Substrate-directable electron transfer reactions. Dramatic rate enhancement in the chemoselective reduction of cyclic esters using SmI2-H 2O: Mechanism, scope, and synthetic utility

Journal of the American Chemical Society

Volumn 135, Issue 42, 2013, Pages 15702-15705

  Szostak, Michal ^a   Spain, Malcolm ^a   Choquette, Kimberly A ^b   Flowers, Robert A ^b   Procter, David J ^a  

^a UNIVERSITY OF MANCHESTER   (United Kingdom)

^b LEHIGH UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CARBON; ESTERS; FREE RADICAL REACTIONS; REDUCTION;

CARBON-CARBON BOND; CHEMOSELECTIVE REDUCTION; ELECTRON-TRANSFER REACTIONS; EXPERIMENTAL EVIDENCE; ORGANIC SYNTHESIS; RADICAL MECHANISM; SYNTHETIC APPLICATION; SYNTHETIC UTILITY;

SAMARIUM COMPOUNDS;

CARBON; ESTER; LACTONE; SAMARIUM DIIODIDE; WATER; ALCOHOL DERIVATIVE; IODIDE; SAMARIUM;

ARTICLE; CHELATION; CHEMICAL BOND; CYCLIZATION; ELECTRON; ELECTRON TRANSPORT; MOLECULAR MECHANICS; SYNTHESIS; CHEMICAL STRUCTURE; CHEMISTRY; OXIDATION REDUCTION REACTION;

ALCOHOLS; ELECTRONS; ESTERS; IODIDES; MOLECULAR STRUCTURE; OXIDATION-REDUCTION; SAMARIUM; WATER;

EID: 84886458189     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja4078864     Document Type: Article

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