Surface-active organics in atmospheric aerosols

Topics in Current Chemistry

Volumn 339, Issue , 2014, Pages 201-260

  McNeill, V Faye ^a   Sareen, Neha ^a   Schwier, Allison N ^a  

^a Columbia University ^*  (United States)

Author keywords

Aerosol; Cloud condensation nuclei; Surface tension; Surfactant

Indexed keywords

EID: 84887118341     PISSN: 03401022     EISSN: None     Source Type: Book Series    
DOI: 10.1007/128-2012-404     Document Type: Article

References (299)

1. Forster P, Ramaswamy V, Artaxo P, Berntsen T, Betts R, Fahey DW, Haywood J, Lean J, Lowe DC, Myhre G, Nganga J, Prinn R, Raga G, Schulz M, Van Dorland R (2007) Changes in atmospheric constituents and in radiative forcing. In: Solomon S, Qin D, Manning M, Chen Z, Marquis M, Averyt KB, Tignor M, Miller HL (eds) Climate change 2007: The physical science basis. Contribution of working group I to the fourth assessment report of the intergovernmental panel on climate change. Cambridge University Press, Cambridge
2. Jimenez JL, Canagaratna MR, Donahue NM, Prevot ASH, Zhang Q, Kroll JH, DeCarlo PF, Allan JD, Coe H, Ng NL, Aiken AC, Docherty KS, Ulbrich IM, Grieshop AP, Robinson AL, Duplissy J, Smith JD, Wilson KR, Lanz VA, Hueglin C, Sun YL, Tian J, Laaksonen A, Raatikainen T, Rautiainen J, Vaattovaara P, Ehn M, Kulmala M, Tomlinson JM, Collins DR, Cubison MJ, Dunlea EJ, Huffman JA, Onasch TB, Alfarra MR, Williams PI, Bower K, Kondo Y, Schneider J, Drewnick F, Borrmann S, Weimer S, Demerjian K, Salcedo D, Cottrell L, Griffin R, Takami A, Miyoshi T, Hatakeyama S, Shimono A, Sun JY, Zhang YM, Dzepina K, Kimmel JR, Sueper D, Jayne JT, Herndon SC, Trimborn AM, Williams LR, Wood EC, Middlebrook AM, Kolb CE, Baltensperger U, Worsnop DR (2009) Evolution of organic aerosols in the atmosphere. Science 326:1525-1529
3. Kanakidou M, Seinfeld JH, Pandis SN, Barnes I, Dentener FJ, Facchini MC, Van Dingenen R, Ervens B, Nenes A, Nielsen CJ, Swietlicki E, Putaud JP, Balkanski Y, Fuzzi S, Horth J, Moortgat GK, Winterhalter R, Myhre CEL, Tsigaridis K, Vignati E, Stephanou EG, Wilson J (2005) Organic aerosol and global climate modelling: A review. Atmos Chem Phys 5:1053-1123
4. Ellison GB, Tuck AF, Vaida V (1999) Atmospheric processing of organic aerosols. J Geophys Res Atmos 104:11633-11641
5. Gill PS, Graedel TE, Weschler CJ (1983) Organic films on atmospheric aerosol-particles, fog droplets, cloud droplets, raindrops, and snowflakes. Rev Geophys 21:903-920
6. Cistola DP, Hamilton JA, Jackson D, Small DM (1988) Ionization and phase-behavior of fatty-acids in water - Application of the Gibbs phase rule. Biochemistry 27:1881-1888
7. Leck C, Bigg EK (2005) Biogenic particles in the surface microlayer and overlaying atmosphere in the central Arctic Ocean during summer. Tellus B 57:305-316
8. Leck C, Bigg EK (2005) Source and evolution of the marine aerosol - A new perspective. Geophys Res Lett 32:L19803. doi:10.1029/2005GL023651
9. Posfai M, Gelencser A, Simonics R, Arato K, Li J, Hobbs PV, Buseck PR (2004) Atmospheric tar balls: Particles from biomass and biofuel burning. J Geophys Res Atmos 109: D06213. doi:10.1029/2003JD004169
10. Reid JP, Dennis-Smither BJ, Kwamena NO, Miles REH, Hanford KL, Homer CJ (2011) The morphology of aerosol particles consisting of hydrophobic and hydrophilic phases: Hydrocarbons, alcohols and fatty acids as the hydrophobic component. Phys Chem Chem Phys 13:15559-15572
11. Tabazadeh A (2005) Organic aggregate formation in aerosols and its impact on the physicochemical properties of atmospheric particles. Atmos Environ 39:5472-5480
12. Bertram AK, Martin ST, Hanna SJ, Smith ML, Bodsworth A, Chen Q, Kuwata M, Liu A, You Y, Zorn SR (2011) Predicting the relative humidities of liquid-liquid phase separation, efflorescence, and deliquescence of mixed particles of ammonium sulfate, organic material, and water using the organic-to-sulfate mass ratio of the particle and the oxygen-to-carbon elemental ratio of the organic component. Atmos Chem Phys 11:10995-11006
13. Tong H-J, Reid JP, Bones DL, Luo BP, Krieger UK (2011) Measurements of the timescales for the mass transfer of water in glassy aerosol at low relative humidity and ambient temperature. Atmos Chem Phys 11:4739-4754
14. Zobrist B, Marcolli C, Pedernera DA, Koop T (2008) Do atmospheric aerosols form glasses? Atmos Chem Phys 8:5221-5244
15. Blanchard DC (1964) Sea-to-air transport of surface active material. Science 146:396-397
16. Buseck PR, Posfai M (1999) Airborne minerals and related aerosol particles: Effects on climate and the environment. Proc Natl Acad Sci USA 96:3372-3379
17. Peterson RE, Tyler BJ (2002) Analysis of organic and inorganic species on the surface of atmospheric aerosol using time-of-flight secondary ion mass spectrometry (TOF-SIMS). Atmos Environ 36:6041-6049
18. Peterson RE, Tyler BJ (2003) Surface composition of atmospheric aerosol: Individual particle characterization by TOF-SIMS. Appl Surf Sci 203:751-756
19. Russell LM, Maria SF, Myneni SCB (2002) Mapping organic coatings on atmospheric particles. Geophys Res Lett 29. doi:10.1029/2002GL014874
20. Tervahattu H, Hartonen K, Kerminen VM, Kupiainen K, Aarnio P, Koskentalo T, Tuck AF, Vaida V (2002) New evidence of an organic layer on marine aerosols. J Geophys Res Atmos 107:4053. doi:10.1029/2000JD000282
21. Tervahattu H, Juhanoja J, Kupiainen K (2002) Identification of an organic coating on marine aerosol particles by TOF-SIMS. J Geophys Res Atmos 107:4319. doi:10.1029/ 2001JD001403
22. Tervahattu H, Juhanoja J, Vaida V, Tuck AF, Niemi JV, Kupiainen K, Kulmala M, Vehkamaki H (2005) Fatty acids on continental sulfate aerosol particles. J Geophys Res Atmos 110. doi:10.1029/2004JD005400
23. Takahama S, Liu S, Russell LM (2010) Coatings and clusters of carboxylic acids in carboncontaining atmospheric particles from spectromicroscopy and their implications for cloudnucleating and optical properties. J Geophys Res Atmos 115. doi:10.1029/2009JD012622
24. Pfann WG, Olsen KM (1953) Purification and prevention of segregation in single crystals of germanium. Phys Rev 89:322-323
25. Asa-Awuku A, Sullivan AP, Hennigan CJ, Weber RJ, Nenes A (2008) Investigation of molar volume and surfactant characteristics of water-soluble organic compounds in biomass burning aerosol. Atmos Chem Phys 8:799-812
26. Cavalli F, Facchini MC, Decesari S, Mircea M, Emblico L, Fuzzi S, Ceburnis D, Yoon YJ, O'Dowd CD, Putaud JP, Dell'Acqua A (2004) Advances in characterization of size-resolved organic matter in marine aerosol over the North Atlantic. J Geophys Res Atmos 109.doi:10.1029/2004JD005137
27. Decesari S, Facchini MC, Mircea M, Cavalli F, Fuzzi S (2003) Solubility properties of surfactants in atmospheric aerosol and cloud/fog water samples. J Geophys Res Atmos 108:4685. doi:10.1029/2003JD003566
28. Facchini MC, Decesari S, Mircea M, Fuzzi S, Loglio G (2000) Surface tension of atmospheric wet aerosol and cloud/fog droplets in relation to their organic carbon content and chemical composition. Atmos Environ 34:4853-4857
29. Kiss G, Tombacz E, Hansson HC (2005) Surface tension effects of humic-like substances in the aqueous extract of tropospheric fine aerosol. J Atmos Chem 50:279-294
30. Salma I, Ocskay R, Varga I, Maenhaut W (2006) Surface tension of atmospheric humic-like substances in connection with relaxation, dilution, and solution pH. J Geophys Res Atmos 111:D23205. doi:10.1029/2005JD007015
31. Taraniuk I, Graber ER, Kostinski A, Rudich Y (2007) Surfactant properties of atmospheric and model humic-like substances (HULIS). Geophys Res Lett 34:L16807. doi:10.1029/ 2007GL029576
32. Facchini MC, Mircea M, Fuzzi S, Charlson RJ (1999) Cloud albedo enhancement by surfaceactive organic solutes in growing droplets. Nature 401:257-259
33. Mazurek AZ, Pogorzelski SJ, Kogut AD (2006) A novel approach for structure quantification of fatty acids films on rain water. Atmos Environ 40:4076-4087
34. Keene WC, Pszenny AAP, Maben JR, Stevenson E, Wall A (2004) Closure evaluation of size-resolved aerosol pH in the New England coastal atmosphere during summer. J Geophys Res Atmos 109:D23202. doi:10.1029/2004JD004801
35. Zhang Q, Jimenez JL, Worsnop DR, Canagaratna M (2007) A case study of urban particle acidity and its influence on secondary organic aerosol. Environ Sci Technol 41:3213-3219
36. Buajarern J, Mitchem L, Reid JP (2007) Characterizing the formation of organic layers on the surface of inorganic/aqueous aerosols by Raman spectroscopy. J Phys Chem A 111:11852-11859
37. Voss LF, Bazerbashi MF, Beekman CP, Hadad CM, Allen HC (2007) Oxidation of oleic acid at air/liquid interfaces. J Geophys Res Atmos 112:D06209. doi:10.1029/2006JD007677
38. Voss LF, Hadad CM, Allen HC (2006) Competition between atmospherically relevant fatty acid monolayers at the air/water interface. J Phys Chem B 110:19487-19490
39. King MD, Rennie AR, Thompson KC, Fisher FN, Dong CC, Thomas RK, Pfrang C, Hughes AV (2009) Oxidation of oleic acid at the air-water interface and its potential effects on cloud critical supersaturations. Phys Chem Chem Phys 11:7699-7707
40. Rogge WF, Mazurek MA, Hildemann LM, Cass GR, Simoneit BRT (1993) Quantification of urban organic aerosols at a molecular-level - identification, abundance and seasonalvariation. Atmos Environ Part A 27:1309-1330
41. Schauer JJ, Kleeman MJ, Cass GR, Simoneit BRT (2001) Measurement of emissions from air pollution sources. 3. C-1-C-29 organic compounds from fireplace combustion of wood. Environ Sci Technol 35:1716-1728
42. Simoneit BRT, Schauer JJ, Nolte CG, Oros DR, Elias VO, Fraser MP, Rogge WF, Cass GR (1999) Levoglucosan, a tracer for cellulose in biomass burning and atmospheric particles. Atmos Environ 33:173-182
43. Hildemann LM, Markowski GR, Cass GR (1991) Chemical composition of emissions from urban sources of fine organic aerosol. Environ Sci Technol 25:744-759
44. Meyers PA, Hites RA (1982) Extractable organic compounds in midwest rain and snow. Atmos Environ 16:2169-2175
45. Rogge WF, Hildemann LM, Mazurek MA, Cass GR, Simoneit BRT (1993) Sources of fine organic aerosol. 4. Particulate abrasion products from leaf surfaces of urban plants. Environ Sci Technol 27:2700-2711
46. Simoneit BRT (1977) Organic matter in eolian dusts over the Atlantic Ocean. Mar Chem 5:443-464
47. Simoneit BRT, Mazurek MA (1982) Organic-matter of the troposphere. 2. Natural background of biogenic lipid matter in aerosols over the rural Western United-States. Atmos Environ 16:2139-2159
48. Zhang Q, Anastasio C (2003) Free and combined amino compounds in atmospheric fine particles (PM2.5) and fog waters from Northern California. Atmos Environ 37:2247-2258
49. Fraser MP, Cass GR, Simoneit BRT (1999) Particulate organic compounds emitted from motor vehicle exhaust and in the urban atmosphere. Atmos Environ 33:2715-2724
50. Grosjean D, Vancauwenberghe K, Schmid JP, Kelley PE, Pitts JN (1978) Identification of C3-C10 aliphatic dicarboxylic-acids in airborne particulate matter. Environ Sci Technol 12:313-317
51. Kawamura K, Kaplan IR (1987) Motor exhaust emissions as a primary source for dicarboxylic-acids in Los-Angeles ambient air. Environ Sci Technol 21:105-110
52. Kawamura K, Ng LL, Kaplan IR (1985) Determination of organic acids (C1-C10) in the atmosphere, motor exhausts, and engine oils. Environ Sci Technol 19:1082-1086
53. Rogge WF, Hildemann LM, Mazurek MA, Cass GR, Simoneit BRT (1993) Sources of fine organic aerosol. 2. Noncatalyst and catalyst-equipped automobiles and heavy-duty diesel trucks. Environ Sci Technol 27:636-651
54. Rogge WF, Hildemann LM, Mazurek MA, Cass GR, Simoneit BRT (1993) Sources of fine organic aerosol. 3. Road dust, tire debris, and organometallic brake lining dust: Roads as sources and sinks. Environ Sci Technol 27:1892-1904
55. Schauer JJ, Kleeman MJ, Cass GR, Simoneit BRT (1999) Measurement of emissions from air pollution sources. 2. C-1 through C-30 organic compounds from medium duty diesel trucks. Environ Sci Technol 33:1578-1587
56. Schauer JJ, Kleeman MJ, Cass GR, Simoneit BRT (2002) Measurement of emissions from air pollution sources. 5. C-1-C-32 organic compounds from gasoline-powered motor vehicles. Environ Sci Technol 36:1169-1180
57. Simoneit BRT (1985) Application of molecular marker analysis to vehicular exhaust for source reconciliations. Int J Environ Anal Chem 22:203-232
58. Sodeman D, Toner SM, Prather KA (2005) Determination of single particle mass spectral signatures from light-duty vehicle emissions. Environ Sci Technol 39:4569-4580
59. Warneck P (2003) In-cloud chemistry opens pathway to the formation of oxalic acid in the marine atmosphere. Atmos Environ 37:2423-2427
60. Cheng Y, Li SM, Leithead A, Brickell PC, Leaitch WR (2004) Characterizations of cispinonic acid and n-fatty acids on fine aerosols in the Lower Fraser Valley during Pacific 2001 Air Quality Study. Atmos Environ 38:5789-5800
61. He LY, Hu M, Huang XF, Yu BD, Zhang YH, Liu DQ (2004) Measurement of emissions of fine particulate organic matter from Chinese cooking. Atmos Environ 38:6557-6564
62. Robinson AL, Subramanian R, Donahue NM, Bernardo-Bricker A, Rogge WF (2006) Source apportionment of molecular markers and organic aerosol. 3. Food cooking emissions. Environ Sci Technol 40:7820-7827
63. Rogge WF, Hildemann LM, Mazurek MA, Cass GR, Simonelt BRT (1991) Sources of fine organic aerosol. 1. Charbroilers and meat cooking operations. Environ Sci Technol 25:1112-1125
64. Schauer JJ, Kleeman MJ, Cass GR, Simoneit BRT (1999) Measurement of emissions from air pollution sources. 1. C-1 through C-29 organic compounds from meat charbroiling. Environ Sci Technol 33:1566-1577
65. Schauer JJ, Kleeman MJ, Cass GR, Simoneit BRT (2002) Measurement of emissions from air pollution sources. 4. C-1-C-27 organic compounds from cooking with seed oils. Environ Sci Technol 36:567-575
66. Schauer JJ, Rogge WF, Hildemann LM, Mazurek MA, Cass GR (1996) Source apportionment of airborne particulate matter using organic compounds as tracers. Atmos Environ 30:3837-3855
67. Zhao Y, Hu M, Slanina S, Zhang Y (2007) Chemical compositions of fine particulate organic matter emitted from Chinese cooking. Environ Sci Technol 41:99-105
68. Barger WR, Garrett WD (1970) Surface active organic material in the marine atmosphere. J Geophys Res 75:4561-4566
69. Bezdek HF, Carlucci AF (1974) Concentration and removal of liquid microlayers from a seawater surface by bursting bubbles. Limnol Oceanogr 19:126-132
70. Garrett WD (1967) The organic chemical composition of the ocean surface. Deep Sea Res Oceanographic Abstracts 14:221-227
71. Gershey RM (1983) Characterization of seawater organic-matter carried by bubble-generated aerosols. Limnol Oceanogr 28:309-319
72. Kawamura K, Gagosian RB (1987) Implications of [omega]-oxocarboxylic acids in the remote marine atmosphere for photo-oxidation of unsaturated fatty acids. Nature 325:330-332
73. Keene WC, Maring H, Maben JR, Kieber DJ, Pszenny AAP, Dahl EE, Izaguirre MA, Davis AJ, Long MS, Zhou XL, Smoydzin L, Sander R (2007) Chemical and physical characteristics of nascent aerosols produced by bursting bubbles at a model air-sea interface. J Geophys Res Atmos 112:D21202. doi:10.1029/ 2007JD008464
74. Marty JC, Saliot A, Buat-Mqnard P, Chesselet R, Hunter KA (1979) Relationship between the lipid compositions of marine aerosols, the sea surface microlayer, and subsurface water. J Geophys Res 84:5707-5716
75. Mochida M, Kitamori Y, Kawamura K, Nojiri Y, Suzuki K (2002) Fatty acids in the marine atmosphere: Factors governing their concentrations and evaluation of organic films on sea-salt particles. J Geophys Res Atmos 107:4325-4334
76. Morris RJ, Culkin F (1974) Lipid chemistry of eastern Mediterranean surface layers. Nature 250:640-642
77. O'Dowd CD, Facchini MC, Cavalli F, Ceburnis D, Mircea M, Decesari S, Fuzzi S, Yoon YJ, Putaud JP (2004) Biogenically driven organic contribution to marine aerosol. Nature 431:676-680
78. Fang J, Kawamura K, Ishimura Y, Matsumoto K (2002) Carbon isotopic composition of fatty acids in the marine aerosols from the Western North Pacific: Implication for the source and atmospheric transport. Environ Sci Technol 36:2598-2604
79. Gagosian RB, Zafiriou OC, Peltzer ET, Alford JB (1982) Lipids in aerosols from the tropical North Pacific: Temporal variability. J Geophys Res 87:11133-11144
80. Pankow JF (1994) An absorption-model of the gas aerosol partitioning involved in the formation of secondary organic aerosol. Atmos Environ 28:189-193
81. Seinfeld JH, Pankow JF (2003) Organic atmospheric particulate material. Ann Rev Phys Chem 54:121-140
82. Ervens B, Volkamer R (2010) Glyoxal processing by aerosol multiphase chemistry: Towards a kinetic modeling framework of secondary organic aerosol formation in aqueous particles. Atmos Chem Phys 10:8219-8244
83. Nopmongcol U, Khamwichit W, Fraser MP, Allen DT (2007) Estimates of heterogeneous formation of secondary organic aerosol during a wood smoke episode in Houston. Texas Atmos Environ 41:3057-3070
84. Sareen N, Schwier AN, Shapiro EL, Mitroo DM, McNeill VF (2010) Secondary organic material formed by methylglyoxal in aqueous aerosol mimics. Atmos Chem Phys 10:997-1016
85. Schwier AN, Sareen N, Mitroo DM, Shapiro EL, McNeill VF (2010) Glyoxal-methylglyoxal cross-reactions in secondary organic aerosol formation. Environ Sci Technol 44:6174-6182
86. Shapiro EL, Szprengiel J, Sareen N, Jen CN, Giordano MR, McNeill VF (2009) Lightabsorbing secondary organic material formed by glyoxal in aqueous aerosol mimics. Atmos Chem Phys 9:2289-2300
87. Tan Y, Carlton AG, Seitzinger SP, Turpin BJ (2010) SOA from methylglyoxal in clouds and wet aerosols: Measurement and prediction of key products. Atmos Environ 44:5218-5226
88. Cole-Filipiak NC, O'Connor AE, Elrod MJ (2010) Kinetics of the hydrolysis of atmospherically relevant isoprene-derived hydroxy epoxides. Environ Sci Technol 44:6718-6723
89. Darer AI, Cole-Filipiak NC, O'Connor AE, Elrod MJ (2011) Formation and stability of atmospherically relevant isoprene-derived organosulfates and organonitrates. Environ Sci Technol 45:1895-1902
90. Eddingsaas NC, VanderVelde DG, Wennberg PO (2010) Kinetics and products of the acidcatalyzed ring-opening of atmospherically relevant butyl epoxy alcohols. J Phys Chem A 114:8106-8113
91. Surratt JD, Chan AWH, Eddingsaas NC, Chan MN, Loza CL, Kwan AJ, Hersey SP, Flagan RC, Wennberg PO, Seinfeld JH (2010) Reactive intermediates revealed in secondary organic aerosol formation from isoprene. Proc Natl Acad Sci USA 107:6640-6645
92. Chebbi A, Carlier P (1996) Carboxylic acids in the troposphere, occurrence, sources, and sinks: A review. Atmos Environ 30:4233-4249
93. Shulman ML, Jacobson MC, Carlson RJ, Synovec RE, Young TE (1996) Dissolution behavior and surface tension effects of organic compounds in nucleating cloud droplets. Geophys Res Lett 23:277-280
94. Tuckermann R (2007) Surface tension of aqueous solutions of water-soluble organic and inorganic compounds. Atmos Environ 41:6265-6275
95. Tuckermann R, Cammenga HK (2004) The surface tension of aqueous solutions of some atmospheric water-soluble organic compounds. Atmos Environ 38:6135-6138
96. Varga Z, Kiss G, Hansson HC (2007) Modelling the cloud condensation nucleus activity of organic acids on the basis of surface tension and osmolality measurements. Atmos Chem Phys 7:4601-4611
97. Asa-Awuku A, Nenes A, Gao S, Flagan RC, Seinfeld JH (2010) Water-soluble SOA from alkene ozonolysis: Composition and droplet activation kinetics inferences from analysis of CCN activity. Atmos Chem Phys 10:1585-1597
98. George I, Abbatt JPD (2010) Heterogeneous oxidation of atmospheric aerosol particles by gas-phase radicals. Nat Chem 2:713-722
99. Altieri KE, Carlton AG, Lim HJ, Turpin BJ, Seitzinger SP (2006) Evidence for oligomer formation in clouds: Reactions of isoprene oxidation products. Environ Sci Technol 40:4956-4960
100. Lim HJ, Carlton AG, Turpin BJ (2005) Isoprene forms secondary organic aerosol through cloud processing: Model simulations. Environ Sci Technol 39:4441-4446
101. Gelencser A, Hoffer A, Kiss G, Tombacz E, Kurdi R, Bencze L (2003) In-situ formation of light-absorbing organic matter in cloud water. J Atmos Chem 45:25-33
102. Li Z, Schwier AN, Sareen N, McNeill VF (2011) Reactive processing of formaldehyde and acetaldehyde in aqueous aerosol mimics: Surface tension depression and secondary organic products. Atmos Chem Phys 11:11617-11629
103. Noziere B, Ekstrom S, Alsberg T, Holmstrom S (2010) Radical-initiated formation of organosulfates and surfactants in atmospheric aerosols. Geophys Res Lett 37:L05806. doi:10.1029/2009GL041683
104. Surratt JD, Kroll JH, Kleindienst TE, Edney EO, Claeys M, Sorooshian A, Ng NL, Offenberg JH, Lewandowski M, Jaoui M, Flagan RC, Seinfeld JH (2007) Evidence for organosulfates in secondary organic aerosol. Environ Sci Technol 41:517-527
105. Archer RJ, La Mer VK (1955) The rate of evaporation of water through fatty acid monolayers. J Phys Chem 59:200-208
106. Rideal EK (1925) On the influence of surface films in the evaporation of water. J Phys Chem 29:1585-1588
107. Rosano HL, La Mer VK (1956) The rate of evaporation of water through monolayers of esters, acids, and alcohols. J Phys Chem 60:348-353
108. Anttila T, Kiendler-Scharr A, Tillman R, Mentel TF (2006) On the reactive uptake of gaseous compounds by organic-coated aqueous aerosols: Theoretical analysis and application to the heterogeneous hydrolysis of N2O5. J Phys Chem A 110:10435-10443
109. Badger CL, Griffiths PT, George I, Abbatt JPD, Cox RA (2006) Reactive uptake of N2O5 by aerosol particles containing mixtures of humic acid and ammonium sulfate. J Phys Chem A 110:6986-6994
110. Escoreia EN, Sjostedt SJ, Abbatt JPD (2010) Kinetics of N2O5 hydrolysis on secondary organic aerosol and mixed ammonium bisulfate-secondary organic aerosol particles. J Phys Chem A 114:13113-13121
111. Folkers M, Mentel TF, Wahner A (2003) Influence of an organic coating on the reactivity of aqueous aerosols probed by the heterogeneous hydrolysis of N2O5. Geophys Res Lett 30:1644-1647
112. McNeill VF, Wolfe GM, Thornton JA (2007) The oxidation of oleate in submicron aqueous salt aerosols: Evidence of a surface process. J Phys Chem A 111:1073-1083
113. McNeill VF, Patterson J, Wolfe GM, Thornton JA (2006) The effect of varying levels of surfactant on the reactive uptake of N2O5 to aqueous aerosol. Atmos Chem Phys 6:1635-1644
114. Rouviere A, Ammann M (2010) The effect of fatty acid surfactants on the uptake of ozone to aqueous halogenide particles. Atmos Chem Phys 10:11489-11500
115. Stemmler K, Vlasenko A, Guimbaud C, Ammann M (2008) The effect of fatty acid surfactants on the uptake of nitric acid to deliquesced NaCl aerosol. Atmos Chem Phys 8:5127-5141
116. Thornton JA, Abbatt JPD (2005) N2O5 reaction on sub-micron sea salt aerosol: Effect of surface active organics. J Phys Chem A 109:10004-10012
117. Thornton JA, Braban CF, Abbatt JPD (2003) N2O5 hydrolysis on sub-micron organic aerosols: The effect of relative humidity, particle phase, and particle size. Phys Chem Chem Phys 5:4593-4603
118. Cosman LM, Bertram AK (2008) Reactive uptake of N2O5 on aqueous H2SO4 solutions coated with 1-component and 2-component monolayers. J Phys Chem A 112:4625-4635
119. Cosman LM, Knopf DA, Bertram AK (2008) N2O5 reactive uptake on aqueous sulfuric acid solutions coated with branched and straight-chain insoluble organic surfactants. J Phys Chem A 112:2386-2396
120. Knopf DA, Cosman LM, Mousavi P, Mokamati S, Bertram AK (2007) A novel flow reactor for studying reactions on liquid surfaces coated by organic monolayers: Methods, validation, and initial results. J Phys Chem A 111:11021-11032
121. Chan MN, Lee AKY, Chan CK (2006) Responses of ammonium sulfate particles coated with glutaric acid to cyclic changes in relative humidity: Hygroscopicity and Raman characterization. Environ Sci Technol 40:6983-6989
122. Cruz CN, Pandis SN (1998) The effect of organic coatings on the cloud condensation nuclei activation of inorganic atmospheric aerosol. J Geophys Res Atmos 103:13111-13123
123. Cruz CN, Pandis SN (2000) Deliquescence and hygroscopic growth of mixed inorganic-organic atmospheric aerosol. Environ Sci Technol 34:4313-4319
124. Glass SV, Park SC, Nathanson GM (2006) Evaporation of water and uptake of HCl and HBr through hexanol films at the surface of supercooled sulfuric acid. J Phys Chem A 110:7593-7601
125. Lawrence JR, Glass SV, Nathanson GM (2005) Evaporation of water through butanol films at the surface of supercooled sulfuric acid. J Phys Chem A 109:7449-7457
126. Lawrence JR, Glass SV, Park SC, Nathanson GM (2005) Surfactant control of gas uptake: Effect of butanol films on HCl and HBr entry into supercooled sulfuric acid. J Phys Chem A 109:7458-7465
127. Park SC, Burden DK, Nathanson GM (2007) The inhibition of N2O5 hydrolysis in sulfuric acid by 1-butanol and 1-hexanol surfactant coatings. J Phys Chem A 111:2921-2929
128. Schofield RK, Rideal EK (1926) The kinetic theory of surface films - Part II. Gaseous, expanded, and condensed films. Proc R Soc 110A:167-177
129. Myers D (1988) Surfactant science and technology. VCH, New York
130. Gilman JB, Vaida V (2006) Permeability of acetic acid through organic films at the airaqueous interface. J Phys Chem A 110:7581-7587
131. Donaldson DJ, Vaida V (2006) The influence of organic films at the air-aqueous boundary on atmospheric processes. Chem Rev 106:1445-1461
132. Donaldson DJ, Valsaraj KT (2010) Adsorption and reaction of trace gas-phase organic compounds on atmospheric water film surfaces: A critical review. Environ Sci Technol 44:865-873
133. Kolb CE, Cox RA, Abbatt JPD, Ammann M, Davis EJ, Donaldson DJ, Garrett BC, George C, Griffiths PT, Hanson DR, Kulmala M, McFiggans G, Poschl U, Riipinen I, Rossi MJ, Rudich Y, Wagner PE, Winkler PM, Worsnop DR, O' Dowd CD (2010) An overview of current issues in the uptake of atmospheric trace gases by aerosols and clouds. Atmos Chem Phys 10:10561-10605
134. Clifford D, Bartels-Rausch T, Donaldson DJ (2007) Suppression of aqueous surface hydrolysis by monolayers of short chain organic amphiphiles. Phys Chem Chem Phys 9:1362-1369
135. Park SC, Burden DK, Nathanson GM (2009) Surfactant control of gas transport and reactions at the surface of sulfuric acid. Acc Chem Res 42:379-387
136. Burden DK, Johnson AM, Nathanson GM (2009) HCl uptake through films of pentanoic acid and pentanoic acid/hexanol mixtures at the surface of sulfuric acid. J Phys Chem A 113:14131-14140
137. Dentener FJ, Crutzen PJ (1993) Reaction of N2O5 on tropospheric aerosols - impact on the global distributions of NOx, O3, and OH. J Geophys Res Atmos 98:7149-7163
138. Evans MJ, Jacob DJ (2005) Impact of new laboratory studies of N(2)O(5) hydrolysis on global model budgets of tropospheric nitrogen oxides, ozone, and OH. Geophys Res Lett 32. doi:10.1029/2005GL022469
139. Liao H, Seinfeld JH, Adams PJ, Mickley LJ (2004) Global radiative forcing of coupled tropospheric ozone and aerosols in a unified general circulation model. J Geophys Res Atmos 109. doi:10.1029/2003JD004456
140. Dash UN, Mohanty BK (1997) Thermodynamic functions of solutions of homologous dicarboxylic acids in water + acetone mixtures from surface tension measurements. Fluid Phase Equilibria 134:267-276
141. Ekström S, Noziere B, Hansson H-C (2009) The cloud condensation nuclei (CCN) properties of 2-methyltetrols and C3-C6 polyols from osmolality and surface tension measurements. Atmos Chem Phys 9:973-980
142. Hyvarinen AR, Lihavainen H, Gaman A, Vairila L, Ojala H, Kulmala M, Viisanen Y (2006) Surface tensions and densities of oxalic, malonic, succinic, maleic, malic, and cis-pinonic acids. J Chem Eng Data 51:255-260
143. Topping DO, McFiggans GB, Kiss G, Varga Z, Facchini MC, Decesari S, Mircea M (2007) Surface tensions of multi-component mixed inorganic/organic aqueous systems of atmospheric significance: Measurements, model predictions and importance for cloud activation predictions. Atmos Chem Phys 7:2371-2398
144. Finlayson-Pitts BJ, Hemminger JC (2000) Physical chemistry of airborne sea salt particles and their components. J Phys Chem A 104:11463-11477
145. Krisch MJ, D'Auria R, Brown MA, Tobias DJ, Hemminger JC, Ammann M, Starr DE, Bluhm H (2007) The effect of an organic surfactant on the liquid-vapor interface of an electrolyte solution. J Phys Chem C 111:13497-13509
146. Clifford D, Donaldson DJ (2007) Direct experimental evidence for a heterogeneous reaction of ozone with bromide at the air-aqueous interface. J Phys Chem A 111:9809-9814
147. Brown SS, Ryerson TB, Wollny AG, Brock CA, Peltier R, Sullivan AP, Weber RJ, Dube WP, Trainer M, Meagher JF, Fehsenfeld FC, Ravishankara AR (2006) Variability in nocturnal nitrogen oxide processing and its role in regional air quality. Science 311:67-70
148. Bertram TH, Thornton JA, Riedel TP (2009) An experimental technique for the direct measurement of N2O5 reactivity on ambient particles. Atmos Meas Tech 2:231-242
149. Bertram TH, Thornton JA, Riedel TP, Middlebrook AM, Bahreini R, Bates TS, Quinn PK, Coffman DJ (2009) Direct observations of N2O5 reactivity on ambient aerosol particles. Geophys Res Lett 36:L19803. doi:10.1029/2009GL040248
150. Bertram TH, Thornton JA (2009) Toward a general parameterization of N(2)O(5) reactivity on aqueous particles: The competing effects of particle liquid water, nitrate and chloride. Atmos Chem Phys 9:8351-8363
151. Riemer N, Vogel H, Vogel B, Anttila T, Kiendler-Scharr A, Mentel TF (2009) Relative importance of organic coatings for the heterogeneous hydrolysis of N(2)O(5) during summer in Europe. J Geophys Res Atmos 114. doi:10.1029/2008JD011369
152. Smoydzin L, von Glasow R (2007) Do organic surface films on sea salt aerosols influence atmospheric chemistry? A model study. Atmos Chem Phys 7:5555-5567
153. Baker MB (1997) Cloud microphysics and climate. Science 276:1072-1078
154. Gavish M, Popovitzbiro R, Lahav M, Leiserowitz L (1990) Ice nucleation by alcohols arranged in monolayers at the surface of water drops. Science 250:973-975
155. Majewski J, Popovitzbiro R, Bouwman WG, Kjaer K, AlsNielsen J, Lahav M, Leiserowitz L (1995) The structural-properties of uncompressed crystalline monolayers of alcohols CnH2n + 1OH (n = 13-31) on water and their role as ice nucleators. Chem Eur J 1:304-311
156. Majewski J, Popovitzbiro R, Kjaer K, Alsnielsen J, Lahav M, Leiserowitz L (1994) Toward a determination of the critical size of ice nuclei - A demonstration by grazing-incidence X-raydiffraction of epitaxial-growth of ice under the C31H63OH alcohol monolayer. J Phys Chem 98:4087-4093
157. Popovitzbiro R, Wang JL, Majewski J, Shavit E, Leiserowitz L, Lahav M (1994) Induced freezing of supercooled water into ice by self-assembled crystalline monolayers of amphiphilic alcohols at the air-water-interface. J Am Chem Soc 116:1179-1191
158. Seeley LH, Seidler GT (2001) Two-dimensional nucleation of ice from supercooled water. Phys Rev Lett 87:055702. doi:10.1103/PhysRevLett.87.055702
159. Ochshorn E, CantrellW(2006) Towards understanding ice nucleation by long chain alcohols. J Chem Phys 124. doi:10.1063/1.2166368
160. Cantrell W, Robinson C (2006) Heterogeneous freezing of ammonium sulfate and sodium chloride solutions by long chain alcohols. Geophys Res Lett 33:L07802. doi:10.1029/ 2005GL024945
161. Zobrist B, Koop T, Luo BP, Marcolli C, Peter T (2007) Heterogeneous ice nucleation rate coefficient of water droplets coated by a nonadecanol monolayer. J Phys Chem C 111:2149-2155
162. Zobrist B, Marcolli C, Peter T, Koop T (2008) Heterogeneous ice nucleation in aqueous solutions: The role of water activity. J Phys Chem A 112:3965-3975
163. Knopf DA, Forrester SM (2011) Freezing of water and aqueous NaCl droplets coated by organic monolayers as a function of surfactant properties and water activity. J Phys Chem A 115:5579-5591
164. Corrigan CE, Novakov T (1999) Cloud condensation nucleus activity of organic compounds: A laboratory study. Atmos Environ 33:2661-2668
165. Cruz CN, Pandis SN (1997) A study of the ability of pure secondary organic aerosol to act as cloud condensation nuclei. Atmos Environ 31:2205-2214
166. Henning S, Rosenorn T, D'Anna B, Gola AA, Svenningsson B, BildeM(2005) Cloud droplet activation and surface tension of mixtures of slightly soluble organics and inorganic salt. Atmos Chem Phys 5:575-582
167. Prenni AJ, DeMott PJ, Kreidenweis SM, Sherman DE, Russell LM, Ming Y (2001) The effects of low molecular weight dicarboxylic acids on cloud formation. J Phys Chem A 105:11240-11248
168. Raymond TM, Pandis SN (2003) Formation of cloud droplets by multicomponent organic particles. J Geophys Res Atmos 108:4469. doi:10.1029/2003JD003503
169. Raymond TM, Pandis SN (2002) Cloud activation of single-component organic aerosol particles. J Geophys Res Atmos 107:4787. doi:10.1029/2002JD002159
170. Liu PSK, Leaitch WR, Banic CM, Li SM, Ngo D, Megaw WJ (1996) Aerosol observations at Chebogue Point during the 1993 North Atlantic Regional Experiment: Relationships among cloud condensation nuclei, size distribution, and chemistry. J Geophys Res Atmos 101:28971-28990
171. Kohler H (1936) The nucleus in the growth of hygroscopic droplets. Trans
172. Seinfeld JH, Pandis SN (2006) Atmospheric chemistry and physics: From air pollution to climate change, 2nd edn. Wiley, New York
173. Chuang PY, Charlson RJ, Seinfeld JH (1997) Kinetic limitations on droplet formation in clouds. Nature 390:594-596
174. Nenes A, Ghan S, Abdul-Razzak H, Chuang PY, Seinfeld JH (2001) Kinetic limitations on cloud droplet formation and impact on cloud albedo. Tellus B 53:133-149
175. Kulmala M, Laaksonen A, Korhonen P, Vesala T, Ahonen T, Barrett JC (1993) The effect of atmospheric nitric acid vapor on cloud condensation nucleus activation. J Geophys Res 98:22949-22958
176. Laaksonen A, Korhonen P, Kulmala M, Charlson RJ (1998) Modification of the Köhler equation to include soluble trace gases and slightly soluble substances. J Atmos Sci 55:853-862
177. Topping D, Mcfiggans G (2012) Tight coupling of particle size, number and composition in atmospheric cloud droplet activation. Atmos Chem Phys 12:3253-3260
178. Padró LT, Asa-Awuku A, Morrison R, Nenes A (2007) Inferring thermodynamic properties from CCN activation experiments: Single-component and binary aerosols. Atmos Chem Phys 7:5263-5274
179. Kulmala M, Laaksonen A, Charlson RJ, Korhonen P (1997) Clouds without supersaturation. Nature 388:336-337
180. Petters MD, Kreidenweis SM (2007) A single parameter representation of hygroscopic growth and cloud condensation nucleus activity. Atmos Chem Phys 7:1961-1971
181. Washburn, E.W. (1926-1930;2003). International Critical Tables of Numerical Data, Physics, Chemistry and Technology (1st Electronic Edition). Knovel. Online version available at: Http://www.knovel.com/web/portal/browse/ display?-EXT-KNOVELDISPLAYbookid= 735&VerticalID=0
182. Dutcher CS, Wexler AS, Clegg SL (2010) Surface tensions of inorganic multicomponent aqueous electrolyte solutions and melts. J Phys Chem A 114:12216-12230
183. Hu Y-F, Lee H (2004) Prediction of the surface tension of mixed electrolyte solutions based on the equation of Patwardhan and Kumar and the fundamental Butler equations. J Colloid Interface Sci 269:442-448
184. Li ZB, Li YG, Lu JF (1999) Surface tension model for concentrated electrolyte aqueous solutions by the Pitzer equation. Ind Eng Chem Res 38:1133-1139
185. Li ZB, Lu BCY (2001) Surface tension of aqueous electrolyte solutions at high concentrations - representation and prediction. Chem Eng Sci 56:2879-2888
186. Hu J, Zhang X, Wang Z (2010) A review on progress in QSPR studies for surfactants. Int J Mol Sci 11:1020-1047
187. Setschenow JZ (1889) Uber Die Konstitution Der Salzosungen auf Grund ihres Verhaltens zu Kohlensaure. Z Physik Chem 4:117-125
188. Matijevic E, Pethica BA (1958) The properties of ionized monolayers, part 1. Sodium dodecyl sulfate at the air/water interface. Trans Faraday Soc 54:1383-1389
189. Adamson AW, Gast AP (1997) Physical chemistry of surfaces, 6th edn. Wiley, New York
190. Booth AM, Topping DO, McFiggans G, Percival CJ (2009) Surface tension of mixed inorganic and dicarboxylic acid aqueous solutions at 298.15 K and their importance for cloud activation predictions. Phys Chem Chem Phys 11:8021-8028
191. Fainerman VB, Miller R (2001) Simple method to estimate surface tension of mixed surfactant solutions. J Phys Chem B 105:11432-11438
192. Fainerman VB, Miller R, Aksenenko EV (2002) Simple model for prediction of surface tension of mixed surfactant solutions. Adv Colloid Interface Sci 96:339-359
193. Hitzenberger R, Berner A, Kasper-Giebl A, Loflund M, Puxbaum H (2002) Surface tension of Rax cloud water and its relation to the concentration of organic material. J Geophys Res 107:4752. doi:10.1029/2002JD002506
194. Barger WR, Garrett WD (1976) Surface active organic material in air over the Mediterranean and over the eastern equatorial Pacific. J Geophys Res 81:3151-3157
195. Seidl W, Hanel G (1983) Surface-active substances on rainwater and atmospheric particles. Pure Appl Geophys 121:1077-1093
196. Capel PD, Gunde R, Zuercher F, Giger W (1990) Carbon speciation and surface tension of fog. Environ Sci Technol 24:722-727
197. Moore RH, Ingall ED, Sorooshian A, Nenes A (2008) Molar mass, surface tension, and droplet growth kinetics of marine organics from measurements of CCN activity. Geophys Res Lett 35:L07801. doi:10.1029/2008GL033350
198. Graber ER, Rudich Y (2006) Atmospheric HULIS: How humic-like are they? A comprehensive and critical review. Atmos Chem Phys 6:729-753
199. Chen Y, Schnitzer M (1978) The surface tension of aqueous solutions of soil humic substances. Soil Sci 125:7-15
200. Anderson MA, Hung AYC, Mills D, Scott MS (1995) Factors affecting the surface tension of soil solutions and solutions of humic acids. Soil Sci 160:111-116
201. Yates LM, von Wandruszka R (1999) Effects of pH and metals on the surface tension of aqueous humic materials. Soil Sci Soc Am J 63:1645-1649
202. Aumann E, Tabazadeh A (2008) Rate of organic film formation and oxidation on aqueous drops. J Geophys Res Atmos 113:D23205. doi:10.1029/2007JD009738
203. Klavins M, Purmalis O (2010) Humic substances as surfactants. Environ Chem Lett 8:349-354
204. Aumann E, Hildemann LM, Tabazadeh A (2010) Measuring and modeling the composition and temperature-dependence of surface tension for organic solutions. Atmos Environ 44:329-337
205. Frosch M, Prisle NL, Bilde M, Varga Z, Kiss G (2011) Joint effect of organic acids and inorganic salts on cloud droplet activation. Atmos Chem Phys 11:3895-3911
206. Terashima M, Fukushima M, Tanaka S (2004) Influence of pH on the surface activity of humic acid: Micelle-like aggregate formation and interfacial adsorption. Colloids Surf A 247:77-83
207. Hagenhoff K, Dong J, Chowdhry B, Leharne S (2010) Aqueous solution of anionic surfactants mixed with soils show a synergistic reduction in surface tension. Water Air Soil Pollut 209:3-13
208. Gaman AI, Kulmala M, Vehkamaki H, Napari I, Mircea M, Facchini MC, Laaksonen A (2004) Binary homogeneous nucleation in water-succinic acid and water-glutaric acid systems. J Chem Phys 120:282
209. Vanhanen J, Hyvarinen A-P, Anttila T, Viisanen Y, Lihavainen H (2008) Ternary solution of sodium chloride, succinic acid, and water - surface tension and its influence on cloud droplet activation. Atmos Chem Phys 8:4595-4604
210. Riipinen I, Koponen IK, Frank GP, Hyvarinen AP, Vanhanen J, Lihavainen H, Lehtinen KEJ, Bilde M, Kulmala M(2007) Adipic and malonic acid aqueous solutions: Surface tensions and saturation vapor pressures. J Phys Chem A 111:12995-13002
211. Langmuir I (1917) The shapes of group molecules forming the surfaces of liquids. Proc Natl Acad Sci USA 3:251-257
212. Langmuir I (1917) The constitution and fundamental properties of solids and liquids. J Am Chem Soc 39:1848-1906
213. De Mul MNG, Davis HT, Evans DF, Bhave AV, Wagner JR (2000) Solution phase behavior and solid phase structure of long-chain sodium soap mixtures. Langmuir 16:8276-8284
214. Johann R, Vollhardt D (1999) Texture features of long-chain fatty acid monolayers at high pH of the aqueous subphase. Mater Sci Eng C 8-9:35-42
215. Slauenwhite DE, Johnson BD (1996) Effect of organic matter on bubble surface tension. J Geophys Res 101:3769-3774
216. Schwier AN, Mitroo DM, McNeill VF (2012) Surface tension depression by low-solubility organic material in aqueous aerosol mimics. Atmos Environ 54:495-500
217. McNeill VF, Yattavelli RLN, Thornton JA, Stipe CB, Landgrebe O (2008) The heterogeneous OH oxidation of palmitic acid in single component and internally mixed aerosol particles: Vaporization, secondary chemistry, and the role of particle phase. Atmos Chem Phys 8:5465-5476
218. Svenningsson B, Rissler J, Swietlicki E,MirceaM, BildeM, FacchiniMC, Decesari S, Fuzzi S, Zhou J, Mønster J, Rosenørn T (2006) Hygroscopic growth and critical supersaturations for mixed aerosol particles of inorganic and organic compounds of atmospheric relevance. Atmos Chem Phys 6:1937-1952
219. Grosjean D (1982) Formaldehyde and other carbonyl in Los Angeles ambient air. Environ Sci Technol 16:254-262
220. Novakov T, Penner JE (1993) Large contribution of organic aerosols to cloud-condensationnuclei concentrations. Nature 365:823-826
221. Rivera-Carpio CA, Corrigan CE, Novakov T, Penner JE, Rogers CF, Chow JC (1996) Derivation of contributions of sulfate and carbonaceous aerosols to cloud condensation nuclei from mass size distributions. J Geophys Res Atmos 101:19483-19493
222. Novakov T, Corrigan CE (1996) Cloud condensation nucleus activity of the organic component of biomass smoke particles. Geophys Res Lett 23:2141-2144
223. Mochida M, Kuwata M, Miyakawa T, Takegawa N, Kawamura K, Kondo Y (2006) Relationship between hygroscopicity and cloud condensation nuclei activity for urban aerosols in Tokyo. J Geophys Res Atmos 111:D23204. doi:10.1029/ 2005JD006980
224. Lance S, Nenes A, Mazzoleni C, Dubey MK, Gates H, Varutbangkul V, Rissman TA, Murphy SM, Sorooshian A, Flagan RC, Seinfeld JH, Feingold G, Jonsson HH (2009) Cloud condensation nuclei activity, closure, and droplet growth kinetics of Houston aerosol during the Gulf of Mexico Atmospheric Composition and Climate Study (GoMACCS). J Geophys Res Atmos 114:D00F15. doi:10.1029/2004JD004596
225. Broekhuizen K, Kumar PP, Abbatt JPD (2004) Partially soluble organics as cloud condensation nuclei: Role of trace soluble and surface active species. Geophys Res Lett 31:L01107. doi:10.1029/2003GL018203
226. Shilling JE, King SM, Mochida M, Worsnop DR, Martin ST (2007) Mass spectral evidence that small changes in composition caused by oxidative aging processes alter aerosol CCN properties. J Phys Chem A 111:3358-3368
227. Schwier AN, Sareen N, Lathem T, Nenes A, McNeill VF (2011) Ozone oxidation of oleic acid films decreases aerosol CCN activity. J Geophys Res Atmos 116. doi:10.1029/ 2010JD015520
228. VanReken TM, Ng NL, Flagan RC, Seinfeld JH (2005) Cloud condensation nucleus activation properties of biogenic secondary organic aerosol. J Geophys Res 110. doi:10.1029/ 2004JD005465
229. Varutbangkul V, Brechtel FJ, Bahreini R, Ng NL, Keywood MD, Kroll JH, Flagan RC, Seinfeld JH, Lee A, Goldstein AH (2006) Hygroscopicity of secondary organic aerosols formed by oxidation of cycloalkenes, monoterpenes, sesquiterpenes, and related compounds. Atmos Chem Phys 6:2367-2388
230. Dinar E, Taraniuk I, Graber ER, Katsman S, Moise T, Anttila T, Mentel TF, Rudich Y (2006) Cloud condensation nuclei properties of model and atmospheric HULIS. Atmos Chem Phys 6:2465-2482
231. Dinar E, Taraniuk I, Graber ER, Anttila T, Mentel TF, Rudich Y (2007) Hygroscopic growth of atmospheric and model humic-like substances. J Geophys Res Atmos 112:D05211. doi:10.1029/2006JD007442
232. Wex H, Hennig T, Salma I, Ocskay R, Kiselev A, Henning S, Massling A, Wiedensohler A, Stratmann F (2007) Hygroscopic growth and measured and modeled critical supersaturations of an atmospheric HULIS sample. Geophys Res Lett 34:L02818. doi:10.1029/ 2006GL028260
233. Fors EO, Rissler J, Massling A, Svenningsson B, Andreae MO, Dusek U, Frank GP, Hoffer A, Bilde M, Kiss G, Janitsek S, Henning S, Facchini MC, Decesari S, Swietlicki E (2010) Hygroscopic properties of Amazonian biomass burning and European background HULIS and investigation of their effects on surface tension with two models linking H-TDMA to CCNC data. Atmos Chem Phys 10:5625-5639
234. Riipinen I, Koponen IK, Frank GP, Hyvaerinen AP, Vanhanen J, Lihavainen H, Lehtinen KEJ, Bilde M, Kulmala M (2007) Adipic and malonic acid aqueous solutions: Surface tensions and saturation vapor pressures. J Phys Chem A 111:12995-13002
235. Pradeep Kumar P, Broekhuizen K, Abbatt JPD (2003) Organic acids as cloud condensation nuclei: Laboratory studies of highly soluble and insoluble species. Atmos Chem Phys 3:509-520
236. Hori M, Ohta S, Murao N, Yamagata S (2003) Activation capability of water soluble organic substances as CCN. J Aerosol Sci 34:419-448
237. Abbatt JPD, Broekhuizen K, Kumal PP (2005) Cloud condensation nucleus activity of internally mixed ammonium sulfate/organic acid aerosol particles. Atmos Environ 39:4767-4778
238. Sareen N, Schwier AN, Lathem T, Nenes A, McNeill VF (2012) Gas-phase surfactants may enhance aerosol cloud nucleation. In press, Proc. Natl. Acad. Sci. USA
239. Kroll JH, Ng NL, Murphy SM, Varutbangkul V, Flagan RC, Seinfeld JH (2005) Chamber studies of secondary organic aerosol growth by reactive uptake of simple carbonyl compounds. J Geophys Res Atmos 110:D23207. doi:10.1029/ 2005JD006004
240. Betterton EA, Hoffmann MR (1988) Henry's law constants of some environmentally important aldehydes. Environ Sci Technol 22:1415-1418
241. Djikaev YS, Tabazadeh A (2003) Effect of adsorption on the uptake of organic trace gas by cloud droplets. J Geophys Res Atmos 108:4869. doi:10.1029/2003JD003741
242. Good N, Topping DO, Allan JD, Flynn M, Fuentes E, Irwin M, Williams PI, Coe H, McFiggans G (2010) Consistency between parameterisations of aerosol hygroscopicity and CCN activity during the RHaMBLe discovery cruise. Atmos Chem Phys 10:3189-3203
243. Irwin M, Good N, Crosier J, Choularton TW, Mcfiggans G (2010) Reconciliation of measurements of hygroscopic growth and critical supersaturation of aerosol particles in central Germany. Atmos Chem Phys 10:11737-11752
244. Asa-Awuku A, Nenes A (2007) Effect of solute dissolution kinetics on cloud droplet formation: Extended Köhler theory. J Geophys Res Atmos 112:D22201. doi:10.1029/ 2005JD006934
245. Seidl W (2000) Model for a surface film of fatty acids on rain water and aerosol particles. Atmos Environ 34:4917-4932
246. Prisle NL, Asmi A, Topping D, Partanen AI, Romakkaniemi S, Dal Maso M, Kulmala M, Laaksonen A, Lehtinen KEJ, McFiggans G, Kokkola H (2012) Surfactant effects in global simulations of cloud droplet activation. Geophys Res Lett 39:L05802. doi:10.1029/ 2011GL050467
247. Chakraborty P, Zachariah MR (2007) Effective negative surface tension: A property of coated nanoaerosols relevant to the atmosphere. J Phys Chem A 111:5459-5464
248. Chakraborty P, Zachariah MR (2008) Sticking coefficient and processing of water vapor on organic-coated nanoaerosols. J Phys Chem A 112:966-972
249. Chakraborty P, Zachariah MR (2011) On the structure of organic-coated water droplets: From net water attractors to oily drops. J Geophys Res 116:D21205. doi:10.1029/ 2011JD015961
250. Hede T, Li X, Leck C, Tu Y, A gren H (2011) Model HULIS compounds in nanoaerosol clusters - investigations of surface tension and aggregate formation using molecular dynamics simulations. Atmos Chem Phys 11:6549-6557
251. Li X, Hede T, Tu Y, Leck C, Agren H (2011) Glycine in aerosol water droplets: A critical assessment of Köhler theory by predicting surface tension from molecular dynamics simulations. Atmos Chem Phys 11:519-527
252. Li X, Hede T, Tu Y, Leck C, Agren H (2011) Amino acids in atmospheric droplets: Perturbation of surfact tension and critical supersaturation predicted by computer simulations. Atmos Chem Phys Discuss 11:30919-30947
253. Li X, Hede T, Tu Y, Leck C, Agren H (2010) Surface-active cis-pinonic acid in atmospheric droplets: A molecular dynamics study. J Phys Chem Lett 1:769-773
254. Ma X, Chakraborty P, Henz BJ, Zachariah MR (2011) Molecular dynamic simulation of dicarboxylic acid coated aqueous aerosol: Structure and processing of water vapor. Phys Chem Chem Phys 13:9374-9384
255. Takahama S, Russell LM (2011) A molecular dynamics study of water mass accommodation on condensed phase water coated by fatty acid monolayers. J Geophys Res Atmos 116. doi:10.1029/2010JD014842
256. Kokkola H, Sorjamaa R, Peraniemi A, Raatikainen T, Laaksonen A (2006) Cloud formation of particles containing humic-like substances. Geophys Res Lett 33:L10816. doi:10.1029/ 2006GL026107
257. Li Z, Williams AL, Rood MJ (1998) Influence of soluble surfactant properties on the activation of aerosol particles containing inorganic solute. J Atmos Sci 55:1859-1866
258. Prisle NL, Dal Maso M, Kokkola H (2011) A simple representation of surface active organic aerosol in cloud droplet formation. Atmos Chem Phys 11:4073-4083
259. Prisle NL, Raatikainen T, Laaksonen A, Bilde M (2010) Surfactants in cloud droplet activation: Mixed organic-inorganic particles. Atmos Chem Phys 10:5663-5683
260. Prisle NL, Raatikainen T, Sorjamaa R, Svenningsson B, Laaksonen A, Bilde M (2008) Surfactant partitioning in cloud droplet activation: A study of C8, C10, C12 and C14 normal fatty acid sodium salts. Tellus B 60:416-431
261. Raatikainen T, Laaksonen A (2011) A simplified treatment of surfactant effects on cloud drop activation. Geosci Model Dev 4:107-116
262. Sorjamaa R, Laaksonen A (2006) The influence of surfactant properties on critical supersaturations of cloud condensation nuclei. J Aerosol Sci 37:1730-1736
263. Sorjamaa R, Svenningsson B, Raatikainen T, Henning S, Bilde M, Laaksonen A (2004) The role of surfactants in Kohler theory reconsidered. Atmos Chem Phys 4:2107-2117
264. Romakkaniemi S, Kokkola H, Smith JN, Prisle NL, Schwier AN, McNeill VF, Laaksonen A (2011) Partitioning of semivolatile surface-active compounds between bulk, surface, and gas-phase. Geophys Res Lett 38:L03807. doi:10.1029/ 2010GL046147
265. Topping D (2010) An analytical solution to calculate bulk mole fractions for any number of components in aerosol droplets after considering partitioning to a surface layer. Geosci Model Dev 3:635-642
266. Ghan SJ, Chung CC, Penner JE (1993) A parameterization of cloud droplet nucleation part I: Single aerosol type. Atmos Res 30:198-221
267. Abdul-Razzak H, Ghan SJ, Carpio CR (1998) A parameterization of aerosol activation 1. Single aerosol type. J Geophys Res Atmos 103:6123-6131
268. Abdul-Razzak H, Ghan SJ (2000) A parameterization of aerosol activation 2. Multiple aerosol types. J Geophys Res Atmos 105:6837-6844
269. Phinney LA, Lohmann U, Leaitch WR (2003) Limitations of using an equilibrium approximation in an aerosol activation parameterization. J Geophys Res Atmos 108:4371. doi:10.1029/2002JD002391
270. Anttila T, Kerminen VM (2002) Influence of organic compounds on the cloud droplet activation: A model investigation considering the volatility, water solubility, and surface activity of organic matter. J Geophys Res 107:4662. doi:10.1029/2001JD001482
271. Nenes A, Charlson RJ, Facchini MC, Kulmala M, Laaksonen A, Seinfeld JH (2002) Can chemical effects on cloud droplet number rival the first indirect effect? Geophys Res Lett 29:1848. doi:10.1029/2002GL015295
272. Rissman TA, Nenes A, Seinfeld JH (2004) Chemical amplification (or dampening) of the Twomey effect: Conditions derived from droplet activation theory. J Atmos Sci 61:919-930
273. Ervens B, Feingold G, Kreidenweis SM (2005) Influence of water-soluble organic carbon on cloud drop number concentration. J Geophys Res Atmos 110:D18211. doi:10.1029/ 2004JD005634
274. Feingold G, Chuang PY (2002) Analysis of the influence of film-forming compounds on droplet growth: Implications for cloud microphysical processes and climate. J Atmos Sci59:2006-2018
275. Lance S, Nenes A, Rissman TA (2004) Chemical and dynamical effects on cloud droplet number: Implications for estimates of the aerosol indirect effect. J Geophys Res Atmos 109: D22208. doi:10.1029/2004JD004596
276. Khvorostyanov VI, Curry JA (2008) Kinetics of cloud drop formation and its parameterization for cloud and climate models. J Atmos Sci 65:2784-2802
277. Asa-Awuku A, Engelhart GJ, Lee BH, Pandis SN, Nenes A (2009) Relating CCN activity, volatility, and droplet growth kinetics of beta-caryophyllene secondary organic aerosol. Atmos Chem Phys 9:795-812
278. Engelhart GJ, Asa-Awuku A, Nenes A, Pandis SN (2008) CCN activity and droplet growth kinetics of fresh and aged monoterpene secondary organic aerosol. Atmos Chem Phys 8:3937-3949
279. Shantz NC, Leaitch WR, Caffrey PF (2003) Effect of organics of low solubility on the growth rate of cloud droplets. J Geophys Res Atmos 108. doi:10.1029/2002JD002540
280. Hegg DA, Gao S, Hoppel W, Frick G, Caffrey P, Leaitch WR, Shantz N, Ambrusko J, Albrechcinski T (2001) Laboratory studies of the efficiency of selected organic aerosols as CCN. Atmos Res 58:155-166
281. Bilde M, Svenningsson B (2004) CCN activation of slightly soluble organics: The importance of small amounts of inorganic salt and particle phase. Tellus B 56:128-134
282. Garland RM, Wise ME, Beaver MR, Dewitt HL, Aiken AC, Jimenez JL, Tolbert MA (2005) Impact of palmitic acid coating on the water uptake and loss of ammonium sulfate particles. Atmos Chem Phys 5:1951-1961
283. Andrews E, Larson SM (1993) Effect of surfactant layers on the size changes of aerosolparticles as a function of relative-humidity. Environ Sci Technol 27:857-865
284. Chang RYW, Liu PSK, Leaitch WR, Abbatt JPD (2007) Comparison between measured and predicted CCN concentrations at Egbert, Ontario: Focus on the organic aerosol fraction at a semi-rural site. Atmos Environ 41:8172-8182
285. Shantz NC, Chang RYW, Slowik JG, Vlasenko A, Abbatt JPD, Leaitch WR (2010) Slower CCN growth kinetics of anthropogenic aerosol compared to biogenic aerosol observed at a rural site. Atmos Chem Phys 10:299-312
286. Ruehl CR, Chuang PY, Nenes A (2008) How quickly do cloud droplets form on atmospheric particles? Atmos Chem Phys 8:1043-1055
287. Ruehl CR, Chuang PY, Nenes A (2009) Distinct CCN activation kinetics above the marine boundary layer along the California coast. Geophys Res Lett 36. doi:10.1029/2009GL038839
288. Murphy SM, Agrawal H, Sorooshian A, Padró LT, Gates H, Hersey S, Welch WA, Jung H, Miller JW, Cocker DR, Nenes A, Jonsson HH, Flagan RC, Seinfeld JH (2009) Comprehensive simultaneous shipboard and airborne characterization of exhaust from a modern container ship at sea. Environ Sci Technol 43:4626-4640
289. Padró LT, Tkacik D, Lathem T, Hennigan CJ, Sullivan AP, Weber RJ, Huey LG, Nenes A (2010) Investigation of cloud condensation nuclei properties and droplet growth kinetics of the water-soluble aerosol fraction in Mexico City. J Geophys Res 115:D09204. doi:10.1029/ 2009JD013195
290. Fridlind AM, Jacobson MZ (2000) A study of gas-aerosol equilibrium and aerosol pH in the remote marine boundary layer during the first aerosol characterization experiment (ACE 1). J Geophys Res Atmos 105:17325-17340
291. Keene WC, Savoie DL (1998) The pH of deliquesced sea-salt aerosol in polluted marine air. Geophys Res Lett 25:2181-2184
292. Pszenny AAP, Moldanov J, Keene WC, Sander R, Maben JR, Martinez M, Crutzen PJ, Perner D, Prinn RG (2004) Halogen cycling and aerosol pH in the Hawaiian marine boundary layer. Atmos Chem Phys 4:147-168
293. Takahama S, Davidson CI, Pandis SN (2006) Semicontinuous measurements of organic carbon and acidity during the Pittsburgh air quality study: Implications for acid-catalyzed organic aerosol formation. Environ Sci Technol 40:2191-2199
294. Tang IN, Munkelwitz HR (1994) Water activities, densities, and refractive-indexes of aqueous sulfates and sodium-nitrate droplets of atmospheric importance. J Geophys Res Atmos 99:18801-18808
295. Tang IN, Tridico AC, Fung KH (1997) Thermodynamic and optical properties of sea salt aerosols. J Geophys Res Atmos 102:23269-23275
296. Kroll JH, Donahue NM, Jimenez JL, Kessler SH, Canagaratna MR, Wilson KR, Altieri KE, Mazzoleni LR, Wozniak AS, Bluhm H, Mysak ER, Smith JD, Kolb CE, Worsnop DR (2011) Carbon oxidation state as a metric for describing the chemistry of atmospheric organic aerosol. Nat Chem 3:133-139
297. Yatavelli RLN, Thornton JA (2010) Particulate organic matter detection using a micro-orifice volatilization impactor coupled to a chemical ionization mass spectrometer (MOVI-CIMS). Aerosol Sci Technol 44:67-74
298. Russell LM, Bahadur R, Ziemann PJ (2011) Identifying organic aerosol sources by comparing functional group composition in chamber and atmospheric particles. Proc Natl Acad Sci USA 108:3516-3521
299. McFiggans G, Artaxo P, Baltensperger U, Coe H, Facchini MC, Feingold G, Fuzzi S, Gysel M, Laaksonen A, Lohmann U, Mentel TF, Murphy DM, O'Dowd CD, Snider JR, Weingartner E (2006) The effect of physical and chemical aerosol properties on warm cloud droplet activation. Atmospheric Chemistry and Physics 6: 2593-2649