From monomers to polymers from renewable resources: Recent advances

Progress in Polymer Science

Volumn 48, Issue , 2015, Pages 1-39

  Gandini, Alessandro ^a   Lacerda, Talita M ^a  

^a UNIVERSITY OF SÃO PAULO   (Brazil)

Author keywords

Furans; Glycerol; Lignin; Plant oils; Polymers from biomass; Polysaccharides; Sugars; Terpenes and rosin

Indexed keywords

CHEMISTRY; GLYCEROL; LIGNIN; POLYSACCHARIDES; SUGARS;

FURANS; PLANT OIL; RECENT PROGRESS; RENEWABLE RESOURCE;

POLYMERS;

EID: 84940447932     PISSN: 00796700     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.progpolymsci.2014.11.002     Document Type: Review

References (313)

1. M.N. Belgacem, and A. Gandini Monomers, polymers and composites from renewable resources 2008 Elsevier Ltd Amsterdam 560 pp.
2. A. Gandini Polymers from renewable resources: a challenge for the future of macromolecular materials Macromolecules 41 2008 9491 9504
3. A. Gandini The irruption of polymers from renewable resources on the scene of macromolecular science and technology Green Chem 13 2011 1061 1083
4. L. Yu Biodegradable polymer blends and composites from renewable resources. 2009 John Wiley and Sons Hoboken 488 pp.
5. P.A. Williams Renewable resources for functional polymers and biomaterials: polysaccharides, proteins and polyesters 2011 RSC Publishing Cambridge 456 pp.
6. S. Kalia, and L. Avérous Biopolymers, biomedical and environmental applications 2011 Scrivener Publishing LLC Salem, MA 642 pp.
7. V. Mittal Renewable polymers: synthesis, processing, and technology 2012 Scrivener Publishing LLC Salem, MA 502 pp.
8. S. Ebnesajjad Handbook of biopolymers and biodegradable plastics. 2013 Elsevier Ltd Oxford 462 pp.
9. G.W. Coates, and M.A. Hillmyer A virtual issue of Macromolecules: "Polymers from Renewable Resources" Macromolecules 42 2009 7987 7989
10. S.J. Eichhorn, and A. Gandini Materials from renewable resources MRS Bull 35 2010 187 190
11. J.-M. Raquez, M. Deléglise, M.-F. Lacrampe, and P. Krawczak Thermosetting (bio)materials derived from renewable resources: a critical review Prog Polym Sci 35 2010 487 509
12. C.K.S. Pillai Challenges for natural monomers and polymers: novel design strategies and engineering to develop advanced polymers Des Monomers Polym 13 2010 87 121
13. R.T. Mathers How well can renewable resources mimic commodity monomers and polymers? J Polym Sci Part A: Polym Chem 50 2012 1 15
14. M.J.-L. Tschan, E. Brulé, P. Haquette, and C.M. Thomas Synthesis of biodegradable polymers from renewable resources Polym Chem 3 2012 836 851
15. G.-Q. Chen, and M.K. Patel Plastics derived from biological sources: present and future: a technical and environmental review Chem Rev 112 2012 2082 2099
16. R. Mülhaupt Green polymer chemistry and bio-based plastics: dreams and reality Macromol Chem Phys 214 2013 159 174
17. M.A.R. Meier Sustainable polymers: reduced environmental impact, renewable raw materials and catalysis Green Chem 16 2014 1672
18. S.A. Miller Sustainable polymers: replacing polymers derived from fossil fuels Polym Chem 5 2014 3117 3118
19. A. Lendlein, and A. Sisson Handbook of biodegradable polymers: isolation, synthesis, characterization and applications 2014 Wiley-VCH Weinheim 405 pp.
20. Anonymous Scrivener Publishing Webpage 2014 www.scrivenerpublishing.com [accessed July 2014]
21. A. Corma, S. Iborra, and A. Velty Chemical routes for the transformation of biomass into chemicals Chem Rev 107 2007 2411 2502
22. J.J. Bozell, and G.R. Petersen Technology development for the production of biobased products from biorefinery carbohydrates - the US Department of Energy's "Top 10" revisited Green Chem 12 2010 539 554
23. C.-H. Zhou, X. Xia, C.-X. Lin, D.-S. Tong, and J. Beltramini Catalytic conversion of lignocellulosic biomass to fine chemicals and fuels Chem Soc Rev 40 2011 5588 5617
24. J.C. Serrano-Ruiz, R. Luque, and A. Sepúlveda-Escribano Transformations of biomass-derived platform molecules: from high added-value chemicals to fuels via aqueous-phase processing Chem Soc Rev 40 2011 5266 5281
25. P. Gallezot Conversion of biomass to selected chemical products Chem Soc Rev 41 2012 1538 1558
26. Anonymous Brazilian Petrochemical Co Webpage 2014 http://ciber.gatech.edu/Braskem.pdf [accessed July 2014]
27. Anonymous GoDaddy, LLC. Bioplastic-Innovation Webpage 2014 http://bioplastic-innovation.com/2012/09/23/braskem-firms-up-plan-for-100m-brazilian-green-plastics-factory/2012 [accessed July 2014]
28. Anonymous Nextant Inc. NexantThinking™. The future of energy and chemicals 2014 http://www.chemsystems.com/reports/search/docs/abstracts/0708S11-abs.pdf [accessed July 2014]
29. M. Iwamoto One step formation of propene from ethene or ethanol through metathesis on nickel ion-loaded silica Molecules 16 2011 7844 7863
30. Z. Song, A. Takahashi, I. Nakamura, and T. Fujitani Phosphorus-modified ZSM-5 for conversion of ethanol to propylene Appl Catal A: Gen 384 2010 201 205
31. M. Pagliaro, and M. Rossi The future of glycerol 2008 RSC Publishing Cambridge 170
32. L. Prati, P. Spontoni, and A. Gaiassi From renewable to fine chemicals through selective oxidation: the case of glycerol Top Catal 52 2009 288 296
33. C. Crotti, E. Farnetti, and N. Guidolin Alternative intermediates for glycerol valorization: iridium-catalyzed formation of acetals and ketals Green Chem 12 2010 2225 2231
34. A. Martin, and M. Richter Oligomerization of glycerol - a critical review Eur J Lipid Sci Technol 113 2011 100 117
35. S. Salehpour, and M.A. Dubé Reaction monitoring of glycerol step-growth polymerization using ATR-FTIR spectroscopy Macromol React Eng 6 2012 85 92
36. S. Salehpour, and M.A. Dubé Towards the sustainable production of higher-molecular-weight polyglycerol Macromol Chem Phys 212 2011 1284 1293
37. H. Kimura Poly(ketomalonate) by catalytic oxidation of glycerol, 4. Anionic polymerization J Polym Sci Part A: Polym Chem 38 2000 664 676
38. H. Kimura Oxidation assisted new reaction of glycerol Polym Adv Technol 12 2001 697 710
39. M. Pagliaro, R. Ciriminna, H. Kimura, M. Rossi, and C. Della Pina From glycerol to value-added products Angew Chem Int Ed Engl 46 2007 4434 4440
40. C.-H.C. Zhou, J.N. Beltramini, Y.-X. Fan, and G.Q.M. Lu Chemoselective catalytic conversion of glycerol as a biorenewable source to valuable commodity chemicals Chem Soc Rev 37 2008 527 549
41. A. Macierzanka, and H. Szela Esterification kinetics of glycerol with fatty acids in the presence of zinc carboxylates: preparation of modified acylglycerol emulsifiers Ind Eng Chem Res 43 2004 7744 7753
42. J.L. Lynn Jr. Detergents and detergency 6th ed. F. Shahidi, Bailey's industrial oil and fat products vol. 6 2005 John Wiley and Sons Hoboken, NJ [chapter 4]
43. D.T. Johnson, and K.A. Taconi The glycerin glut: options for the value-added conversion of crude glycerol resulting from biodiesel production Environ Prog 26 2009 338 348
44. J.R. Weiser, P.N. Zawaneh, and D. Putnam Poly(carbonate-ester)s of dihydroxyacetone and lactic acid as potential biomaterials Biomacromolecules 12 2011 977 986
45. M. Helou, J.-M. Brusson, J.-F. Carpentier, and S.M. Guillaume Functionalized polycarbonates from dihydroxyacetone: insights into the immortal ring-opening polymerization of 2,2-dimethoxytrimethylene carbonate Polym Chem 2 2011 2789 2795
46. P.N. Zawaneh, A.M. Doody, A.N. Zelikin, and D. Putnam Diblock copolymers based on dihydroxyacetone and ethylene glycol: synthesis, characterization, and nanoparticle formulation Biomacromolecules 7 2006 3245 3251
47. A.N. Zelikin, and D. Putnam Poly(carbonate-acetal)s from the dimer form of dihydroxyacetone Macromolecules 38 2005 5532 5537
48. L.-S. Wang, S.-X. Cheng, and R.-X. Zhuo Novel biodegradable aliphatic polycarbonate based on ketal protected dihydroxyacetone Macromol Rapid Commun 25 2004 959 963
49. T. Fukuoka, H. Habe, D. Kitamoto, and K. Sakaki Bioprocessing of glycerol into glyceric acid for use in bioplastic monomer J Oleo Sci 60 2011 369 373
50. H. Al-Mesfer, and B.J. Tighe Polymers for biodegradable medical device. III. Polymerization and copolymerization of cyclic derivatives of tartronic acid Biomaterials 8 1987 353 359
51. P.G. Parzuchowski, M. Jaroch, M. Tryznowski, and G. Rokicki Synthesis of new glycerol-based hyperbranched polycarbonates Macromolecules 41 2008 3859 3865
52. 2 monomer J Polym Sci Part A: Polym Chem 47 2009 3860 3868
53. X. Zhao, L. Liu, H. Dai, C. Ma, X. Tan, and R. Yu Synthesis and application of water-soluble hyperbranched poly(ester)s from maleic anhydride and glycerol J Appl Polym Sci 113 2009 3376 3381
54. I.N. Kurniasih, H. Liang, J.P. Rabe, and R. Haag Supramolecular aggregates of water soluble dendritic polyglycerol architectures for the solubilization of hydrophobic compounds Macromol Rapid Commun 31 2010 1516 1520
55. M. Simões, S. Baranton, and C. Coutanceau Electrochemical valorisation of glycerol ChemSusChem 5 2012 2106 2124
56. R.C. Schulz Acrolein polymers Encyclopedia of polymer science and technology vol. 1 2011 John Wiley and Sons Inc. Hoboken 134 142
57. B. Katryniok, S. Paul, V. Bellière-Baca, P. Rey, and F. Dumeignil Glycerol dehydration to acrolein in the context of new uses of glycerol Green Chem 12 2010 2079 2098
58. A. Corma, G.W. Huber, L. Sauvanaud, and P. O'Connor Biomass to chemicals: catalytic conversion of glycerol/water mixtures into acrolein, reaction network J Catal 257 2008 163 171
59. P.D. Pham, S. Monge, V. Lapinte, Y. Raoul, and J.J. Robin Various radical polymerizations of glycerol-based monomers Eur J Lipid Sci Technol 115 2013 28 40
60. V. Plasman, and T. Caulier Polyglycerol esters demonstrate superior antifogging properties for films Plast Addit Compd 2005 30 33
61. S.R. Sandler, and F.R. Berg Room temperature polymerization of glycidol J Polym Sci Part A1 4 1966 1253 1259
62. R. Tokar, P. Kubisa, and S. Penczek Cationic polymerization of glycidol: coexistence of the activated monomer and active chain end mechanism Macromolecules 27 1994 320 322
63. Sunder A, Mülhaupt R. In presence of basic catalysts and solvent: continuous distillation; colorless; by-product inhibition. US 6,822,068, 2004.
64. T. Kuzuyama, and H. Seto Diversity of the biosynthesis of the isoprene units Nat Prod Rep 20 2003 171 183
65. Anonymous Danisco-du Pont Co. Danisco Webpage 2014 http://www.danisco.com/cms/connect/corporate/media+relations/news/frontpage/pressrelease-453-en.htm [accessed Sept 2014]
66. I. Bechthold, K. Bretz, S. Kabasci, R. Kopitzky, and A. Springer Succinic acid: a new platform chemical for biobased polymers from renewable resources Chem Eng Technol 31 2008 647 654
67. Q.A. Acton Succinic acids - advances in research and application. 2013 ScholarlyBrief Atlanta 76 pp.
68. C. Delhomme, D. Weuster-Botz, and F.E. Kühn Succinic acid from renewable resources as a C4 building-block chemical - a review of the catalytic possibilities in aqueous media Green Chem 11 2009 13 26
69. Y. Jiang, A. Woortman, G. van Ekenstein, and K. Loos Enzyme-catalyzed synthesis of unsaturated aliphatic polyesters based on green monomers from renewable resources Biomolecules 3 2013 461 480
70. Z. Tai, J. Zhang, A. Wang, M. Zheng, and T. Zhang Temperature-controlled phase-transfer catalysis for ethylene glycol production from cellulose Chem Commun 48 2012 7052 7054
71. X. Wang, L. Meng, F. Wu, Y. Jiang, L. Wang, and X. Mu Efficient conversion of microcrystalline cellulose to 1,2-alkanediols over supported Ni catalysts Green Chem 14 2012 758
72. M. Rose, and R. Palkovits Cellulose-based sustainable polymers: state of the art and future trends Macromol Rapid Commun 32 2011 1299 1311
73. H. Kobayashi, and A. Fukuoka Synthesis and utilisation of sugar compounds derived from lignocellulosic biomass Green Chem 15 2013 1740 1763
74. B. Kamm, P.R. Gruber, and M. Kamm Biorefineries - industrial processes and products vols. 1 and 2 2006 Wiley-VCH Weinheim 360 pp.
75. T.E. Amidon, C.D. Wood, A.M. Shupe, Y. Wang, M. Graves, and S. Liu Biorefinery: conversion of woody biomass to chemicals, energy and materials J Biobased Mater Bioenergy 2 2008 100 120
76. G.M. Campbell, A. Azapagic, and P. Vadlani Managing the transition decades: tactical options for an uncertain route towards a clear strategic goal Chem Eng Res Des 87 2009 1101 1102
77. M.S. Singhvi, S. Chaudhari, and D.V. Gokhale Lignocellulose processing: a current challenge RSC Adv 4 2014 8271 8277
78. P.C. Rodrigues Pinto, E.A. Borges da Silva, and A. Rodrigues Comparative study of solid-phase extraction and liquid-liquid extraction for the reliable quantification of high value added compounds from oxidation processes of wood-derived lignin Ind Eng Chem Res 49 2010 12311 12318
79. A.K. Deepa, and P.L. Dhepe Solid acid catalyzed depolymerization of lignin into value added aromatic monomers RSC Adv 4 2014 12625 12629
80. A. Gandini, and A.J.D. Silvestre Terpenes: major sources, properties and applications M.N. Belgacem, A. Gandini, Monomers, polymers and composites from renewable resources 2008 Elsevier Ltd Amsterdam 17 38
81. P.A. Wilbon, F. Chu, and C. Tang Progress in renewable polymers from natural terpenes, terpenoids, and rosin Macromol Rapid Commun 34 2013 8 37
82. 3 catalyst: toward sustainable plastics from renewable biomass resources Green Chem 13 2011 2362 2364
83. S. Kobayashi, C. Lu, T.R. Hoye, and M.A. Hillmyer Controlled polymerization of a cyclic diene prepared from the ring-closing metathesis of a naturally occurring monoterpene J Am Chem Soc 131 2009 7960 7961
84. M. Firdaus, L. Montero de Espinosa, and M.A.R. Meier Terpene-based renewable monomers and polymers via thiol-ene additions Macromolecules 44 2011 7253 7262
85. M. Firdaus, and M.A.R. Meier Renewable polyamides and polyurethanes derived from limonene Green Chem 15 2013 370 380
86. R.T. Mathers, K. Damodaran, M.G. Rendos, and M.S. Lavrich Functional hyperbranched polymers using ring-opening metathesis polymerization of dicyclopentadiene with monoterpenes Macromolecules 42 2009 1512 1518
87. C.M. Byrne, S.D. Allen, E.B. Lobkovsky, and G.W. Coates Alternating copolymerization of limonene oxide and carbon dioxide J Am Chem Soc 126 2004 11404 11405
88. C. Robert, F. de Montigny, and C.M. Thomas Tandem synthesis of alternating polyesters from renewable resources Nat Commun 2 2011 586 592
89. J.R. Lowe, W.B. Tolman, and M.A. Hillmyer Oxidized dihydrocarvone as a renewable multifunctional monomer for the synthesis of shape memory polyesters Biomacromolecules 10 2009 2003 2008
90. J. Shin, M.T. Martello, M. Shrestha, J.E. Wissinger, W.B. Tolman, and M.A. Hillmyer Pressure-sensitive adhesives from renewable triblock copolymers Macromolecules 44 2011 87 94
91. B. Lepoittevin, X. Wang, J.-P. Baltaze, H. Liu, J.-M. Herry, M.-N. Bellon-Fontained, and P. Roger Radical polymerization and preliminary microbiological investigation of new polymer derived from myrtenol Eur Polym J 47 2011 1842 1851
92. M.T. Martello, A. Burns, and M. Hillmyer Bulk ring-opening transesterification polymerization of the renewable δ-decalactone using an organocatalyst ACS Macro Lett 1 2012 131 135
93. M. Colonna, C. Berti, M. Fiorini, E. Binassi, M. Mazzacurati, M. Vannini, and S. Karanam Synthesis and radiocarbon evidence of terephthalate polyesters completely prepared from renewable resources Green Chem 13 2011 2543 2548
94. J. Jeromenok, W. Böhlmann, M. Antonietti, and J. Weber Intrinsically microporous polyesters from betulin - toward renewable materials for gas separation made from birch bark Macromol Rapid Commun 32 2011 1846 1851
95. J. Zhang Rosin-based chemicals and polymers 2012 Smithers Rapra Shawbury 250 pp.
96. H. Wang, B. Liu, X. Liu, J. Zhang, and M. Xian Synthesis of biobased epoxy and curing agents using rosin and the study of cure reactions Green Chem 10 2008 1190 1196
97. X. Liu, W. Xin, and J. Zhang Rosin-based acid anhydrides as alternatives to petrochemical curing agents Green Chem 11 2009 1018 1025
98. H. Wang, X. Liu, B. Liu, J. Zhang, and M. Xian Synthesis of rosin-based flexible anhydride-type curing agents and properties of the cured epoxy Polym Int 58 2009 1435 1441
99. X. Liu, W. Xin, and J. Zhang Rosin-derived imide-diacids as epoxy curing agents for enhanced performance Bioresour Technol 101 2010 2520 2524
100. F.R. Mustata, and N. Tudorachi Epoxy resins cross-linked with rosin adduct derivatives: cross-linking and thermal behaviors Ind Eng Chem Res 49 2010 12414 12422
101. J.A. Galbis, and M.G. García Martín Sugars as monomers M.N. Belgacem, A. Gandini, Monomers, polymers and composites from renewable resources 2008 Elsevier Amsterdam 89 114
102. A. Ghadban, and L. Albertin Synthesis of glycopolymer architectures by reversible-deactivation radical polymerization Polymers 5 2013 431 526
103. F. Fenouillot, A. Rousseau, G. Colomines, and R. Saint-Loup Prog Polym Sci 35 2010 578 622
104. M. Rose, and R. Palkovits Isosorbide as a renewable platform chemical for versatile applications - Quo Vadis? ChemSusChem 5 2012 167 176
105. Z.S. Petrovic, M. Ionescu, J. Milic, and E. Eastwood Curing and properties of isosorbide-based epoxy resins 2013 Abstracts of Papers of the 245th Meeting of the American Chemical Society Publ # 603
106. J. Wu, P. Eduard, S. Thiyagarajan, J. van Haveren, D.S. van Es, C.E. Koning, M. Lutz, and C.F. Guerra Isohexide derivatives from renewable resources as chiral building blocks ChemSusChem 5 2011 599 603
107. D.S. van Es Rigid biobased building blocks J Renew Mater 1 2013 61 72
108. S. Thiyagarajan, L. Gootjes, W. Vogelzang, J. Wu, J. van Haveren, and D.S. van Es Chiral building blocks from biomass: 2,5-diamino-2,5-dideoxy-1,4-3,6-dianhydroiditol Tetrahedron 67 2011 383 389
109. L. Jasinska, M. Villani, J. Wu, D.S. van Es, E. Klop, S. Rastogi, and C.E. Koning Novel, fully biobased semicrystalline polyamides Macromolecules 44 2011 3458 3466
110. J. Wu, P. Eduard, S. Thiyagarajan, L. Jasinska-Walc, A. Rozanski, C.F. Guerra, B.A.J. Noordover, J. van Haveren, D.S. van Es, and C.E. Koning Semicrystalline polyesters based on a novel renewable building block Macromolecules 45 2012 5069 5080
111. C. Lavilla, A. Martínez de Ilarduya, A. Alla, M.G. García-Martín, J.A. Galbis, and S. Muñoz-Guerra Bio-based aromatic polyesters from a novel bicyclic diol derived from d-mannitol Macromolecules 45 2012 8257 8266
112. C. Lavilla, A. Martínez de Ilarduya, A. Alla, and S. Muñoz-Guerra PET copolyesters made from a d-mannitol-derived bicyclic diol Polym Chem 4 2013 282 289
113. C. Lavilla, A. Alla, A.M. de Ilarduya, E. Benito, M.G. García-Martín, J.A. Galbis, and S. Muñoz-Guerra Carbohydrate-based polyesters made from bicyclic acetalized galactaric acid Biomacromolecules 12 2011 2642 2652
114. C. Lavilla, A. Alla, A.M. de Ilarduya, E. Benito, M.G. García-Martín, J.A. Galbis, and S. Muñoz-Guerra Carbohydrate-based copolyesters made from bicyclic acetalized galactaric acid J Polym Sci Part A: Polym Chem 50 2012 1591 1604
115. C. Lavilla, A. Alla, A.M. de Ilarduya, E. Benito, M.G. García-Martín, J.A. Galbis, and S. Muñoz-Guerra Bio-based poly(butylene terephthalate) copolyesters containing bicyclic diacetalized galactitol and galactaric acid: influence of composition on properties Polymer 53 2012 3432 3445
116. B. Begines, F. Zamora, M. Violante de Paz, I. Roffé, M. Mancera, and J.A. Galbis Synthesis and characterization of new carbohydrate-based polyureas J Renew Mater 1 2013 212 221
117. B.A.J. Noordover, R. Duchateau, R.A.T.M. van Benthem, W. Ming, and C.E. Koning Enhancing the functionality of biobased polyester coating resins through modification with citric acid Biomacromolecules 8 2007 3860 3870
118. M. Yokoe, K. Aoi, and M. Okada Biodegradable polymers based on renewable resources, IX. Synthesis and degradation behavior of polycarbonates based on 1,4:3,6-dianhydrohexitols and tartaric acid derivatives with pendant functional groups J Polym Sci Part A: Polym Chem 43 2005 3909 3919
119. R. Marín, A. Martínez de Ilarduya, P. Romero, J.R. Sarasua, E. Meaurio, E. Zuza, and S. Muñoz-Guerra Spectroscopic evidence for stereocomplex formation by enantiomeric polyamides derived from tartaric acid Macromolecules 41 2008 3734 3738
120. R. Marín, A. Martínez de Ilarduya, and S. Muñoz-Guerra Linear polyurethanes made from naturally occurring tartaric acid J Polym Sci Part A: Polym Chem 47 2009 2391 2407
121. B. Deebika, S. Balamurugan, and P. Kannan Liquid crystalline H-bonded polymers influenced by chiral and achiral spacers J Polym Res 19 2012 9920 9926
122. Y.-C. Chung, J.W. Choi, D.H. Lee, and B.C. Chun The laterally attached tartaric acid of polyurethane copolymer and its impact on shape memory and low-temperature flexibility J Intell Mater Syst Struct 23 2012 505 513
123. S. Dhamaniya, and J. Jacob Synthesis and characterization of polyesters based on tartaric acid derivatives Polymer 51 2010 5392 5399
124. N. Kihara, and T. Endo Cyclic carbonate and l-lysine derivatives J Polym Sci Part A: Polym Chem 34 1996 2173 2179
125. N. Kihara, K. Makabe, and T. Endo Polycondensation of o-hydroxy carboxylic acid derived from l-phenylalanine and ethylene carbonate J Polym Sci Part A: Polym Chem 34 1996 1819 1822
126. Y.-M. Bao, G.-R. Shen, J. He, and Y.-S. Li Water-soluble hyperbranched poly(ester urethane)s based on d,l-alanine: isocyanate-free synthesis, post-functionalization and application Green Chem 14 2012 2243 2250
127. A. Gandini, and M.N. Belgacem Furan derivatives and furan chemistry at the service of macromolecular materials M.N. Belgacem, A. Gandini, Monomers, polymers and composites from renewable resources 2008 Elsevier Ltd Amsterdam 115 152
128. A. Gandini, and M.N. Belgacem Furans in polymer chemistry Prog Polym Sci 22 1997 1203 1379
129. C. Moreau, M. Naceur, and A. Gandini Recent catalytic advances in the chemistry of substituted furans from carbohydrates and in the ensuing polymers Top Catal 27 2004 11 30
130. A. Gandini Furans as offspring of sugars and polysaccharides and progenitors of a family of remarkable polymers: a review of recent progress Polym Chem 1 2010 245 251
131. A. Gandini Furans as offsprings of sugars and polysaccharides and progenitors of an emblematic family of polymer siblings R.T. Mathers, M.A.R. Meier, Green polymerization methods: renewable starting materials, catalysis and waste reduction 2011 Wiley-VCH Weinheim 29 56
132. A. Gandini Furan monomers and their polymers: synthesis, properties and applications D. Plackett, Biopolymers - new materials for sustainable films and coatings 2011 Wiley-VCH Weinheim 179 209
133. A. Gandini, and M.N. Belgacem Furan resins H. Dodiuk, S.H. Goodman, Handbook of thermoset plastics 2014 Elsevier Ltd Amsterdam 93 110
134. A. Gandini The furan/maleimide Diels-Alder reaction: a versatile click-unclick tool in macromolecular synthesis Prog Polym Sci 38 2013 1 29
135. C. Vilela, A.J.D. Silvestre, and A. Gandini Thermoreversible nonlinear Diels-Alder polymerization of furan/plant oil monomers J Polym Sci Part A: Polym Chem 51 2013 2260 2270
136. A. Gandini, T.M. Lacerda, and A.J.F. Carvalho A straightforward double coupling of furan moieties onto epoxidized triglycerides: synthesis of monomers based on two renewable resources Green Chem 15 2013 1514 1519
137. T.M. Lacerda, and A. Gandini Marriage of furans and vegetable oils through click chemistry for the preparation of macromolecular materials J Renew Mater 2 2014 2 12
138. T.M. Lacerda, A.J.F. Carvalho, and A. Gandini Two alternative approaches to the Diels-Alder polymerization of tung oil RSC Adv 4 2014 26829 26837
139. C. García-Astrain, A. Gandini, D. Coelho, I. Mondragon, A. Retegi, A. Eceiza, M.A. Corcuera, and N. Gabilondo Green chemistry for the synthesis of methacrylate-based hydrogels crosslinked through Diels-Alder reaction Eur Polym J 49 2013 3998 4007
140. X.-H. Jin, D. Sheberla, L.J.W. Shimon, and M. Bendikov Highly coplanar very long oligo(alkylfuran)s: a conjugated system with specific head-to-head defect J Am Chem Soc 136 2014 2592 2601
141. A. Demirbas Biodiesel fuels from vegetable oils via catalytic and non-catalytic supercritical alcohol transesterifications and other methods: a survey Energy Convers Manage 44 2003 2093 2109
142. F. Ma, and M.A. Hanna Biodiesel production: a review Bioresour Technol 70 1999 1 15
143. Y. Chisti Biodiesel from microalgae Biotechnol Adv 25 2007 294 306
144. H. Fukuda, A. Kondo, and H. Noda Biodiesel fuel production by transesterification of oils J Biosci Bioeng 92 2001 405 416
145. Y. Lu, and R.C. Larock Novel polymeric materials from vegetable oils and vinyl monomers: preparation, properties, and applications ChemSusChem 2 2009 136 147
146. M.A.R. Meier, J.O. Metzger, and U.S. Schubert Plant oil renewable resources as green alternatives in polymer science Chem Soc Rev 36 2007 1788 1802
147. Z. Petrovic Polyurethanes from vegetable oils Polym Rev 48 2008 109 155
148. Y. Xia, and R.C. Larock Vegetable oil-based polymeric materials: synthesis, properties, and applications Green Chem 12 2010 1893 1909
149. U. Biermann, U. Bornscheuer, M.A.R. Meier, J.O. Metzger, and H.J. Schäfer Oils and fats as renewable raw materials in chemistry Angew Chem Int Ed 50 2011 3854 3871
150. L. Montero de Espinosa, and M.A.R. Meier Plant oils: the perfect renewable resource for polymer science? Eur Polym J 47 2011 837 852
151. N. Karak Vegetable oil-based polymers: properties, processing and applications 2012 Woodhead Publishing Limited Cambridge 336 pp.
152. G. Lligadas, J.C. Ronda, M. Galià, and V. Cádiz Renewable polymeric materials from vegetable oils: a perspective Mater Today 16 2013 337 343
153. G. Lligadas, J.C. Ronda, M. Galià, and V. Cádiz Monomers and polymers from plant oils via click chemistry reactions J Polym Sci Part A: Polym Chem 51 2013 2111 2124
154. M.A. Mosiewicki, and M.I. Aranguren A short review on novel biocomposites based on plant oil precursors Eur Polym J 49 2013 1243 1256
155. Z.S. Petrović, I. Javni, and M. Ionescu Biological oils as precursors to novel polymeric materials J Renew Mater 1 2013 167 186
156. Y. Xia, R.L. Quirino, and R.C. Larock Bio-based thermosetting polymers from vegetable oils J Renew Mater 1 2013 3 27
157. S. Miao, P. Wang, Z. Su, and S. Zhang Vegetable-oil-based polymers as future polymeric biomaterials Acta Biomater 10 2014 1692 1704
158. F.S. Güner, Y. YaʇcI, and A.T. Erciyes Polymers from triglyceride oils Prog Polym Sci 31 2006 633 670
159. C. Vilela, A.J.D. Silvestre, and A. Gandini Plant oils as purveyors of macromolecular materials - their status in review Ind Crop Prod 2015 [in press]
160. A. Gandini, and T.M. Lacerda Polymers from plant oils 2015 Smithers Rapra Shawbury [in press]
161. M. Galià, L. Montero de Espinosa, J.C. Ronda, G. Lligadas, and V. Cádiz Vegetable oil-based thermosetting polymers Eur J Lipid Sci Technol 112 2010 87 96
162. T.F. Garrison, M.R. Kessler, and R.C. Larock Effects of unsaturation and different ring-opening methods on the properties of vegetable oil-based polyurethane coatings Polymer 55 2014 1004 1011
163. A. Gandini Epoxy polymers based on renewable resources J.P. Pascault, R.J.J. Williams, Epoxy polymers: new materials and innovation 2010 Wiley-VCH Weiheim 55 78
164. H. Pelletier, N. Belgacem, and A. Gandini Acrylated vegetable oils as photocrosslinkable materials J Appl Polym Sci 99 2006 3218 3221
165. H. Pelletier, and A. Gandini Preparation of acrylated and urethanated triacylglycerols Eur J Lipid Sci Technol 108 2006 411 420
166. S.N. Khot, J.J. Lascala, E. Can, S.S. Morye, G.I. Williams, G.R. Palmese, S.H. Kusefoglu, and R.P. Wool Development and application of triglyceride-based polymers and composites J Appl Polym Sci 82 2001 703 723
167. J. La Scala, and R.P. Wool Property analysis of triglyceride-based thermosets Polymer 46 2005 61 69
168. M.A.R. Meier Metathesis with oleochemicals: new approaches for the utilization of plant oils as renewable resources in polymer science Macromol Chem Phys 210 2009 1073 1079
169. A. Rybak, and M.A.R. Meier Cross-metathesis of fatty acid derivatives with methyl acrylate: renewable raw materials for the chemical industry Green Chem 9 2007 1356 1361
170. O. Kreye, T. Tóth, and M.A.R. Meier Poly-α,β-unsaturated aldehydes derived from castor oil via ADMET polymerization Eur J Lipid Sci Technol 113 2011 31 38
171. O. Türünç, and M.A.R. Meier Thiol-ene vs. ADMET: a complementary approach to fatty acid-based biodegradable polymers Green Chem 13 2011 314 320
172. X. Miao, C. Fischmeister, P.H. Dixneuf, C. Bruneau, J.-L. Dubois, and J.-L. Couturier Polyamide precursors from renewable 10-undecenenitrile and methyl acrylate via olefin cross-metathesis Green Chem 14 2012 2179 2183
173. C.O. Akintayo, H. Mutlu, M. Kempf, M. Wilhelm, and M.A.R. Meier Acyclic triene metathesis polymerization of plukenetia conophora oil: branched polymers by direct polymerization of renewable resources Macromol Chem Phys 213 2012 87 96
174. L. Montero de Espinosa, M. Winkler, and M.A.R. Meier Acyclic diene metathesis polymerization and heck polymer-polymer conjugation for the synthesis of star-shaped block copolymers Macromol Rapid Commun 34 2013 1381 1386
175. O. Türünç, and M.A.R. Meier Fatty acid derived monomers and related polymers via thiol-ene (click) additions Macromol Rapid Commun 31 2010 1822 1826
176. A.B. Lowe Thiol-ene "click" reactions and recent applications in polymer and materials synthesis Polym Chem 1 2010 17 36
177. O. Türünç, and M.A.R. Meier The thiol-ene (click) reaction for the synthesis of plant oil derived polymers Eur J Lipid Sci Technol 115 2013 41 54
178. G. Lligadas Renewable polyols for polyurethane synthesis via thiol-ene/yne couplings of plant oils Macromol Chem Phys 214 2013 415 422
179. R.J. González-Paz, G. Lligadas, J.C. Ronda, M. Galià, and V. Cádiz Thiol-yne reaction of alkyne-derivatized fatty acids J Renew Mater 1 2013 187 194
180. D.W. Janes, K. Shanmuganathan, D.Y. Chou, and C.J. Ellison Soybean oil based fibers made without solvent or heat ACS Macro Lett 1 2012 1138 1142
181. C. Lluch, G. Lligadas, J.C. Ronda, M. Galià, and V. Cádiz "Click" synthesis of fatty acid derivatives as fast-degrading polyanhydride precursors Macromol Rapid Commun 32 2011 1343 1351
182. J. Hong, Q. Luo, and B.K. Shah Catalyst- and solvent-free "click" chemistry: a facile approach to obtain cross-linked biopolymers from soybean oil Biomacromolecules 11 2010 2960 2965
183. R.A. Burton, M.J. Gidley, and G.B. Fincher Heterogeneity in the chemistry, structure and function of plant cell walls Nat Chem Biol 6 2010 724 732
184. J. Ralph, K. Lundquist, G. Brunow, F. Lu, H. Kim, P.F. Schatz, J.M. Marita, R.D. Hatfield, S.A. Ralph, J.H. Christensen, and W. Boerjan Lignins: natural polymers from oxidative coupling of 4-hydroxyphenyl-propanoids Phytochem Rev 3 2004 29 60
185. G. Gellerstedt, and G. Henriksson Lignins: major sources, structure and properties M.N. Belgacem, A. Gandini, Monomers, polymers and composites from renewable resources 2008 Elsevier Amsterdam 201 224
186. J. Lora Industrial commercial lignins: sources, properties and applications M.N. Belgacem, A. Gandini, Monomers, polymers and composites from renewable resources 2008 Elsevier Amsterdam 225 242
187. A. Gandini Lignins as components of macromolecular materials M.N. Belgacem, A. Gandini, Monomers, polymers and composites from renewable resources 2008 Elsevier Amsterdam 243 272
188. H. Hatakeyama, and T. Hatakeyama Lignin structure, properties, and applications Adv Polym Sci 232 2010 1 63
189. W.O.S. Doherty, P. Mousavioun, and C.M. Fellows Value-adding to cellulosic ethanol: lignin polymers Ind Crops Prod 33 2011 259 276
190. V.K. Thakur, M.K. Thakur, P. Raghavan, and M.R. Kessler Progress in green polymer composites from lignin for multifunctional applications: a review ACS Sustain Chem Eng 2 2014 1072 1092
191. J.H. Banoub, B. Benjelloun-Mlayah, F. Ziarelli, N. Joly, and M. Delmas Elucidation of the complex molecular structure of wheat straw lignin polymer by atmospheric pressure photoionization quadrupole time-of-flight tandem mass spectrometry Rapid Commun Mass Spectrom 21 2007 2867 2888
192. M. Delmas Vegetal refining agrochemistry Chem Eng Technol 31 2008 792 797
193. M.N. Belgacem, and A. Gandini Partial or total oxypropylation of natural polymers and the use of the ensuing materials as composites or polyol macromonomers M.N. Belgacem, A. Gandini, Monomers, polymers and composites from renewable resources 2008 Elsevier Amsterdam 273 288
194. J.P.S. Aniceto, I. Portugal, and C.M. Silva Biomass-based polyols through oxypropylation reaction ChemSusChem 5 2012 1358 1368
195. C.A. Cateto, M.F. Barreiro, A.E. Rodrigues, and M.N. Belgacem Optimization study of lignin oxypropylation in view of the preparation of polyurethane rigid foams Ind Eng Chem Res 48 2009 2583 2589
196. T. Voitl, and P.R. von Rohr Reply to "Comments on 'demonstration of a process for the conversion of kraft lignin into vanillin and methyl vanillate by acidic oxidation in aqueous methanol"' Ind Eng Chem Res 49 2010 3501 3503
197. E.A. Borges da Silva, M. Zabkova, J.D. Araújo, C.A. Cateto, M.F. Barreiro, M.N. Belgacem, and A.E. Rodrigues An integrated process to produce vanillin and lignin-based polyurethanes from kraft lignin Chem Eng Res Des 87 2009 1276 1292
198. P.C. Rodrigues Pinto, E.A. Borges da Silva, and A.E. Rodrigues Insights into oxidative conversion of lignin to high-added-value phenolic aldehydes Ind Eng Chem Res 50 2011 741 748
199. A.S. Amarasekara, B. Wiredu, and A. Razzaq Vanillin based polymers: I. An electrochemical route to polyvanillin Green Chem 14 2012 2395 2397
200. J.F. Stanzione III, J.M. Sadler, J.J. La Scala, K.H. Reno, and R.P. Wool Vanillin-based resin for use in composite applications Green Chem 14 2012 2346 2352
201. C. Aouf, J. Lecomte, P. Villeneuve, E. Dubreucq, and H. Fulcrand Chemo-enzymatic functionalization of gallic and vanillic acids: synthesis of bio-based epoxy resins prepolymers Green Chem 14 2012 2328 2336
202. L. Mialon, A.G. Pemba, and S.A. Miller Biorenewable polyethylene terephthalate mimics derived from lignin and acetic acid Green Chem 12 2010 1704 1706
203. L. Mialon, R. Vanderhenst, A.G. Pemba, and S.A. Miller Polyalkylenehydroxybenzoates (PAHBs): biorenewable aromatic/aliphatic polyesters from lignin Macromol Rapid Commun 32 2011 1386 1392
204. M. Kleinert, and T. Barth Phenols from lignin Chem Eng Technol 31 2008 736 745
205. J. Zakzeski, and B.M. Weckhuysen Catalytic lignin valorization process for the production of aromatic chemicals and hydrogen ChemSusChem 5 2012 1602 1609
206. 2 oxidation RSC Adv 4 2014 6232 6238
207. A.J. Ragauskas, G.T. Beckham, M.J. Biddy, R. Chandra, F. Chen, M.F. Davis, B.H. Davison, R.A. Dixon, P. Gilna, M. Keller, P. Langan, A.K. Naskar, J.N. Saddler, T.J. Tschaplinski, G.A. Tuskan, and C.E. Wyman Lignin valorization: improving lignin processing in the biorefinery Science 344 2014 1246843/1-10
208. N. Mansouri, A. Pizzi, and J. Salvadó Lignin-based wood panel adhesives without formaldehyde Holz Als Roh- Und Werkst 65 2006 65 70
209. M. Wang, M. Leitch, and C. Xu Synthesis of phenol-formaldehyde resol resins using organosolv pine lignins Eur Polym J 45 2009 3380 3388
210. Y. Jin, X. Cheng, and Z. Zheng Preparation and characterization of phenol-formaldehyde adhesives modified with enzymatic hydrolysis lignin Bioresour Technol 101 2010 2046 2048
211. Y.S. Kim, and J.F. Kadla Preparation of a thermoresponsive lignin-based biomaterial through atom transfer radical polymerization Biomacromolecules 11 2010 981 988
212. T. Saito, R.H. Brown, M.A. Hunt, D.L. Pickel, J.M. Pickel, J.M. Messman, F.S. Baker, M. Kellerd, and A.K. Naskar Turning renewable resources into value-added polymer: development of lignin-based thermoplastic Green Chem 14 2012 3295 3303
213. H. Chung, and N.R. Washburn Improved lignin polyurethane properties with Lewis acid treatment ACS Appl Mater Interfaces 4 2012 2840 2846
214. H. Hatakeyama, and T. Hatakeyama Advances of polyurethane foams derived from lignin J Renew Mater 1 2013 113 123
215. D. Klemm, B. Heublein, H.-P. Fink, and A. Bohn Cellulose: fascinating biopolymer and sustainable raw material Angew Chem Int Ed 44 2005 3358 3393
216. S. Pérez, and D. Samain Structure and engineering of celluloses D. Horton, Advances in carbohydrate chemistry and biochemistry 2010 The American University Washington, DC 25 116
217. M.N. Belgacem, and A. Gandini Production, chemistry and properties of cellulose-based materials D. Plackett, Biopolymers: new materials for sustainable films and coatings 2011 John Wiley and Sons Hoboken, NJ 151 178
218. D. Klemm, B. Philipp, T. Heinze, U. Heinze, and W. Wagenchnecht Comprehensive cellulose chemistry vols. 1 and 2 1998 Wiley-VCH Weinheim 650 pp.
219. D.N.-S. Hon, and N. Shiraishi Wood and cellulose chemistry 2001 Marcel Dekke New York 928 pp.
220. T. Heinze, and K. Petzold Cellulose chemistry: novel products and synthesis paths M.N. Belgacem, A. Gandini, Monomers, polymers and composites from renewable resources 2008 Elsevier Amsterdam 343 368
221. J. Hinestroza, and A.N. Netravali Cellulose based composites 2014 Wiley-VCH Weinheim 328 pp.
222. O. Rojas Cellulose chemistry and properties: materials, fibers and composites Adv Polym Sci 2015 [in press]
223. T. Nishino, I. Matsuda, and K. Hirao All-cellulose composite Macromolecules 37 2004 7683 7687
224. T. Nishino, and N. Arimoto All-cellulose composite prepared by selective dissolving of fiber surface Biomacromolecules 8 2007 2712 2716
225. N. Soykeabkaew, N. Arimoto, T. Nishino, and T. Peijs All-cellulose composites by surface selective dissolution of aligned ligno-cellulosic fibres Compos Sci Technol 68 2008 2201 2207
226. N. Soykeabkaew, C. Sian, S. Gea, T. Nishino, and T. Peijs All-cellulose nanocomposites by surface selective dissolution of bacterial cellulose Cellulose 16 2009 435 444
227. W. Gindl, and J. Keckes All-cellulose nanocomposite Polymer 46 2005 10221 10225
228. W. Gindl, T. Schöberl, and J. Keckes Structure and properties of a pulp fibre-reinforced composite with regenerated cellulose matrix Appl Phys A 83 2006 19 22
229. J.-C. Benoit, Z. Duchemin, R.H. Newman, and M.P. Staiger Phase transformations in microcrystalline cellulose due to partial dissolution Cellulose 14 2007 311 320
230. B.J.C. Duchemin, R.H. Newman, and M.P. Staiger Structure-property relationship of all-cellulose composites Compos Sci Technol 69 2009 1225 1230
231. D. Han, and L. Yan Preparation of all-cellulose composite by selective dissolving of cellulose surface in PEG/NaOH aqueous solution Carbohydr Polym 79 2010 614 619
232. S. Ouajai, and R.A. Shanks Preparation, structure and mechanical properties of all-hemp cellulose biocomposites Compos Sci Technol 69 2009 2119 2126
233. H. Nilsson, S. Galland, P.T. Larsson, E.K. Gamstedt, T. Nishino, L.A. Berglund, and T. Iversen A non-solvent approach for high-stiffness all-cellulose biocomposites based on pure wood cellulose Compos Sci Technol 70 2010 1704 1712
234. A. Junior de Menezes, D. Pasquini, A.A.S. Curvelo, and A. Gandini Self-reinforced composites obtained by the partial oxypropylation of cellulose fibers, 1. Characterization of the materials obtained with different types of fibers Carbohydr Polym 76 2009 437 442
235. A. Junior de Menezes, D. Pasquini, A.A.S. Curvelo, and A. Gandini Self-reinforced composites obtained by the partial oxypropylation of cellulose fibers, 2. Effect of catalyst on the mechanical and dynamic mechanical properties Cellulose 16 2008 239 246
236. D. Klemm, F. Kramer, S. Moritz, T. Lindström, M. Ankerfors, D. Gray, and A. Dorris Nanocelluloses: a new family of nature-based materials Angew Chem Int Ed 50 2011 5438 5466
237. C. Weder, W. Thielemans, M. Roman, S. Renneckar, W. Gindl, S. Veigel, J. Keckes, H. Yano, K. Abe, M. Nogi, A.N. Nakagaito, A. Mangalam, J. Simonsen, A.S. Benight, A. Bismarck, L.A. Berglund, and T.T. Peijs Review: current international research into cellulose nanofibres and nanocomposites J Mater Sci 45 2009 1 33
238. S.J. Eichhorn Cellulose nanowhiskers: promising materials for advanced applications Soft Matter 7 2011 303 315
239. A. Dufresne Nanocellulose: from nature to high performance tailored materials 2012 de Gruyter Berlin 460 pp.
240. K. Missoum, M. Belgacem, and J. Bras Nanofibrillated cellulose surface modification: a review Materials 6 2013 1745 1766
241. Y. Habibi Key advances in the chemical modification of nanocelluloses Chem Soc Rev 43 2014 1519 1542
242. Y. Zhang, T. Nypelö, C. Salas, J. Arboleda, I.C. Hoeger, and O.J. Rojas Cellulose nanofibrils: from strong materials to bioactive surfaces J Renew Mater 1 2013 195 211
243. Y. Habibi, L.A. Lucia, and O.J. Rojas Cellulose nanocrystals: chemistry, self-assembly, and applications Chem Rev 110 2010 3479 3500
244. I. Siró, and D. Plackett Microfibrillated cellulose and new nanocomposite materials: a review Cellulose 17 2010 459 494
245. E. Pecoraro, D.M.Y. Messaddeq, and S.J.L. Ribeiro Bacterial cellulose from Gluconacetobacter xylinus: preparation, properties and applications M.N. Belgacem, A. Gandini, Monomers, polymers and composites from renewable resources 2008 Elsevier Amsterdam 369 384
246. M. Henriksson, L.A. Berglund, P. Isaksson, T. Lindström, and T. Nishino Cellulose nanopaper structures of high toughness Biomacromolecules 9 2008 1579 1585
247. L.A. Berglund, and T. Peijs Cellulose biocomposites - from bulk moldings to nanostructured systems MRS Bull 35 2010 201 207
248. H. Fukuzumi, T. Saito, T. Iwata, Y. Kumamoto, and A. Isogai Transparent and high gas barrier films of cellulose nanofibers prepared by TEMPO-mediated oxidation Biomacromolecules 10 2009 162 165
249. A.N. Nakagaito, and M. Nogi Displays from transparent films of natural nanofibers MRS Bull 35 2010 214 218
250. P. Gatenholm, and D. Klemm Bacterial nanocellulose as a renewable material for biomedical applications MRS Bull 35 2010 208 214
251. E. Trovatti The future of bacterial cellulose and other microbial polysaccharides J Renew Mater 1 2013 28 41
252. A. Gandini, and M.N. Belgacem Modifying cellulose fiber surfaces in the manufacture of natural fiber composites N.E. Zafeiropoulos, Interface engineering in natural fibre composites for maximum performance 2011 Woodhead Publishing Ltd Cambridge 3 42
253. H. Wang, G. Gurau, and R.D. Rogers Ionic liquid processing of cellulose Chem Soc Rev 41 2012 1519 1537
254. A.G. Cunha, and A. Gandini Turning polysaccharides into hydrophobic materials: a critical review, Part 1. Cellulose Cellulose 17 2010 875 889
255. M. Rinaudo Chitin and chitosan: properties and applications Prog Polym Sci 31 2006 603 632
256. C. Peniche, W. Argüelles-Monal, and F.M. Goycoolea Chitin and chitosan: major sources, properties and applications M.N. Belgacem, A. Gandini, Monomers, polymers and composites from renewable resources 2008 Elsevier Amsterdam 517 542
257. S. Fernandes, C.S.R. Freire, C.P. Neto, and A. Gandini The bulk oxypropylation of chitin and chitosan and the characterization of the ensuing polyols Green Chem 10 2008 93 97
258. M. Dash, F. Chiellini, R.M. Ottenbrite, and E. Chiellini Chitosan - a versatile semi-synthetic polymer in biomedical applications Prog Polym Sci 36 2011 981 1014
259. H. Peniche, and C. Peniche Chitosan nanoparticles: a contribution to nanomedicine Polym Int 60 2011 883 889
260. S.C. Fernandes, C.S. Freire, A.J. Silvestre, C. Pascoal Neto, and A. Gandini Novel materials based on chitosan and cellulose Polym Int 60 2011 875 882
261. A.G. Cunha, S.C.M. Fernandes, C.S.R. Freire, A.J.D. Silvestre, C.P. Neto, and A. Gandini What is the real value of chitosan's surface energy? Biomacromolecules 9 2008 610 614
262. A.G. Cunha, and A. Gandini Turning polysaccharides into hydrophobic materials: a critical review, Part 2. Hemicelluloses, chitin/chitosan, starch, pectin and alginates Cellulose 17 2010 1045 1065
263. M.L. Zheludkevich, J. Tedim, C.S.R. Freire, S.C.M. Fernandes, S. Kallip, A. Lisenkov, A. Gandini, and M.G.S. Ferreira Self-healing protective coatings with "green" chitosan based pre-layer reservoir of corrosion inhibitor J Mater Chem 21 2011 4805 4812
264. J. Carneiro, J. Tedim, S.C.M. Fernandes, C.S.R. Freire, A.J.D. Silvestre, A. Gandini, M.G.S. Ferreira, and M.L. Zheludkevich Chitosan-based self-healing protective coatings doped with cerium nitrate for corrosion protection of aluminum alloy 2024 Prog Org Coat 75 2012 8 13
265. J. Carneiro, J. Tedim, S.C.M. Fernandes, C.S.R. Freire, A. Gandini, M.G.S. Ferreira, and M.L. Zheludkevich Chitosan as a smart coating for controlled release of corrosion inhibitor 2-mercaptobenzothiazole ECS Electrochem Lett 2 2013 C19 C22
266. A.J.F. Carvalho Starch: major sources, properties and applications as thermoplastic materials M.N. Belgacem, A. Gandini, Monomers, polymers and composites from renewable resources 2008 Elsevier Amsterdam 321 342
267. A.J.F. Carvalho Starch as source of polymeric materials S. Kalia, L. Avérous, Biopolymers, biomedical and environmental applications 2011 Scrivener Publishing LLC Salem, MA 81 98
268. L.P.B. Jannsen, and L. Moscicki Thermoplastic starch 2009 Wiley-VCH Weinheim 255 pp.
269. F. Xie, P.J. Halley, and L. Avérous Rheology to understand and optimize processibility, structures and properties of starch polymeric materials Prog Polym Sci 37 2012 595 623
270. F. Xie, P. Luckman, J. Milne, L. McDonald, C. Young, and C.Y. Tu Thermoplastic starch J Renew Mater 2 2014 95 106
271. P.J. Halley, and L. Avérous Starch polymers: from genetic engineering to green applications 2014 Elsevier Amsterdam 484 pp.
272. G. Li, P. Sarazin, and B.D. Favis The relationship between starch gelatinization and morphology control in melt-processed polymer blends with thermoplastic starch Macromol Chem Phys 209 2008 991 1002
273. H. Liu, F. Xie, L. Yu, L. Chen, and L. Li Thermal processing of starch-based polymers Prog Polym Sci 34 2009 1348 1368
274. W.-C. Liu, P.J. Halley, and R.G. Gilbert Mechanism of degradation of starch, a highly branched polymer, during extrusion Macromolecules 43 2010 2855 2864
275. A.L. Da Róz, A.A.S. Curvelo, and A. Gandini Preparation and characterization of cross-linked starch polyurethanes Carbohydr Polym 77 2009 526 529
276. J. Hedin, A. Östlund, and M. Nydén UV induced cross-linking of starch modified with glycidyl methacrylate Carbohydr Polym 79 2010 606 613
277. Y. Leng, Y. Zhang, X. Chen, C. Yi, B. Fan, and Q. Wu Hydrophobic thermoplastic starches modified with polyester-based polyurethane microparticles: effects of various diisocyanates Ind Eng Chem Res 50 2011 11130 11135
278. A.J.F. Carvalho, A.A.S. Curvelo, and A. Gandini Surface chemical modification of thermoplastic starch: reactions with isocyanates, epoxy functions and stearoyl chloride Ind Crops Prod 21 2005 331 336
279. A. Sankri, A. Arhaliass, I. Dez, A.C. Gaumont, Y. Grohens, D. Lourdin, I. Pillin, A. Rolland-Sabaté, and E. Leroy Thermoplastic starch plasticized by an ionic liquid Carbohydr Polym 82 2010 256 263
280. D. Le Corre, J. Bras, and A. Dufresne Starch nanoparticles: a review Biomacromolecules 11 2010 1139 1153
281. I.M.G. Martins, S.P. Magina, L. Oliveira, C.S.R. Freire, A.J.D. Silvestre, C. Pascoal Neto, and A. Gandini New biocomposites based on thermoplastic starch and bacterial cellulose Compos Sci Technol 69 2009 2163 2168
282. P.R. Chang, R. Jian, P. Zheng, J. Yu, and X. Ma Preparation and properties of glycerol plasticized-starch (GPS)/cellulose nanoparticle (CN) composites Carbohydr Polym 79 2010 301 305
283. G. Moad Chemical modification of starch by reactive extrusion Prog Polym Sci 36 2011 218 237
284. Carvalho AJF. Thermoplastic starch modification by reactive extrusion: depolymerization/poymerization processing. Private communication; 2014.
285. T.S. Nossa, M.N. Belgacem, A. Gandini, and A.J.F. Carvalho Thermoreversible crosslinked thermoplastic starch Polym Int 2015 [submitted for publication]
286. A. Junior de Menezes, D. Pasquini, A.A.S. Curvelo, and A. Gandini Oxypropylation of corn starch granules Biomacromolecules 8 2007 2047 2050
287. C. Lan, L. Yu, P. Chen, L. Chen, W. Zou, G. Simon, and X. Zhang Design, preparation and characterization of self-reinforced starch films through chemical modification Macromol Mater Eng 295 2010 1025 1030
288. T. Liebert, M.C.V. Nagel, T. Jordan, A. Heft, B. Grünler, and T. Heinze Pure, transparent-melting starch esters: synthesis and characterization Macromol Rapid Commun 32 2011 1312 1318
289. L. Avérous Polylactic acid: synthesis, properties and applications M.N. Belgacem, A. Gandini, Monomers, polymers and composites from renewable resources 2008 Elsevier Amsterdam 433 450
290. A. Auras, L.-T. Lim, S.E.M. Selke, and H. Tsuji Poly(lactic acid): synthesis, structures, properties, processing and applications 2011 Wiley-VCH Weinheim 499 pp.
291. L.T. Sin, A.R. Rahmat, and W.A.W.A. Rahman Polylactic acid 2012 Elsevier Ltd Amsterdam 352 pp.
292. I. Chodak Polyhydroxyalkanoates: origin, properties and applications M.N. Belgacem, A. Gandini, Monomers, polymers and composites from renewable resources 2008 Elsevier Amsterdam 451 478
293. G.-Q. Chen A microbial polyhydroxyalkanoates (PHA) based bio- and materials industry Chem Soc Rev 38 2009 2434 2446
294. K. Sudesh, and H. Abe Practical guide to microbial polyhydroxyalkanoates 2010 Smithers Rapra Akron 160 pp.
295. T.G. Volova Polyhydroxyalkanoates - plastic materials of the 21st century: production, properties and applications 2014 Nova Publishers New York 282 pp.
296. I. Spiridon, and V.I. Popa Hemicelluloses: major sources, properties and applications M.N. Belgacem, A. Gandini, Monomers, polymers and composites from renewable resources 2008 Elsevier Amsterdam 289 304
297. M. Rinaudo Polyelectrolytes derived from natural polysaccharides M.N. Belgacem, A. Gandini, Monomers, polymers and composites from renewable resources 2008 Elsevier Amsterdam 495 516
298. K.J. Edgar, T. Heinze, and C.M. Buchanan Polysaccharide materials: performance by design Symposium series vol. 1017 2009 American Chemical Society Washington, DC 292 pp.
299. L. Zhang, and M. Zeng Proteins as sources of materials M.N. Belgacem, A. Gandini, Monomers, polymers and composites from renewable resources 2008 Elsevier Amsterdam 479 494
300. C.J.R. Verbeek, and L.E. van den Berg Extrusion processing and properties of protein-based thermoplastics Macromol Mater Eng 295 2010 10 21
301. O.S. Rabotyagova, P. Cebe, and D.L. Kaplan Protein-based block copolymers Biomacromolecules 12 2011 269 289
302. S. Khosravi, F. Khabbaz, P. Nordqvist, and M. Johansson Protein-based adhesives for particleboards Ind Crops Prod 32 2010 275 283
303. A.J.D. Silvestre, C. Pascoal Neto, and A. Gandini Cork and suberins: major sources, properties, applications M.N. Belgacem, A. Gandini, Monomers, polymers and composites from renewable resources 2008 Elsevier Amsterdam 305 320
304. K. Ranathunge, L. Schreiber, and R. Franke Suberin research in the genomics era - new interest for an old polymer Plant Sci 180 2011 399 413
305. O. Serra, S. Chatterjee, M. Figueras, M. Molinas, and R.E. Stark Deconstructing a plant macromolecular assembly: chemical architecture, molecular flexibility, and mechanical performance of natural and engineered potato suberins Biomacromolecules 15 2014 799 811
306. A.F. Sousa, A. Gandini, A.J.D. Silvestre, and C. Pascoal Neto Novel suberin-based biopolyesters: from synthesis to properties J Polym Sci Part A: Polym Chem 49 2011 2281 2291
307. A.F. Sousa, A.J.D. Silvestre, A. Gandini, and C. Pascoal Neto Synthesis of aliphatic suberin-like polyesters by ecofriendly catalytic systems High Perform Polym 24 2012 4 8
308. H. Garcia, R. Ferreira, C. Martins, A.F. Sousa, C.S.R. Freire, A.J.D. Silvestre, W. Kunz, L.P.N. Rebelo, and C.S. Pereira Ex situ reconstitution of the plant biopolyester suberin as a film Biomacromolecules 15 2014 1806 1813
309. E. Trovatti, A.J.F. Carvalho, S.J.L. Ribeiro, and A. Gandini Simple green approach to reinforce natural rubber with bacterial cellulose nano fibers Biomacromolecules 14 2013 2667 2674
310. M.A. Hillmyer, and W.B. Tolman Aliphatic polyester block polymers: renewable, degradable, and sustainable Acc Chem Res 47 2014 2390 2396
311. A. Pizzi Bioadhesives for wood and fibers: a critical review Rev Adhesion Adhesives 1 2013 88 113
312. X. Li, M.C. Basso, F.L. Braghiroli, V. Fierro, A. Pizzi, and A. Celzard Tailoring the structure of cellular vitreous carbon foams Carbon 50 2012 2026 2036
313. A. Morelli, D. Puppi, and F. Chiellini Polymers from renewable resources: perspectives in biomedical applications J Renew Mater 1 2013 83 112