SmI2-induced umpolung of the C=N bond: First reductive conjugate addition of nitrones to α,β-unsaturated esters

Angewandte Chemie - International Edition

Volumn 42, Issue 20, 2003, Pages 2265-2268

  Masson, Géraldine ^a   Cividino, Pascale ^a   Py, Sandrine ^a   Vallée, Yannick ^a  

^a UNIVERSITÉ JOSEPH FOURIER   (France)

Author keywords

Amino acids; Chiral auxiliaries; Nitrones; Samarium; Umpolung

Indexed keywords

AMINO ACIDS; CHEMICAL BONDS; NITROGEN;

STEREOSELECTION;

ESTERS;

AMINO ACID DERIVATIVE; ESTER DERIVATIVE; NITRONE DERIVATIVE; SAMARIUM DIIODIDE;

ARTICLE; CHEMICAL ANALYSIS; CHEMICAL BOND; CHEMICAL REACTION; CHEMICAL STRUCTURE; REDUCTION; STEREOCHEMISTRY;

EID: 0038319141     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200250480     Document Type: Article

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