Iridium(III)-Catalyzed CH Amidation of Arylphosphoryls Leading to a P-Stereogenic Center

Chemistry - A European Journal

Volumn 20, Issue 39, 2014, Pages 12421-12425

  Gwon, Donghyeon ^a,b   Lee, Donggun ^a,b   Kim, Jiyu ^a,b   Park, Sehoon ^a,b   Chang, Sukbok ^a,b  

^a Korea Advanced Institute of Science and Technology (KAIST)   (South Korea)

^b Institute for Basic Science   (South Korea)

Author keywords

asymmetric induction; chirality; C H functionalization; iridium catalysis; phosphine oxides

Indexed keywords

CATALYSIS; CHIRALITY; PHOSPHORUS COMPOUNDS;

AMIDATION; ASYMMETRIC INDUCTION; ASYMMETRIC REACTION; DIASTEREOMERIC RATIOS; FUNCTIONALIZATIONS; IRIDIUM CATALYSIS; PHOSPHINE OXIDE; STEREOGENIC CENTERS;

IRIDIUM COMPOUNDS;

EID: 84982256685     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.201404151     Document Type: Article

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66. 3 to afford the corresponding amidated phosphine in 89 % yield, and detailed experimental procedures are presented in the Supporting Information.