Quantitative voltammetry of the reduction of methyl benzoate in thf reveals strong ion pairing of the radical anion with tetra-n-butyl cations

Journal of Physical Organic Chemistry

Volumn 22, Issue 3, 2009, Pages 247-253

  Baron, Ronan ^a   Kershaw, Neil M ^a   Donohoe, Timothy J ^a   Compton, Richard G ^a  

^a UNIVERSITY OF OXFORD   (United Kingdom)

Author keywords

Cryoelectrochemistry; Diffusion coefficients; Electrode reaction mechanisms; Ion pairs; Microelectrodes; Single electron transfer; TBAP; Tetrahydrofuran

Indexed keywords

ACTIVATION ANALYSIS; ACTIVATION ENERGY; ARRHENIUS PLOTS; CHRONOAMPEROMETRY; DIFFUSION; ELECTROLYSIS; ELECTRON TRANSITIONS; FREE RADICAL REACTIONS; MICROELECTRODES; NEGATIVE IONS; PLATINUM; POSITIVE IONS; RATE CONSTANTS; REDUCTION; SURFACE DEFECTS; SURFACE DIFFUSION;

CRYOELECTROCHEMISTRY; DIFFUSION COEFFICIENTS; ELECTRODE REACTION MECHANISMS; ION PAIRS; SINGLE ELECTRON TRANSFER; TBAP; TETRAHYDROFURAN;

CYCLIC VOLTAMMETRY;

EID: 62649162784     PISSN: 08943230     EISSN: 10991395     Source Type: Journal    
DOI: 10.1002/poc.1462     Document Type: Article

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