Reactive processing of formaldehyde and acetaldehyde in aqueous aerosol mimics: Surface tension depression and secondary organic products

Atmospheric Chemistry and Physics

Volumn 11, Issue 22, 2011, Pages 11617-11629

  Li, Z ^a   Schwier, A N ^a   Sareen, N ^a   McNeill, V F ^a  

^a Columbia University ^*  (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ACETALDEHYDE; AEROSOL; CARBONYL COMPOUND; CHEMICAL REACTION; FORMALDEHYDE; SURFACE TENSION; VOLATILE ORGANIC COMPOUND;

EID: 80955128580     PISSN: 16807316     EISSN: 16807324     Source Type: Journal    
DOI: 10.5194/acp-11-11617-2011     Document Type: Article

References (41)

1. Adamson, A. W. and Gast, A. P., Physical chemistry of surfaces, Wiley, New York, 1997.
2. Baboukas, E. D., Kanakidou, M., and Mihalopoulos, N.: Car-boxylic acids in gas and particulate phase above the Atlantic Ocean, J. Geophys. Res., 105, 14459-14471, 2000.
3. Betterton, E. A. and Hoffmann, M. R.: Henry Law Constants of Some Environmentally Important Aldehydes, Environ. Sci. Technol., 22, 1415-1418, 1988. (Pubitemid 19002984)
4. Casale, M. T., Richman, A. R., Elrod, M. J., Garland, R. M., Beaver, M. R., and Tolbert, M. A.: Kinetics of acid-catalyzed aldol condensation reactions of aliphatic aldehydes, Atmos. Environ., 41, 6212-6224, 2007. (Pubitemid 47268190)
5. Deno, N. C. and Newman, M. S.: Mechanism of Sulfation of Alcohols, J. Am. Chem. Soc., 72, 3852-3856, 1950.
6. Djikaev, Y. S. and Tabazadeh, A.: Effect of adsorption on the uptake of organic trace gas by cloud droplets, J. Geophys. Res.-Atmos., 108, 4869, doi:10.1029/2003JD003741, 2003.
7. Donaldson, D. J. and Vaida, V.: The influence of organic films at the air-aqueous boundary on atmospheric processes, Chem. Rev., 106, 1445-1461, 2006. (Pubitemid 43676514)
8. Ervens, B. and Volkamer, R.: Glyoxal processing by aerosol multiphase chemistry: towards a kinetic modeling framework of secondary organic aerosol formation in aqueous particles, Atmos. Chem. Phys., 10, 8219-8244, doi:10.5194/acp-10-8219-2010, 2010.
9. Ervens, B., Turpin, B. J., and Weber, R. J.: Secondary organic aerosol formation in cloud droplets and aqueous particles (aqSOA): a review of laboratory, field and model studies, Atmos. Chem. Phys., 11, 11069-11102, doi:10.5194/acp-11-11069-2011, 2011.
10. Facchini, M. C., Mircea, M., Fuzzi, S., and Charlson, R. J.: Cloud albedo enhancement by surface-active organic solutes in growing droplets, Nature, 401, 257-259, 1999.
11. Folkers, M., Mentel, T. F., and Wahner, A.: Influence of an organic coating on the reactivity of aqueous aerosols probed by the heterogeneous hydrolysis of N2O5, Geophys. Res. Lett., 30, 1644-1647, 2003.
12. Fung, K. and Wright, B.: Measurement of Formaldehyde and Ac-etaldehyde using 2,4-dinitrophenylhydrazine-impregnated cartridges during the carbonaceous species methods comparison study, Aerosol Sci. Technol., 12, 44-48, 1990. (Pubitemid 20195263)
13. Galloway, M. M., Chhabra, P. S., Chan, A. W. H., Surratt, J. D., Flagan, R. C., Seinfeld, J. H., and Keutsch, F. N.: Glyoxal uptake on ammonium sulphate seed aerosol: reaction products and reversibility of uptake under dark and irradiated conditions, At-mos. Chem. Phys., 9, 3331-3345, doi:10.5194/acp-9- 3331-2009, 2009.
14. Grosjean, D.: Formaldehyde and other carbonyl in Los Angeles ambient air, Environ. Sci. Technol., 16, 254-262, 1982. (Pubitemid 12077996)
15. Healy, R. M., Wenger, J. C., Metzger, A., Duplissy, J., Kalberer, M., and Dommen, J.: Gas/particle partitioning of carbonyls in the photooxidation of isoprene and 1,3,5-trimethylbenzene, At-mos. Chem. Phys., 8, 3215-3230, doi:10.5194/acp-8-3215-2008, 2008.
16. Henning, S., Rosenørn, T., D'Anna, B., Gola, A. A., Svenningsson, B., and Bilde, M.: Cloud droplet activation and surface tension of mixtures of slightly soluble organics and inorganic salt, Atmos. Chem. Phys., 5, 575-582, doi:10.5194/acp-5-575-2005, 2005. (Pubitemid 40405306)
17. Jimenez, J. L., Canagaratna, M. R., Donahue, N. M., Prevot, A. S. H., Zhang, Q., Kroll, J. H., DeCarlo, P. F., Allan, J. D., Coe, H., Ng, N. L., Aiken, A. C., Docherty, K. S., Ulbrich, I. M., Grieshop, A. P., Robinson, A. L., Duplissy, J., Smith, J. D., Wilson, K. R., Lanz, V. A., Hueglin, C., Sun, Y. L., Tian, J., Laak-sonen, A., Raatikainen, T., Rautiainen, J., Vaattovaara, P., Ehn, M., Kulmala, M., Tomlinson, J. M., Collins, D. R., Cubison, M. J., Dunlea, E. J., Huffman, J. A., Onasch, T. B., Alfarra, M. R., Williams, P. I., Bower, K., Kondo, Y., Schneider, J., Drewnick, F., Borrmann, S., Weimer, S., Demerjian, K., Salcedo, D., Cot-trell, L., Griffin, R., Takami, A., Miyoshi, T., Hatakeyama, S., Shimono, A., Sun, J. Y., Zhang, Y. M., Dzepina, K., Kimmel, J. R., Sueper, D., Jayne, J. T., Herndon, S. C., Trimborn, A. M., Williams, L. R., Wood, E. C., Middlebrook, A. M., Kolb, C. E., Baltensperger, U., and Worsnop, D. R.: Evolution of Organic Aerosols in the Atmosphere, Science, 326, 1525-1529, 2009.
18. Kanakidou, M., Seinfeld, J. H., Pandis, S. N., Barnes, I., Dentener, F. J., Facchini, M. C., Van Dingenen, R., Ervens, B., Nenes, A., Nielsen, C. J., Swietlicki, E., Putaud, J. P., Balkanski, Y., Fuzzi, S., Horth, J., Moortgat, G. K., Winterhalter, R., Myhre, C. E. L., Tsigaridis, K., Vignati, E., Stephanou, E. G., and Wilson, J.: Organic aerosol and global climate modelling: a review, At-mos. Chem. Phys., 5, 1053-1123, doi:10.5194/acp-5-1053-2005, 2005. (Pubitemid 40560480)
19. Köhler, H.: The nucleus in the growth of hygroscopic droplets, Trans. Faraday Soc., 32, 1152-1161, 1936.
20. Kroll, J. H., Ng L. N., Murphy, S. M., Varutbangkul, V., Fla-gan, R. C., and Seinfeld, J. H.: Chamber studies of secondary organic aerosol growth by reactive uptake of simple carbonyl compounds, J. Geophys. Res., 110, D23207, doi:10.1029/2005JD006004, 2005. (Pubitemid 43141257)
21. Lim, Y. B., Tan, Y., Perri, M. J., Seitzinger, S. P., and Turpin, B. J.: Aqueous chemistry and its role in secondary organic aerosol (SOA) formation, Atmos. Chem. Phys., 10, 10521-10539, doi:10.5194/acp-10-10521-2010, 2010.
22. Loudon, G. M.: Organic chemistry, Roberts and Co, Greenwood Village, Colo, 2009.
23. McNeill, V. F., Patterson, J., Wolfe, G. M., and Thornton, J. A.: The effect of varying levels of surfactant on the reactive uptake of N2O5 to aqueous aerosol, Atmos. Chem. Phys., 6, 1635-1644, doi:10.5194/acp-6-1635-2006, 2006. (Pubitemid 44198619)
24. Minerath, E. C., Casale, M. T., and Elrod, M. J.: Kinetics feasibility study of alcohol sulfate esterification reactions in tropospheric aerosols, Environ. Sci. Technol., 42, 4410-4415, 2008. (Pubitemid 351842383)
25. Munger, J. W., Jacob, D. J., Daube, B. C., Horowitz, L. W., Keene, W. C., and Heikes, B. G.: Formaldehyde, glyoxal, and methyl-glyoxal in air and cloudwater at a rural mountain site in central Virginia, J. Geophys. Res., 100, 9325-9333, 1995. (Pubitemid 26436858)
26. Nozière, B., Dziedzic, P., and Córdova, A.: Products and Kinetics of the Liquid-Phase Reaction of Glyoxal Catalyzed by Ammonium Ions (NH4+), J. Phys. Chem. A, 113, 231-237, 2009.
27. Nozière, B., Dziedzic, P., and Córdova, A.: Inorganic ammonium salts and carbonate salts are efficient catalysts for aldol condensation in atmospheric aerosols, Phys. Chem. Chem. Phys., 12, 3864-3872, 2010a.
28. Nozière, B., Ekström, S., Alsberg, T., and Holmström, S.: Radical-initiated formation of organosulfates and surfactants in atmospheric aerosols, Geophys. Res. Lett., 37, L05806, doi:10.1029/2009GL041683, 2010b.
29. Perri, M. J., Lim, Y. B., Seitzinger, S. P., and Turpin, B. J.: Organosulfates from glycolaldehyde in aqueous aerosols and clouds: Laboratory studies, Atmos. Environ., 44, 2658-2664, 2010.
30. Romakkaniemi, S., Kokkola, H., Smith, J. N., Prisle, N. L., Schwier, A. N., McNeill, V. F., and Laaksonen, A.: Partitioning of Semivolatile Surface-Active Compounds Between Bulk, Surface, and Gas-Phase, Geophys. Res. Lett., 38, L03807, doi:10.1029/2010GL046147, 2011.
31. Sareen, N., Schwier, A. N., Shapiro, E. L., Mitroo, D., and McNeill, V. F.: Secondary organic material formed by methylglyoxal in aqueous aerosol mimics, Atmos. Chem. Phys., 10, 997-1016, doi:10.5194/acp-10-997-2010, 2010.
32. Schwier, A. N., Sareen, N., Mitroo, D. M., Shapiro, E. L., and McNeill, V. F.: Glyoxal-Methylglyoxal Cross-Reactions in Secondary Organic Aerosol Formation, Environ. Sci. Technol., 44, 6174-6182, 2010.
33. Seinfeld, J. H. and Pandis, S. N.: Atmospheric chemistry and physics from air pollution to climate change, Wiley, New York, 1998.
34. Setschenow, J. Z.: Uber Die Konstitution Der Salzosungen auf Grund ihres Verhaltens zu Kohlensaure, Z. Phys. Chem., 4, 117-125, 1889.
35. Shapiro, E. L., Szprengiel, J., Sareen, N., Jen, C. N., Giordano, M. R., and McNeill, V. F.: Light-absorbing secondary organic material formed by glyoxal in aqueous aerosol mimics, Atmos. Chem. Phys., 9, 2289-2300, doi:10.5194/acp-9-2289-2009, 2009.
36. Shulman, M. L., Jacobson, M. C., Carlson, R. J., Synovec, R. E., and Young, T. E.: Dissolution behavior and surface tension effects of organic compounds in nucleating cloud droplets, Geo-phys. Res. Lett., 23, 277-280, 1996.
37. Tan, Y., Perri, M. J., Seitzinger, S. P., and Turpin, B. J.: Effects of Precursor Concentration and Acidic Sulfate in Aqueous Glyoxal-OH Radical Oxidation and Implications for Secondary Organic Aerosol, Environ. Sci. Technol., 43, 8105-8112, 2009.
38. Tan, Y., Carlton, A. G., Seitzinger, S. P., and Turpin, B. J.: SOA from methylglyoxal in clouds and wet aerosols: Measurement and prediction of key products, Atmos. Environ., 44, 5218-5226, 2010.
39. Wang, X. F., Gao, S., Yang, X., Chen, H., Chen, J. M., Zhuang, G. S., Surratt, J. D., Chan, M. N., and Seinfeld, J. H.: Evidence for High Molecular Weight Nitrogen-Containing Organic Salts in Urban Aerosols, Environ. Sci. Technol., 44, 4441-4446, 2010.
40. Yu, G., Bayer, A. R., Galloway, M. M., Korshavn, K. J., Fry, C. G., and Keutsch, F. N.: Glyoxal in Aqueous Ammonium Sulfate Solutions: Products, Kinetics and Hydration Effects, Environ. Sci. Technol., 45, 6336-6342, 2011.
41. Zhou, X. L. and Mopper, K.: Apparent Partition-Coefficients of 15 Carbonyl-Compounds Between Air and Seawater and Between Air and Fresh-Water-Implications for Air Sea Exchange, Environ. Sci. Technol., 24, 1864-1869, 1990.