Importance of C-N bond rotation in N-acyl oxazolidinones in their SmI 2-promoted coupling to acrylamides

Journal of the American Chemical Society

Volumn 131, Issue 29, 2009, Pages 10253-10262

  Taaning, Rolf H ^a   Lindsay, Karl B ^a   Schiøtt, Birgit ^a   Daasbjerg, Kim ^a   Skrydstrup, Troels ^a  

^a AARHUS UNIVERSITY   (Denmark)

Author keywords

[No Author keywords available]

Indexed keywords

ACRYLAMIDE; ACRYLAMIDES; ACTIVATION BARRIERS; BENEFICIAL EFFECTS; BIDENTATE COORDINATION; BOND ROTATIONS; C-C BOND FORMATION; CARBON-CARBON BOND; CHIRAL AUXILIARIES; DFT CALCULATION; DOMINATING FACTORS; IMIDE DERIVATIVES; LEWIS ACID; LINEAR CORRELATION; ORGANIC REACTION; OXAZOLIDINONE; OXAZOLIDINONES; PRODUCT DISTRIBUTIONS; RELATIVE REACTIVITIES; S-TRANS; TRANSITION-STATE;

ACTIVATION ENERGY; AMIDES; COMPETITION; COORDINATION REACTIONS; HYDROGELS; PARAFFINS; SULFUR COMPOUNDS;

ROTATION;

ACRYLAMIDE DERIVATIVE; CARBON; IMIDE; LEWIS ACID; NITROGEN; OXAZOLIDINONE DERIVATIVE;

AB INITIO CALCULATION; ARTICLE; CHEMICAL BOND; CHEMICAL REACTION; CIS TRANS ISOMERISM; CONFORMATION; ELECTRON TRANSPORT; ENERGY; KINETICS;

ACRYLAMIDES; CARBON; MOLECULAR STRUCTURE; NITROGEN; OXAZOLIDINONES; ROTATION; STEREOISOMERISM;

EID: 67651218646     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja903401y     Document Type: Article

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