Stabilization of the trigonal high-temperature phase of formamidinium lead iodide

Journal of Physical Chemistry Letters

Volumn 6, Issue 7, 2015, Pages 1249-1253

  Binek, Andreas ^a   Hanusch, Fabian C ^a   Docampo, Pablo ^a   Bein, Thomas ^a  

^a UNIVERSITY OF MUNICH   (Germany)

Author keywords

FAPbI3; formamidinium lead iodide; hybrid perovskite; phase stabilization; temperature dependent XRD

Indexed keywords

IODINE COMPOUNDS; LAYERED SEMICONDUCTORS; LEAD METALLOGRAPHY; PEROVSKITE; PEROVSKITE SOLAR CELLS; STABILIZATION;

FAPBI3; HEXAGONAL SYMMETRY; HIGH TEMPERATURE PHASE; LATTICE SHRINKAGES; LEAD IODIDE; PHASE STABILIZATION; TEMPERATURE DEPENDENT; TEMPERATURE RANGE;

LEAD COMPOUNDS;

EID: 84926619011     PISSN: None     EISSN: 19487185     Source Type: Journal    
DOI: 10.1021/acs.jpclett.5b00380     Document Type: Article

References (26)

1. Ball, J. M.; Lee, M. M.; Hey, A.; Snaith, H. J. Low-Temperature Processed Meso-Superstructured to Thin-Film Perovskite Solar Cells Energy Environ. Sci. 2013, 6, 1739-1743
2. Liu, M.; Johnston, M. B.; Snaith, H. J. Efficient Planar Heterojunction Perovskite Solar Cells by Vapour Deposition Nature 2013, 501, 395-398
3. Burschka, J.; Pellet, N.; Moon, S.-J.; Humphry-Baker, R.; Gao, P.; Nazeeruddin, M. K.; Gratzel, M. Sequential Deposition As a Route to High-Performance Perovskite-Sensitized Solar Cells Nature 2013, 499, 316-319
4. Kazim, S.; Nazeeruddin, M. K.; Grätzel, M.; Ahmad, S. Perowskit als Lichtabsorptionsmaterial: ein Durchbruch in der Photovoltaik Angew. Chem. 2014, 126, 2854-2867
5. Docampo, P.; Ball, J. M.; Darwich, M.; Eperon, G. E.; Snaith, H. J. Efficient Organometal Trihalide Perovskite Planar-Heterojunction Solar Cells on Flexible Polymer Substrates Nat. Commun. 2013, 4, 2761
6. You, J.; Hong, Z.; Yang, Y.; Chen, Q.; Cai, M.; Song, T.-B.; Chen, C.-C.; Lu, S.; Liu, Y.; Zhou, H.; Yang, Y. Low-Temperature Solution-Processed Perovskite Solar Cells with High Efficiency and Flexibility ACS Nano 2014, 8, 1674
7. Chiang, Y.-F.; Jeng, J.-Y.; Lee, M.-H.; Peng, S.-R.; Chen, P.; Guo, T.-F.; Wen, T.-C.; Hsu, Y.-J.; Hsu, C.-M. High Voltage and Efficient Bilayer Heterojunction Solar Cells Based on Organic-Inorganic Hybrid Perovskite Absorber with Low-Cost Flexible Substrate Phys. Chem. Chem. Phys. 2014, 16, 6033
8. Lee, M. M.; Teuscher, J.; Miyasaka, T.; Murakami, T. N.; Snaith, H. J. Efficient Hybrid Solar Cells Based on Meso-Superstructured Organometal Halide Perovskites Science 2012, 338, 643-647
9. Zhou, H.; Chen, Q.; Li, G.; Luo, S.; Song, T.-b.; Duan, H.-S.; Hong, Z.; You, J.; Liu, Y.; Yang, Y. Interface Engineering of Highly Efficient Perovskite Solar Cells Science 2014, 345, 542-546
10. Baikie, T.; Fang, Y. N.; Kadro, J. M.; Schreyer, M.; Wei, F. X.; Mhaisalkar, S. G.; Graetzel, M.; White, T. J. Synthesis and Crystal Chemistry of the Hybrid Perovskite (CH3NH3) PbI3 for Solid-State Sensitised Solar Cell Applications J. Mater. Chem. A 2013, 1, 5628-5641
11. Stoumpos, C. C.; Malliakas, C. D.; Kanatzidis, M. G. Semiconducting Tin and Lead Iodide Perovskites with Organic Cations: Phase Transitions, High Mobilities, and Near-Infrared Photoluminescent Properties Inorg. Chem. 2013, 52, 9019-9038
12. Filip, M. R.; Eperon, G. E.; Snaith, H. J.; Giustino, F. Steric Engineering of Metal-Halide Perovskites with Tunable Optical Band Gaps Nat. Commun. 2014, 5, 5757
13. Shockley, W.; Queisser, H. J. Detailed Balance Limit of Efficiency of p-n Junction Solar Cells J. Appl. Phys. 1961, 32, 510-519
14. Pellet, N.; Gao, P.; Gregori, G.; Yang, T.-Y.; Nazeeruddin, M. K.; Maier, J.; Grätzel, M. Mixed-Organic-Cation Perovskite Photovoltaics for Enhanced Solar-Light Harvesting Angew. Chem., Int. Ed. 2014, 53, 3151-3157
15. Jeon, N. J.; Noh, J. H.; Yang, W. S.; Kim, Y. C.; Ryu, S.; Seo, J.; Seok, S. I. Compositional Engineering of Perovskite Materials for High-Performance Solar Cells Nature 2015, 517, 476-480
16. Eperon, G. E.; Stranks, S. D.; Menelaou, C.; Johnston, M. B.; Herz, L.; Snaith, H. Formamidinium Lead Trihalide: A Broadly Tunable Perovskite for Efficient Planar Heterojunction Solar Cells Energy Environ. Sci. 2014, 7, 982-988
17. Noh, J. H.; Im, S. H.; Heo, J. H.; Mandal, T. N.; Seok, S. I. Chemical Management for Colorful, Efficient, and Stable Inorganic-Organic Hybrid Nanostructured Solar Cells Nano Lett. 2013, 13, 1764-1769
18. Choi, J. J.; Yang, X.; Norman, Z. M.; Billinge, S. J. L.; Owen, J. S. Structure of Methylammonium Lead Iodide Within Mesoporous Titanium Dioxide: Active Material in High-Performance Perovskite Solar Cells Nano Lett. 2014, 14, 127-133
19. Docampo, P.; Hanusch, F. C.; Stranks, S. D.; Döblinger, M.; Feckl, J. M.; Ehrensperger, M.; Minar, N. K.; Johnston, M. B.; Snaith, H. J.; Bein, T. Solution Deposition-Conversion for Planar Heterojunction Mixed Halide Perovskite Solar Cells. Adv. Energy Mater. 2014, 4.
20. Wu, X.; Trinh, M. T.; Niesner, D.; Zhu, H.; Norman, Z.; Owen, J. S.; Yaffe, O.; Kudisch, B. J.; Zhu, X. Trap States in Lead Iodide Perovskites J. Am. Chem. Soc. 2015, 137, 2089-96
21. Noel, N. K.; Abate, A.; Stranks, S. D.; Parrott, E.; Burlakov, V.; Goriely, A.; Snaith, H. J. Enhanced Photoluminescence and Solar Cell Performance via Lewis Base Passivation of Organic-Inorganic Lead Halide Perovskites ACS Nano 2014, 8, 9815-21
22. Amat, A.; Mosconi, E.; Ronca, E.; Quarti, C.; Umari, P.; Nazeeruddin, M. K.; Grätzel, M.; De Angelis, F. Cation-Induced Band-Gap Tuning in Organohalide Perovskites: Interplay of Spin-Orbit Coupling and Octahedra Tilting Nano Lett. 2014, 14, 3608-16
23. Li, W.; Thirumurugan, A.; Barton, P. T.; Lin, Z.; Henke, S.; Yeung, H. H. M.; Wharmby, M. T.; Bithell, E. G.; Howard, C. J.; Cheetham, A. K. Mechanical Tunability via Hydrogen Bonding in Metal-Organic Frameworks with the Perovskite Architecture J. Am. Chem. Soc. 2014, 136, 7801-7804
24. Frost, J. M.; Butler, K. T.; Brivio, F.; Hendon, C. H.; van Schilfgaarde, M.; Walsh, A. Atomistic Origins of High-Performance in Hybrid Halide Perovskite Solar Cells Nano Lett. 2014, 14, 2584-90
25. Madelung, E. Das elektrische Feld in Systemen von regelmäßig angeordneten Punktladungen Phys. Z. 1919, 19, 524-533
26. Harrison, W. A. Electronic Structure and the Properties of Solids; Freeman: San Francisco, 1980