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Volumn 110, Issue 24, 2006, Pages 7593-7601

Evaporation of water and uptake of HCl and HBr through hexanol films at the surface of supercooled sulfuric acid

Author keywords

[No Author keywords available]

Indexed keywords

HEXANOL FILMS; SURFACE FILMS; WATER EVAPORATION;

EID: 33745700117     PISSN: 10895639     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp057260t     Document Type: Article
Times cited : (25)

References (74)
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  • 30
    • 33745776688 scopus 로고    scopus 로고
    • For a review of gas transport through surfactant films, see the introduction of ref 26
    • For a review of gas transport through surfactant films, see the introduction of ref 26.
  • 34
    • 33745785238 scopus 로고    scopus 로고
    • note
    • 4 at 213 K. New measurements in ref 48 show that the surface coverage is closer to 50%.
  • 36
    • 33745771737 scopus 로고    scopus 로고
    • for simulations showing that methanol enters unimpeded into methanol-coated water
    • See also Monta, A. Chem. Phys. Lett. 2003, 375, 1, for simulations showing that methanol enters unimpeded into methanol-coated water.
    • (2003) Chem. Phys. Lett. , vol.375 , pp. 1
    • Monta, A.1
  • 41
    • 33745782056 scopus 로고    scopus 로고
    • note
    • -. As emphasized in ref 15, α is not a useful parameter when some of the gas molecules react first at the surface, and we should not have used this variable in refs 27 and 34 to label HCl and HBr entry into sulfuric acid. The a notation is common in the literature, however, when it is unclear whether molecules enter the bulk intact or after reacting in the interfacial region.
  • 45
    • 0031407388 scopus 로고    scopus 로고
    • Calculations were performed at mae.ucdavis.edu/wexler/aim.htm.
    • Carslaw, K. S.; Peter, T.; Clegg, S. L. Rev. Geophys. 1997, 35, 125. Calculations were performed at mae.ucdavis.edu/wexler/aim.htm.
    • (1997) Rev. Geophys. , vol.35 , pp. 125
    • Carslaw, K.S.1    Peter, T.2    Clegg, S.L.3
  • 55
    • 33745781258 scopus 로고    scopus 로고
    • To be submitted for publication
    • Krier, J. M.; Nathanson, G. M. To be submitted for publication.
    • Krier, J.M.1    Nathanson, G.M.2
  • 61
    • 33745787258 scopus 로고    scopus 로고
    • Ph.D. Thesis, University of Wisconsin-Madison
    • Glass, S. V. Ph.D. Thesis, University of Wisconsin-Madison, 2005.
    • (2005)
    • Glass, S.V.1
  • 62
    • 33745796738 scopus 로고    scopus 로고
    • note
    • exch obtained from eq 1.
  • 63
    • 33745794465 scopus 로고    scopus 로고
    • To be submitted for publication. This article will explore detailed-balance constraints on the connection between HCl solvation times and entry probabilities in surfactant-coated sulfuric acid
    • Park, S.-C.; Glass, S. V.; Nathanson, G. M. To be submitted for publication. This article will explore detailed-balance constraints on the connection between HCl solvation times and entry probabilities in surfactant-coated sulfuric acid.
    • Park, S.-C.1    Glass, S.V.2    Nathanson, G.M.3
  • 70
    • 33745800453 scopus 로고    scopus 로고
    • note
    • 2O.
  • 72
    • 0043234732 scopus 로고    scopus 로고
    • The entry probability of HCl into pure 1-octanol droplets is only 0.008 at 273 K, suggesting that this surfactant may significantly impede HCl uptake into sulfuric acid. In contrast, the more polarizable and more acidic HBr molecule enters 1-octanol on each collision. See Zhang, H. Z.; Li, Y. Q.; Davidovits, P.; Williams, L. R.; Jayne, J. T.; Kolb, C. E.; Worsnop, D. R. J. Phys. Chem. A 2003, 107, 6398.
    • (2003) J. Phys. Chem. A , vol.107 , pp. 6398
    • Zhang, H.Z.1    Li, Y.Q.2    Davidovits, P.3    Williams, L.R.4    Jayne, J.T.5    Kolb, C.E.6    Worsnop, D.R.7


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.