Mechanistic study of the SmI2/H2O/amine-mediated reduction of alkyl halides: Amine base strength (pKBH+) dependent rate

Journal of the American Chemical Society

Volumn 127, Issue 23, 2005, Pages 8340-8347

  Dahlén, Anders ^a   Hilmersson, Göran ^a  

^a Department of Chemistry ^*  (Sweden)

Author keywords

[No Author keywords available]

Indexed keywords

ACTIVATION ANALYSIS; CHEMICAL ACTIVATION; CHEMICAL BONDS; HALOGEN COMPOUNDS; ISOTOPES; RATE CONSTANTS; REDUCTION;

ACTIVATION PARAMETERS; ALKYL HALIDES; AMINE-MEDIATED REDUCTION; CARBON-HALIDE BONDS;

AMINES;

1 BROMODECANE; 1 CHLORODECANE; 1 IODODECANE; ALKYL GROUP; AMINE; CARBON 13; DECANE; HALIDE; UNCLASSIFIED DRUG;

ARTICLE; CATALYSIS; CHEMICAL BOND; CHEMICAL REACTION KINETICS; CHEMICAL STRUCTURE; TEMPERATURE DEPENDENCE; TEMPERATURE SENSITIVITY;

EID: 20444492751     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja043323u     Document Type: Article

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