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Volumn 338, Issue 6106, 2012, Pages 504-506

Chiral cyclopentadienyl ligands as stereocontrolling element in asymmetric C-H functionalization

Author keywords

[No Author keywords available]

Indexed keywords

CYCLOPENTADIENE DERIVATIVE; HYDROXAMIC ACID; LIGAND; METAL; RHODIUM COMPLEX;

EID: 84867818759     PISSN: 00368075     EISSN: 10959203     Source Type: Journal    
DOI: 10.1126/science.1226938     Document Type: Article
Times cited : (495)

References (37)
  • 13
    • 33846585041 scopus 로고    scopus 로고
    • B. Heller et al., Chemistry 13, 1117 (2007).
    • (2007) Chemistry , vol.13 , pp. 1117
    • Heller, B.1
  • 15
    • 84922691851 scopus 로고    scopus 로고
    • note
    • Sandwich complexes containing two Cp moieties such as ansa-ebthi metallocenes of Ti, Zr, or Hf are versatile catalysts for several asymmetric reactions. For an overview, see (16).
  • 26
    • 84922712532 scopus 로고    scopus 로고
    • note
    • Although Fig. 1 depicts solely the differences of the two most stable conformers, we assume that reactions proceed under Curtin-Hammett conditions. Therefore, no judgment on the reactive conformer, the one with a lower transition state, is possible.
  • 27
    • 84922747073 scopus 로고    scopus 로고
    • note
    • Materials and methods are available as supplementary materials on Science Online. For the syntheses and an x-ray structure of 1c, see figs. S1 to S3.
  • 33
    • 84922700598 scopus 로고    scopus 로고
    • note
    • 2} by silver salts and carboxylate additives.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.