Mechanistic Insights into the Palladium-Catalyzed Aziridination of Aliphatic Amines by C-H Activation

Journal of the American Chemical Society

Volumn 137, Issue 33, 2015, Pages 10632-10641

  Smalley, Adam P ^a   Gaunt, Matthew J ^a  

^a UNIVERSITY OF CAMBRIDGE   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

ACETIC ACID; ACTIVATION ANALYSIS; CATALYSIS; CHEMICAL ACTIVATION; COMPUTATION THEORY; DESIGN FOR TESTABILITY; ORGANIC ACIDS; PH;

COMPUTATIONAL INVESTIGATION; INTERACTION ANALYSIS; PALLADIUM-CATALYZED; PALLADIUM-CATALYZED REACTIONS; REACTION CONDITIONS; REACTION MECHANISM; REDUCTIVE ELIMINATION; SYNTHESIS CONDITIONS;

DENSITY FUNCTIONAL THEORY;

ACETIC ACID; ACETIC ANHYDRIDE; ALIPHATIC AMINE; CARBENE; CYCLOHEXANE DERIVATIVE; PALLADIUM; PALLADIUM ACETATE; TETRACHLOROETHANE; TOLUENE; AMINE; AZIRIDINE; AZIRIDINE DERIVATIVE; CARBON; HYDROGEN;

ARTICLE; AZIRIDINATION; CATALYSIS; CATALYST; CHEMICAL REACTION; CHEMICAL REACTION KINETICS; CONCENTRATION RESPONSE; DENSITY FUNCTIONAL THEORY; GAS CHROMATOGRAPHY; HYDROGEN BOND; MECHANICS; REACTION ANALYSIS; SYNTHESIS; CHEMICAL STRUCTURE; CHEMISTRY; CONFORMATION; KINETICS; QUANTUM THEORY;

AMINES; AZIRIDINES; CARBON; CATALYSIS; HYDROGEN; KINETICS; MODELS, MOLECULAR; MOLECULAR CONFORMATION; PALLADIUM; QUANTUM THEORY;

EID: 84941649212     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/jacs.5b05529     Document Type: Article

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