Organocatalytic enamine-activation of cyclopropanes for highly stereoselective formation of cyclobutanes

Journal of the American Chemical Society

Volumn 137, Issue 4, 2015, Pages 1685-1691

  Halskov, Kim Søholm ^a   Kniep, Florian ^a   Lauridsen, Vibeke Henriette ^a   Iversen, Eva Høgh ^a   Donslund, Bjarke Skyum ^a   Jørgensen, Karl Anker ^a  

^a AARHUS UNIVERSITY   (Denmark)

Author keywords

[No Author keywords available]

Indexed keywords

CHEMICAL ACTIVATION; REACTION INTERMEDIATES; STEREOSELECTIVITY;

DIASTEREOMERIC RATIOS; DONOR-ACCEPTOR CYCLOPROPANES; ENANTIOMERIC EXCESS; EXPERIMENTAL APPROACHES; IN-SITU CONDENSATIONS; ORBITAL INTERACTION; SECONDARY AMINES; STEREOSELECTIVE FORMATION;

PROPANE;

ACETALDEHYDE; BENZOFURAN DERIVATIVE; CYCLOBUTANE DERIVATIVE; CYCLOPROPANE DERIVATIVE; ENAMINE; INDOLE DERIVATIVE; OXINDOLE; SPIROCYCLOBUTANEBENZOFURANONE; SPIROCYCLOBUTANEOXINDOLE; UNCLASSIFIED DRUG;

ARTICLE; CATALYSIS; CATALYST; COVALENT BOND; CYCLOADDITION; DIASTEREOISOMER; ENANTIOMER; ENANTIOSELECTIVITY; REACTION TIME; RING OPENING; STEREOCHEMISTRY;

EID: 84922425029     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja512573q     Document Type: Article

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