Ketyl-type radicals from cyclic and acyclic esters are stabilized by SmI2(H2O)n: the role of SmI2(H 2O)n in post-electron transfer steps

Journal of the American Chemical Society

Volumn 136, Issue 23, 2014, Pages 8459-8466

  Szostak, Michal ^a   Spain, Malcolm ^a   Procter, David J ^a  

^a UNIVERSITY OF MANCHESTER   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

ELECTRON TRANSITIONS; ESTERS;

CARBOXYLIC ACID DERIVATIVES; CHEMOSELECTIVE; ELECTRON TRANSFER; EXPERIMENTAL EVIDENCE; MECHANISM-BASED; REDUCTIVE COUPLINGS; SECOND ELECTRONS; THERMODYNAMIC CONTROL;

FREE RADICAL REACTIONS;

ANION; CARBONYL DERIVATIVE; CARBOXYLIC ACID DERIVATIVE; LACTONE; RADICAL; SAMARIUM; SAMARIUM IODIDE; UNCLASSIFIED DRUG; WATER;

ARTICLE; CYCLIZATION; ELECTRON TRANSPORT; OXIDATION REDUCTION POTENTIAL; PROTON TRANSPORT; THERMODYNAMICS;

EID: 84902256705     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja503494b     Document Type: Article

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