Trap States in Lead Iodide Perovskites J. Am. Chem. Soc. 2015, 137, 2089-2096 10.1021/ja512833n
231. Fang, H.-H.; Raissa, R.; Abdu-Aguye, M.; Adjokatse, S.; Blake, G. R.; Even, J.; Loi, M. A. Photophysics of Organic-Inorganic Hybrid Lead Iodide Perovskite Single Crystals Adv. Funct. Mater. 2015, 25, 2378-2385 10.1002/adfm.201404421
232. Saba, M.; Quochi, F.; Mura, A.; Bongiovanni, G. Excited State Properties of Hybrid Perovskites Acc. Chem. Res. 2016, 49, 166-173 10.1021/acs.accounts.5b00445
233. Elliott, R. J. Intensity of Optical Absorption by Excitons Phys. Rev. 1957, 108, 1384-1389 10.1103/PhysRev.108.1384
234. Sturge, M. D. Optical Absorption of Gallium Arsenide between 0.6 and 2.75 eV Phys. Rev. 1962, 127, 768-773 10.1103/PhysRev.127.768
235. x J. Phys. Chem. Lett. 2014, 5, 1300-1306 10.1021/jz500434p
236. Manser, J. S.; Kamat, P. V. Band Filling with Free Charge Carriers in Organometal Halide Perovskites Nat. Photonics 2014, 8, 737-743 10.1038/nphoton.2014.171
237. Kira, M.; Jahnke, F.; Koch, S. Microscopic Theory of Excitonic Signatures in Semiconductor Photoluminescence Phys. Rev. Lett. 1998, 81, 3263-3266 10.1103/PhysRevLett.81.3263
238. Koch, S. W.; Kira, M.; Khitrova, G.; Gibbs, H. M. Semiconductor Excitons in New Light Nat. Mater. 2006, 5, 523-531 10.1038/nmat1658
239. 4- Octahedra J. Phys. Soc. Jpn. 1994, 63, 3870-3879 10.1143/JPSJ.63.3870
240. Ishihara, T. Optical Properties of PbI-Based Perovskite Structures J. Lumin. 1994, 60-61, 269-274 10.1016/0022-2313(94)90145-7
241. Liu, M.; Johnston, M. B.; Snaith, H. J. Efficient Planar Heterojunction Perovskite Solar Cells by Vapour Deposition Nature 2013, 501, 395-398 10.1038/nature12509
242. Wannier, G. H. The Structure of Electronic Excitation Levels in Insulating Crystals Phys. Rev. 1937, 52, 191-197 10.1103/PhysRev.52.191
243. Yang, W.; Yao, Y.; Wu, C.-Q. Origin of the High Open Circuit Voltage in Planar Heterojunction Perovskite Solar Cells: Role of the Reduced Bimolecular Recombination J. Appl. Phys. 2015, 117, 095502 10.1063/1.4913519
244. Johnston, M. B.; Herz, L. M. Hybrid Perovskites for Photovoltaics: Charge-Carrier Recombination, Diffusion, and Radiative Efficiencies Acc. Chem. Res. 2016, 49, 146-154 10.1021/acs.accounts.5b00411
245. 3 Solar Cells Studied by Photoluminescence and Photoabsorption Spectroscopy IEEE J. Photovoltaics 2015, 5, 401-405 10.1109/JPHOTOV.2014.2364115
246. Wu, K.; Bera, A.; Ma, C.; Du, Y.; Yang, Y.; Li, L.; Wu, T. Temperature-Dependent Excitonic Photoluminescence of Hybrid Organometal Halide Perovskite Films Phys. Chem. Chem. Phys. 2014, 16, 22476-22481 10.1039/C4CP03573A
247. 3 Thin Films: Determination of Exciton Binding Energy J. Lumin. 2012, 132, 345-349 10.1016/j.jlumin.2011.09.006
248. 3 Phys. Status Solidi RRL 2015, 9, 559-563 10.1002/pssr.201510265
249. Zhu, X.-Y.; Podzorov, V. Charge Carriers in Hybrid Organic-Inorganic Lead Halide Perovskites Might Be Protected as Large Polarons J. Phys. Chem. Lett. 2015, 6, 4758-4761 10.1021/acs.jpclett.5b02462
250. 3 Perovskite-Based Photovoltaic Devices Appl. Phys. Lett. 2015, 106, 173502 10.1063/1.4919109
251. Schmitt-Rink, S.; Chemla, D. S.; Miller, D. A. B. Theory of Transient Excitonic Optical Nonlinearities in Semiconductor Quantum-Well Structures Phys. Rev. B: Condens. Matter Mater. Phys. 1985, 32, 6601-6609 10.1103/PhysRevB.32.6601
252. 3 Hybrid Perovskite: Interplay of Theory and Experiment J. Phys. Chem. Lett. 2014, 5, 279-284 10.1021/jz402589q
253. Tanaka, K.; Takahashi, T.; Kondo, T.; Umebayashi, T.; Asai, K.; Ema, K. Image Charge Effect on Two-Dimensional Excitons in an Inorganic-Organic Quantum-Well Crystal Phys. Rev. B: Condens. Matter Mater. Phys. 2005, 71, 045312 10.1103/PhysRevB.71.045312
254. Saha, M. N. On a Physical Theory of Stellar Spectra Proc. R. Soc. London, Ser. A 1921, 99, 135-153 10.1098/rspa.1921.0029
255. Grancini, G.; Srimath Kandada, A. R.; Frost, J. M.; Barker, A. J.; De Bastiani, M.; Gandini, M.; Marras, S.; Lanzani, G.; Walsh, A.; Petrozza, A. Role of Microstructure in the Electron-Hole Interaction of Hybrid Lead Halide Perovskites Nat. Photonics 2015, 9, 695-701 10.1038/nphoton.2015.151
256. 3 Energy Environ. Sci. 2015, 8, 3700-3707 10.1039/C5EE02503F
257. Stranks, S. D.; Burlakov, V. M.; Leijtens, T.; Ball, J. M.; Goriely, A.; Snaith, H. J. Recombination Kinetics in Organic-Inorganic Perovskites: Excitons, Free Charge, and Subgap States Phys. Rev. Appl. 2014, 2, 034007 10.1103/PhysRevApplied.2.034007
258. de Quilettes, D. W.; Vorpahl, S. M.; Stranks, S. D.; Nagaoka, H.; Eperon, G. E.; Ziffer, M. E.; Snaith, H. J.; Ginger, D. S. Impact of Microstructure on Local Carrier Lifetime in Perovskite Solar Cells Science 2015, 348, 683-686 10.1126/science.aaa5333
259. Cingolani, R.; Calcagnile, L.; Colĺ, G.; Rinaldi, R.; Lomoscolo, M.; DiDio, M.; Franciosi, A.; Vanzetti, L.; LaRocca, G. C.; Campi, D. Radiative Recombination Processes in Wide-Band-Gap II-VI Quantum Wells: The Interplay between Excitons and Free Carriers J. Opt. Soc. Am. B 1996, 13, 1268 10.1364/JOSAB.13.001268
260. Price, M. B.; Butkus, J.; Jellicoe, T. C.; Sadhanala, A.; Briane, A.; Halpert, J. E.; Broch, K.; Hodgkiss, J. M.; Friend, R. H.; Deschler, F. Hot-Carrier Cooling and Photoinduced Refractive Index Changes in Organic-inorganic Lead Halide Perovskites Nat. Commun. 2015, 6, 8420 10.1038/ncomms9420
261. Zimmermann, R. Nonlinear Optics and the Mott Transition in Semiconductors Phys. Status Solidi B 1988, 146, 371-384 10.1002/pssb.2221460140
262. Mott, N. F. Metal-Insulator Transition Rev. Mod. Phys. 1968, 40, 677-683 10.1103/RevModPhys.40.677
263. Schweizer, H.; Forchel, A.; Hangleiter, A.; Schmitt-Rink, S.; Löwenau, J.; Haug, H. Ionization of the Direct-Gap Exciton in Photoexcited Germanium Phys. Rev. Lett. 1983, 51, 698-701 10.1103/PhysRevLett.51.698
264. Haug, H.; Schmitt-Rink, S. Basic Mechanisms of the Optical Nonlinearities of Semiconductors Near the Band Edge J. Opt. Soc. Am. B 1985, 2, 1135-1142 10.1364/JOSAB.2.001135
265. Thomas, G. A.; Rice, T. M. Trions, Molecules and Excitons above the Mott Density in Ge Solid State Commun. 1977, 23, 359-363 10.1016/0038-1098(77)90232-0
266. Shah, J.; Leheny, R. F.; Lin, C. Dynamic Burstein Shift in GaAs Solid State Commun. 1976, 18, 1035-1037 10.1016/0038-1098(76)91233-3
267. Shah, J.; Combescot, M.; Dayem, A. H. Investigation of Exciton-Plasma Mott Transition in Si Phys. Rev. Lett. 1977, 38, 1497-1500 10.1103/PhysRevLett.38.1497
268. Hoyer, W.; Kira, M.; Koch, S. W. Influence of Coulomb and Phonon Interaction on the Exciton Formation Dynamics in Semiconductor Heterostructures Phys. Rev. B: Condens. Matter Mater. Phys. 2003, 67, 155113 10.1103/PhysRevB.67.155113
269. Sum, T. C.; Mathews, N.; Xing, G.; Lim, S. S.; Chong, W. K.; Giovanni, D.; Dewi, H. A. Spectral Features and Charge Dynamics of Lead Halide Perovskites: Origins and Interpretations Acc. Chem. Res. 2016, 49, 294-302 10.1021/acs.accounts.5b00433
270. Srimath Kandada, A. R.; Petrozza, A. Photophysics of Hybrid Lead Halide Perovskites: The Role of Microstructure Acc. Chem. Res. 2016, 49, 536-544 10.1021/acs.accounts.5b00464
271. 3. Charge Separation, Recombination, and Trapping J. Phys. Chem. Lett. 2015, 6, 2086-2095 10.1021/acs.jpclett.5b00594
272. Sheng, C.; Zhang, C.; Zhai, Y.; Mielczarek, K.; Wang, W.; Ma, W.; Zakhidov, A.; Vardeny, Z. V. Exciton versus Free Carrier Photogeneration in Organometal Trihalide Perovskites Probed by Broadband Ultrafast Polarization Memory Dynamics Phys. Rev. Lett. 2015, 114, 116601 10.1103/PhysRevLett.114.116601
273. 2 J. Am. Chem. Soc. 2014, 136, 12205-12208 10.1021/ja504632z
274. Stamplecoskie, K. G.; Manser, J. S.; Kamat, P. V. Dual Nature of the Excited State in Organic-Inorganic Lead Halide Perovskites Energy Environ. Sci. 2015, 8, 208-215 10.1039/C4EE02988G
275. Manser, J. S.; Reid, B.; Kamat, P. V. Evolution of Organic-Inorganic Lead Halide Perovskite from Solid-State Iodoplumbate Complexes J. Phys. Chem. C 2015, 119, 17065-17073 10.1021/acs.jpcc.5b05898
276. Zhai, Y.; Sheng, C. X.; Zhang, C.; Vardeny, Z. V. Ultrafast Spectroscopy of Photoexcitations in Organometal Trihalide Perovskites Adv. Funct. Mater. 2016, 26, 1617-1627 10.1002/adfm.201505115
277. Burstein, E. Anomalous Optical Absorption Limit in InSb Phys. Rev. 1954, 93, 632-633 10.1103/PhysRev.93.632
278. Moss, T. S. The Interpretation of the Properties of Indium Antimonide Proc. Phys. Soc., London, Sect. B 1954, 67, 775-782 10.1088/0370-1301/67/10/306
279. Miller, A.; Miller, D. A. B.; Smith, S. D. Dynamic Non-Linear Optical Processes in Semiconductors Adv. Phys. 1981, 30, 697-800 10.1080/00018738100101437
280. Kamat, P. V.; Dimitrijevic, N. M.; Nozik, A. J. Dynamic Burstein-Moss Shift in Semiconductor Colloids J. Phys. Chem. 1989, 93, 2873-2875 10.1021/j100345a003
281. Puthussery, J.; Lan, A.; Kosel, T. H.; Kuno, M. Band-Filling of Solution-Synthesized CdS Nanowires ACS Nano 2008, 2, 357-367 10.1021/nn700270a
282. Zimmermann, R.; Kilimann, K.; Kraeft, W. D.; Kremp, D.; Röpke, G. Dynamical Screening and Self-Energy of Excitons in the electron-Hole Plasma Phys. Status Solidi B 1978, 90, 175-187 10.1002/pssb.2220900119
283. Chen, K.; Barker, A. J.; Morgan, F. L. C.; Halpert, J. E.; Hodgkiss, J. M. Effect of Carrier Thermalization Dynamics on Light Emission and Amplification in Organometal Halide Perovskites J. Phys. Chem. Lett. 2015, 6, 153-158 10.1021/jz502528c
284. Trinh, M. T.; Wu, X.; Niesner, D.; Zhu, X. Many-Body Interactions in Photo-Excited Lead Iodide Perovskite J. Mater. Chem. A 2015, 3, 9285-9290 10.1039/C5TA01093D
285. Huang, D.; Chyi, J.-I.; Morkoç, H. Carrier Effects on the Excitonic Absorption in GaAs Quantum-Well Structures: Phase-Space Filling Phys. Rev. B: Condens. Matter Mater. Phys. 1990, 42, 5147-5153 10.1103/PhysRevB.42.5147
286. Je, K.-C.; Choi, M.; Yim, S.-Y.; Ahn, J.; Park, S.-H. Separation of Screened Coulomb Interaction and Phase-Space Filling in Exciton Bleaching of Multiple Quantum Wells Phys. Rev. B: Condens. Matter Mater. Phys. 2002, 66, 155312 10.1103/PhysRevB.66.155312
287. Meier, T.; Koch, S. Excitons versus Unbound Electron-Hole Pairs and Their Influence on Exciton Bleaching: A Model Study Phys. Rev. B: Condens. Matter Mater. Phys. 1999, 59, 13202-13208 10.1103/PhysRevB.59.13202
288. Ulbricht, R.; Hendry, E.; Shan, J.; Heinz, T. F.; Bonn, M. Carrier Dynamics in Semiconductors Studied with Time-Resolved Terahertz Spectroscopy Rev. Mod. Phys. 2011, 83, 543-586 10.1103/RevModPhys.83.543
289. Ponseca, C. S., Jr.; Sundström, V. Revealing the Ultrafast Charge Carrier Dynamics in Organo Metal Halide Perovskite Solar Cell Materials Using Time Resolved THz Spectroscopy Nanoscale 2016, 8, 6249-6257 10.1039/C5NR08622A
290. 3 Perovskite Films Nat. Commun. 2015, 6, 7903 10.1038/ncomms8903
291. 2 Nanoparticles: Interplay of Free and Shallowly Trapped Electrons J. Phys. Chem. C 2014, 118, 22561-22572 10.1021/jp505214d
292. Ulbricht, R.; Hendry, E.; Shan, J.; Heinz, T. F.; Bonn, M. Carrier Dynamics in Semiconductors Studied with Time-Resolved Terahertz Spectroscopy Rev. Mod. Phys. 2011, 83, 543-586 10.1103/RevModPhys.83.543
293. Ponseca, C. S.; Savenije, T. J.; Abdellah, M.; Zheng, K.; Yartsev, A.; Pascher, T.; Harlang, T.; Chabera, P.; Pullerits, T.; Stepanov, A. et al. Organometal Halide Perovskite Solar Cell Materials Rationalized: Ultrafast Charge Generation, High and Microsecond-Long Balanced Mobilities, and Slow Recombination J. Am. Chem. Soc. 2014, 136, 5189-5192 10.1021/ja412583t
294. x Energy Environ. Sci. 2014, 7, 2269-2275 10.1039/c4ee01358a
295. Guo, Z.; Manser, J. S.; Wan, Y.; Kamat, P. V.; Huang, L. Spatial and Temporal Imaging of Long-Range Charge Transport in Perovskite Thin Films by Ultrafast Microscopy Nat. Commun. 2015, 6, 7471 10.1038/ncomms8471
296. Simpson, M. J.; Doughty, B.; Yang, B.; Xiao, K.; Ma, Y.-Z. Spatial Localization of Excitons and Charge Carriers in Hybrid Perovskite Thin Films J. Phys. Chem. Lett. 2015, 6, 3041-3047 10.1021/acs.jpclett.5b01050
297. 3 Perovskite Films: Influence of Exciton Binding Energy J. Phys. Chem. Lett. 2015, 6, 4688-4692 10.1021/acs.jpclett.5b02290
298. x Films Chem. Commun. 2014, 50, 11727-11730 10.1039/C4CC04973J
299. De Bastiani, M.; D'Innocenzo, V.; Stranks, S. D.; Snaith, H. J.; Petrozza, A.; Bastiani, M. De; Innocenzo, V. D. Role of the Crystallization Substrate on the Photoluminescence Properties of Organo-Lead Mixed Halides Perovskites APL Mater. 2014, 2, 081509 10.1063/1.4889845
300. Wehrenfennig, C.; Eperon, G. E.; Johnston, M. B.; Snaith, H. J.; Herz, L. M. High Charge Carrier Mobilities and Lifetimes in Organolead Trihalide Perovskites Adv. Mater. 2014, 26, 1584-1589 10.1002/adma.201305172
301. Noel, N. K.; Abate, A.; Stranks, S. D.; Parrott, E. S.; Burlakov, V. M.; Goriely, A.; Snaith, H. J. Enhanced Photoluminescence and Solar Cell Performance via Lewis Base Passivation of Organic-Inorganic Lead Halide Perovskites ACS Nano 2014, 8, 9815-9821 10.1021/nn5036476
302. You, J.; Hong, Z.; Yang, Y. M.; Chen, Q.; Cai, M.; Song, T.; Chen, C.; Lu, S.; Liu, Y.; Zhou, H. et al. Low-Temperature Solution-Processed Perovskite Solar Cells with High Efficiency and Flexibility ACS Nano 2014, 8, 1674-1680 10.1021/nn406020d
303. Liang, P. W.; Liao, C. Y.; Chueh, C. C.; Zuo, F.; Williams, S. T.; Xin, X. K.; Lin, J.; Jen, A. K. Y. Additive Enhanced Crystallization of Solution-Processed Perovskite for Highly Efficient Planar-Heterojunction Solar Cells Adv. Mater. 2014, 26, 3748-3754 10.1002/adma.201400231
304. Ponseca, C. S.; Hutter, E. M.; Piatkowski, P.; Cohen, B.; Pascher, T.; Douhal, A.; Yartsev, A.; Sundström, V.; Savenije, T. J. Mechanism of Charge Transfer and Recombination Dynamics in Organo Metal Halide Perovskites and Organic Electrodes, PCBM, and Spiro-OMeTAD: Role of Dark Carriers J. Am. Chem. Soc. 2015, 137, 16043-16048 10.1021/jacs.5b08770
305. Noel, N. K.; Stranks, S. D.; Abate, A.; Wehrenfennig, C.; Guarnera, S.; Haghighirad, A.-A.; Sadhanala, A.; Eperon, G. E.; Pathak, S. K.; Johnston, M. B. et al. Lead-Free Organic-Inorganic Tin Halide Perovskites for Photovoltaic Applications Energy Environ. Sci. 2014, 7, 3061-3068 10.1039/C4EE01076K
306. Savenije, T. J.; Ponseca, C. S.; Kunneman, L.; Abdellah, M.; Zheng, K.; Tian, Y.; Zhu, Q.; Canton, S. E.; Scheblykin, I. G.; Pullerits, T. et al. Thermally Activated Exciton Dissociation and Recombination Control the Carrier Dynamics in Organometal Halide Perovskite J. Phys. Chem. Lett. 2014, 5, 2189-2194 10.1021/jz500858a
307. Tauc, J.; Menth, A. States in the Gap J. Non-Cryst. Solids 1972, 8-10, 569-585 10.1016/0022-3093(72)90194-9
308. Lasher, G.; Stern, F. Spontaneous and Stimulated Recombination Radiation in Semiconductors Phys. Rev. 1964, 133, A553-A563 10.1103/PhysRev.133.A553
309. Beard, M. C.; Ellingson, R. J. Multiple Exciton Generation in Semiconductor Nanocrystals: Toward Efficient Solar Energy Conversion Laser Photonics Rev. 2008, 2, 377-399 10.1002/lpor.200810013
310. Robel, I.; Gresback, R.; Kortshagen, U.; Schaller, R. D.; Klimov, V. I. Universal Size-Dependent Trend in Auger Recombination in Direct-Gap and Indirect-Gap Semiconductor Nanocrystals Phys. Rev. Lett. 2009, 102, 177404 10.1103/PhysRevLett.102.177404
311. Hangleiter, A.; Häcker, R. Enhancement of Band-to-Band Auger Recombination by Electron-Hole Correlations Phys. Rev. Lett. 1990, 65, 215-218 10.1103/PhysRevLett.65.215
312. 3 Solid-State Solar Cells Energy Environ. Sci. 2014, 7, 1148-1158 10.1039/c3ee43844a
313. Robel, I.; Bunker, B. A.; Kamat, P. V.; Kuno, M. Exciton Recombination Dynamics in CdSe Nanowires: Bimolecular to Three-Carrier Auger Kinetics Nano Lett. 2006, 6, 1344-1349 10.1021/nl060199z
314. Langevin, P. The Recombination and Mobilities of Ions in Gases Ann. Chim. Phys. 1903, 28, 433-530
315. 3 Bull. Chem. Soc. Jpn. 1990, 63, 2521-2525 10.1246/bcsj.63.2521
316. 3) Z. Naturforsch., A: Phys. Sci. 1990, 45, 307-312 10.1515/zna-1990-3-416
317. Adriaenssens, G. J.; Arkhipov, V. I. Non-Langevin Recombination in Disordered Materials with Random Potential Distributions Solid State Commun. 1997, 103, 541-543 10.1016/S0038-1098(97)00233-0
318. Pivrikas, A.; Juška, G.; Mozer, A. J.; Scharber, M.; Arlauskas, K.; Sariciftci, N. S.; Stubb, H.; Österbacka, R. Bimolecular Recombination Coefficient as a Sensitive Testing Parameter for Low-Mobility Solar-Cell Materials Phys. Rev. Lett. 2005, 94, 176806 10.1103/PhysRevLett.94.176806
319. 3 Nano Lett. 2015, 15, 248-253 10.1021/nl503494y
320. Choi, J. J.; Yang, X.; Norman, Z. M.; Billinge, S. J. L.; Owen, J. S. Structure of Methylammonium Lead Iodide Within Mesoporous Titanium Dioxide: Active Material in High-Performance Perovskite Solar Cells Nano Lett. 2014, 14, 127-133 10.1021/nl403514x
321. Vietmeyer, F.; Frantsuzov, P. A.; Janko, B.; Kuno, M. Carrier Recombination Dynamics in Individual CdSe Nanowires Phys. Rev. B: Condens. Matter Mater. Phys. 2011, 83, 115319 10.1103/PhysRevB.83.115319
322. Brandt, O.; Kanamoto, K.; Gotoda, M.; Isu, T.; Tsukada, N. Recombination Processes and Photoluminescence Intensity in Quantum Wells under Steady-State and Transient Conditions Phys. Rev. B: Condens. Matter Mater. Phys. 1995, 51, 7029-7037 10.1103/PhysRevB.51.7029
323. Vrućinić, M.; Matthiesen, C.; Sadhanala, A.; Divitini, G.; Cacovich, S.; Dutton, S. E.; Ducati, C.; Atatüre, M.; Snaith, H.; Friend, R. H. et al. Local Versus Long-Range Diffusion Effects of Photoexcited States on Radiative Recombination in Organic-Inorganic Lead Halide Perovskites Adv. Sci. 2015, 2, 1500136 10.1002/advs.201570037
324. Wang, C.; Li, C.-Y.; Hasselbeck, M. P.; Imangholi, B.; Sheik-Bahae, M. Precision, All-Optical Measurement of External Quantum Efficiency in Semiconductors J. Appl. Phys. 2011, 109, 093108 10.1063/1.3580259
325. Bisquert, J.; Mora-Seró, I. Simulation of Steady-State Characteristics of Dye-Sensitized Solar Cells and the Interpretation of the Diffusion Length J. Phys. Chem. Lett. 2010, 1, 450-456 10.1021/jz900297b
326. Masetti, G.; Severi, M.; Solmi, S. Modeling of Carrier Mobility against Carrier Concentration in Arsenic-, Phosphorus-, and Boron-Doped Silicon IEEE Trans. Electron Devices 1983, 30, 764-769 10.1109/T-ED.1983.21207
327. Pearson, G. L.; Haynes, J. R.; Shockley, W. Comment on Mobility Anomalies in Germanium Phys. Rev. 1950, 78, 295-296 10.1103/PhysRev.78.295.2
328. 3 Perovskite Solar Cells Nano Lett. 2014, 14, 888-893 10.1021/nl404252e
329. Saidaminov, M. I.; Abdelhady, A. L.; Murali, B.; Alarousu, E.; Burlakov, V. M.; Peng, W.; Dursun, I.; Wang, L.; He, Y.; Maculan, G. et al. High-Quality Bulk Hybrid Perovskite Single Crystals within Minutes by Inverse Temperature Crystallization Nat. Commun. 2015, 6, 7586 10.1038/ncomms8586
330. 3 Single Crystals Science 2015, 347, 967-970 10.1126/science.aaa5760
331. 3 Perovskite Solar Cell J. Phys. Chem. Lett. 2015, 6, 2469-2476 10.1021/acs.jpclett.5b00889
332. Sheng, R.; Ho-Baillie, A.; Huang, S.; Chen, S.; Wen, X.; Hao, X.; Green, M. A. Methylammonium Lead Bromide Perovskite-Based Solar Cells by Vapor-Assisted Deposition J. Phys. Chem. C 2015, 119, 3545-3549 10.1021/jp512936z
333. Chung, I.; Lee, B.; He, J.; Chang, R. P. H.; Kanatzidis, M. G. All-Solid-State Dye-Sensitized Solar Cells with High Efficiency Nature 2012, 485, 486-489 10.1038/nature11067
334. 2-Derived Hybrid-Perovskite Solar Absorbers Chem. Mater. 2015, 27, 7240-7243 10.1021/acs.chemmater.5b03581
335. Buin, A.; Pietsch, P.; Xu, J.; Voznyy, O.; Ip, A. H.; Comin, R.; Sargent, E. H. Materials Processing Routes to Trap-Free Halide Perovskites Nano Lett. 2014, 14, 6281-6286 10.1021/nl502612m
336. Liu, J.; Prezhdo, O. V. Chlorine Doping Reduces Electron-Hole Recombination in Lead Iodide Perovskites: Time-Domain Ab Initio Analysis J. Phys. Chem. Lett. 2015, 6, 4463-4469 10.1021/acs.jpclett.5b02355
337. Hodes, G.; Kamat, P. V. Understanding the Implication of Carrier Diffusion Length in Photovoltaic Cells J. Phys. Chem. Lett. 2015, 6, 4090-4092 10.1021/acs.jpclett.5b02052
338. Frost, J. M.; Walsh, A. What Is Moving in Hybrid Halide Perovskite Solar Cells? Acc. Chem. Res. 2016, 49, 528-535 10.1021/acs.accounts.5b00431
339. Pisula, W.; Feng, X.; Müllen, K. Charge-Carrier Transporting Graphene-Type Molecules Chem. Mater. 2011, 23, 554-567 10.1021/cm102252w
340. Tamai, Y.; Ohkita, H.; Benten, H.; Ito, S. Exciton Diffusion in Conjugated Polymers: From Fundamental Understanding to Improvement in Photovoltaic Conversion Efficiency J. Phys. Chem. Lett. 2015, 6, 3417-3428 10.1021/acs.jpclett.5b01147
341. Jiang, C.-S.; Yang, M.; Zhou, Y.; To, B.; Nanayakkara, S. U.; Luther, J. M.; Zhou, W.; Berry, J. J.; van de Lagemaat, J.; Padture, N. P. et al. Carrier Separation and Transport in Perovskite Solar Cells Studied by Nanometre-Scale Profiling of Electrical Potential Nat. Commun. 2015, 6, 8397 10.1038/ncomms9397
342. Baumann, A.; Väth, S.; Rieder, P.; Heiber, M. C.; Tvingstedt, K.; Dyakonov, V. Identification of Trap States in Perovskite Solar Cells J. Phys. Chem. Lett. 2015, 6, 2350-2354 10.1021/acs.jpclett.5b00953
343. Gundel, P.; Schubert, M. C.; Warta, W. Origin of Trapping in Multicrystalline Silicon J. Appl. Phys. 2008, 104, 073716 10.1063/1.2990053
344. Oga, H.; Saeki, A.; Ogomi, Y.; Hayase, S.; Seki, S. Improved Understanding of the Electronic and Energetic Landscapes of Perovskite Solar Cells: High Local Charge Carrier Mobility, Reduced Recombination, and Extremely Shallow Traps J. Am. Chem. Soc. 2014, 136, 13818-13825 10.1021/ja506936f
345. Kim, J.; Lee, S.-H.; Lee, J. H.; Hong, K.-H. The Role of Intrinsic Defects in Methylammonium Lead Iodide Perovskite J. Phys. Chem. Lett. 2014, 5, 1312-1317 10.1021/jz500370k
346. 3 Perovskite Solar Cell Absorber Appl. Phys. Lett. 2014, 104, 063903 10.1063/1.4864778
347. Garcia-Fernandez, P.; Aramburu, J. a.; Barriuso, M. T.; Moreno, M. Key Role of Covalent Bonding in Octahedral Tilting in Perovskites J. Phys. Chem. Lett. 2010, 1, 647-651 10.1021/jz900399m
348. 3 Cells J. Phys. Chem. Lett. 2015, 6, 2452-2456 10.1021/acs.jpclett.5b00968
349. Soufiani, A. M.; Huang, F.; Reece, P.; Sheng, R.; Ho-Baillie, A.; Green, M. A. Polaronic Exciton Binding Energy in Iodide and Bromide Organic-Inorganic Lead Halide Perovskites Appl. Phys. Lett. 2015, 107, 231902 10.1063/1.4936418
350. 3 Perovskite Films Phys. Chem. Chem. Phys. 2014, 16, 22122-22130 10.1039/C4CP03533J
351. Busmundrud, O.; Feder, J. Electrical Conduction and Phase Transitions in CsPbCl3 Solid State Commun. 1971, 9, 1575-1577 10.1016/0038-1098(71)90610-7
352. Mizusaki, J.; Arai, K.; Fueki, K. Ionic Conduction of the Perovskite-Type Halides Solid State Ionics 1983, 11, 203-211 10.1016/0167-2738(83)90025-5
353. Snaith, H. J.; Abate, A.; Ball, J. M.; Eperon, G. E.; Leijtens, T.; Noel, N. K.; Stranks, S. D.; Wang, J. T. W.; Wojciechowski, K.; Zhang, W. Anomalous Hysteresis in Perovskite Solar Cells J. Phys. Chem. Lett. 2014, 5, 1511-1515 10.1021/jz500113x
354. Yuan, Y.; Huang, J. Ion Migration in Organometal Trihalide Perovskite and Its Impact on Photovoltaic Efficiency and Stability Acc. Chem. Res. 2016, 49, 286-293 10.1021/acs.accounts.5b00420
355. Eperon, G. E.; Paternò, G. M.; Sutton, R. J.; Zampetti, A.; Haghighirad, A. A.; Cacialli, F.; Snaith, H. J. Inorganic Caesium Lead Iodide Perovskite Solar Cells J. Mater. Chem. A 2015, 3, 19688-19695 10.1039/C5TA06398A
356. Zhang, Y.; Liu, M.; Eperon, G. E.; Leijtens, T. C.; McMeekin, D.; Saliba, M.; Zhang, W.; de Bastiani, M.; Petrozza, A.; Herz, L. M. et al. Charge Selective Contacts, Mobile Ions and Anomalous Hysteresis in organic-Inorganic Perovskite Solar Cells Mater. Horiz. 2015, 2, 315-322 10.1039/C4MH00238E
357. van Reenen, S.; Kemerink, M.; Snaith, H. J. Modeling Anomalous Hysteresis in Perovskite Solar Cells J. Phys. Chem. Lett. 2015, 6, 3808-3814 10.1021/acs.jpclett.5b01645
358. Unger, E. L.; Hoke, E. T.; Bailie, C. D.; Nguyen, W. H.; Bowring, A. R.; Heumuller, T.; Christoforo, M. G.; McGehee, M. D. Hysteresis and Transient Behavior in Current-Voltage Measurements of Hybrid-Perovskite Absorber Solar Cells Energy Environ. Sci. 2014, 7, 3690-3698 10.1039/C4EE02465F
359. Chen, B.; Yang, M.; Zheng, X.; Wu, C.; Li, W.; Yan, Y.; Bisquert, J.; Garcia-Belmonte, G.; Zhu, K.; Priya, S. Impact of Capacitive Effect and Ion Migration on the Hysteretic Behavior of Perovskite Solar Cells J. Phys. Chem. Lett. 2015, 6, 4693-4700 10.1021/acs.jpclett.5b02229
360. 2 Layer J. Phys. Chem. Lett. 2014, 5, 2927-2934 10.1021/jz501392m
361. Xu, J.; Buin, A.; Ip, A. H.; Li, W.; Voznyy, O.; Comin, R.; Yuan, M.; Jeon, S.; Ning, Z.; McDowell, J. J. et al. Perovskite-Fullerene Hybrid Materials Suppress Hysteresis in Planar Diodes Nat. Commun. 2015, 6, 7081 10.1038/ncomms8081
362. Eames, C.; Frost, J. M.; Barnes, P. R. F.; O'Regan, B. C.; Walsh, A.; Islam, M. S. Ionic Transport in Hybrid Lead Iodide Perovskite Solar Cells Nat. Commun. 2015, 6, 7497 10.1038/ncomms8497
363. Azpiroz, J. M.; Mosconi, E.; Bisquert, J.; De Angelis, F. Defect Migration in Methylammonium Lead Iodide and Its Role in Perovskite Solar Cell Operation Energy Environ. Sci. 2015, 8, 2118-2127 10.1039/C5EE01265A
364. Haruyama, J.; Sodeyama, K.; Han, L.; Tateyama, Y. First-Principles Study of Ion Diffusion in Perovskite Solar Cell Sensitizers J. Am. Chem. Soc. 2015, 137, 10048-10051 10.1021/jacs.5b03615
365. Egger, D. A.; Kronik, L.; Rappe, A. M. Theory of Hydrogen Migration in Organic-Inorganic Halide Perovskites Angew. Chem., Int. Ed. 2015, 54, 12437-12441 10.1002/anie.201502544
366. Xiao, Z.; Yuan, Y.; Shao, Y.; Wang, Q.; Dong, Q.; Bi, C.; Sharma, P.; Gruverman, A.; Huang, J. Giant Switchable Photovoltaic Effect in Organometal Trihalide Perovskite Devices Nat. Mater. 2014, 14, 193-198 10.1038/nmat4150
367. Yuan, Y.; Chae, J.; Shao, Y.; Wang, Q.; Xiao, Z.; Centrone, A.; Huang, J. Photovoltaic Switching Mechanism in Lateral Structure Hybrid Perovskite Solar Cells Adv. Energy Mater. 2015, 5, 1500615 10.1002/aenm.201500615
368. Li, C.; Tscheuschner, S.; Paulus, F.; Hopkinson, P. E.; Kießling, J.; Köhler, A.; Vaynzof, Y.; Huettner, S. Iodine Migration and Its Effect on Hysteresis in Perovskite Solar Cells Adv. Mater. 2016, 28, 2446-2454 10.1002/adma.201503832
369. Bag, M.; Renna, L. A.; Adhikari, R. Y.; Karak, S.; Liu, F.; Lahti, P. M.; Russell, T. P.; Tuominen, M. T.; Venkataraman, D. Kinetics of Ion Transport in Perovskite Active Layers and Its Implications for Active Layer Stability J. Am. Chem. Soc. 2015, 137, 13130-13137 10.1021/jacs.5b08535
370. 3 Perovskite Solar Cells: The Role of a Compensated Electric Field Energy Environ. Sci. 2015, 8, 995-1004 10.1039/C4EE03664F
371. Bischak, C. G.; Sanehira, E. M.; Precht, J. T.; Luther, J. M.; Ginsberg, N. S. Heterogeneous Charge Carrier Dynamics in Organic-Inorganic Hybrid Materials: Nanoscale Lateral and Depth-Dependent Variation of Recombination Rates in Methylammonium Lead Halide Perovskite Thin Films Nano Lett. 2015, 15, 4799-4807 10.1021/acs.nanolett.5b01917
372. Shao, Y.; Fang, Y.; Li, T.; Wang, Q.; Dong, Q.; Deng, Y.; Yuan, Y.; Wei, H.; Wang, M.; Gruverman, A. et al. Grain Boundary Dominated Ion Migration in Polycrystalline Organic-inorganic Halide Perovskite Films Energy Environ. Sci. 2016, 9, 1752-1759 10.1039/C6EE00413J
373. 3 Perovskite under Ambient Conditions Chem. Mater. 2016, 28, 303-311 10.1021/acs.chemmater.5b04122
374. 3 Crystals Using Inverse Solubility Sci. Rep. 2015, 5, 11654 10.1038/srep11654
375. Zhu, F.; Men, L.; Guo, Y.; Zhu, Q.; Bhattacharjee, U.; Goodwin, P. M.; Petrich, J. W.; Smith, E. A.; Vela, J. Shape Evolution and Single Particle Luminescence of Organometal Halide Perovskite Nanocrystals ACS Nano 2015, 9, 2948-2959 10.1021/nn507020s
376. Park, Y.-S.; Guo, S.; Makarov, N.; Klimov, V. I. Room Temperature Single-Photon Emission from Individual Perovskite Quantum Dots ACS Nano 2015, 9, 10386-10393 10.1021/acsnano.5b04584