Direct observations of N2O5 reactivity on ambient aerosol particles

Geophysical Research Letters

Volumn 36, Issue 19, 2009, Pages

  Bertram, Timothy H ^a,b   Thornton, Joel A ^a   Riedel, Theran P ^a   Middlebrook, Ann M ^c   Bahreini, Roya ^c,d   Bates, Timothy S ^e   Quinn, Patricia K ^e   Coffman, Derek J ^e  

^a UNIVERSITY OF WASHINGTON   (United States)

^b UNIVERSITY OF CALIFORNIA   (United States)

^c EARTH SYSTEM RESEARCH LABORATORY   (United States)

^d UNIVERSITY OF COLORADO   (United States)

^e NOAA EARTH SYSTEM RESEARCH LABORATORY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

AEROSOL FLOW REACTORS; AEROSOL PARTICLES; AMBIENT AEROSOLS; CHEMICAL COMPOSITIONS; CHEMICAL IONIZATION; DIRECT OBSERVATION; LARGE-SCALE MODELS; ORGANIC MASS; OZONE PRODUCTION; PARAMETERIZATIONS; RELATIVE HUMIDITIES; URBAN LOCATIONS;

ATMOSPHERIC AEROSOLS; ATMOSPHERIC HUMIDITY; ATMOSPHERIC MOVEMENTS; ATMOSPHERICS; MASS SPECTROMETRY; MOISTURE; OZONE; REACTION RATES;

CHEMICAL REACTIVITY;

AEROSOL COMPOSITION; AMBIENT AIR; MASS SPECTROMETRY; NITROGEN OXIDES; OZONE; PARAMETERIZATION; REACTION RATE; RELATIVE HUMIDITY; URBAN ATMOSPHERE;

EID: 72049120921     PISSN: 00948276     EISSN: None     Source Type: Journal    
DOI: 10.1029/2009GL040248     Document Type: Article

References (31)

1. 5 by aerosol particles containing mixtures of humic acid and ammonium sulfate, J. Phys. Chem. A, 110(21), 6986-6994, doi:10.1021/jp0562678.
2. 5 with NaCl solution: Bulk and aerosol experiments, J. Geophys. Res., 102(D3), 3795-3804, doi:10.1029/96JD03057.
3. 5 reactivity on aqueous particles: the competing effects of particle liquid water, nitrate and chloride, Atmos. Chem. Phys. Discuss., 9, 15,181-15,214.
4. 5 reactivity on ambient particles, Atmos. Meas. Tech., 2, 231-242.
5. Brown, S. S., et al. (2006), Variability in nocturnal nitrogen oxide processing and its role in regional air quality, Science, 311(5757), 67-70, doi:10.1126/science.1120120.
6. 5 determined from aircraft measurements during the Second Texas Air Quality Study: Comparison to current model parameterizations, J. Geophys. Res., 114, D00F10, doi:10.1029/2008JD011679.
7. Carslaw, K. S., et al. (1995), A thermodynamic model of the system HCl-HNO3-H2SO4-H2O, including solubilities of HBr, from less than 200 to 328 K, J. Phys. Chem., 99(29), 11,557-11,574, doi:10.1021/ j100029a039.
8. Davis, J. M., et al. (2008), Parameterization of N2O5 reaction probabilities on the surface of particles containing ammonium, sulfate, and nitrate, Atmos. Chem. Phys., 8, 5295-5311.
9. DeCarlo, P. F., et al. (2006), Field-deployable, high-resolution, time-of-flight aerosol mass spectrometer, Anal. Chem., 78(24), 8281-8289, doi:10.1021/ac061249n.
10. 3, and OH, J. Geophys. Res., 98(D4), 7149-7163, doi:10.1029/92JD02979.
11. Drewnick, F., et al. (2005), A new time-of-flight aerosol mass spectrometer (TOF-AMS)-Instrument description and first field deployment, Aerosp. Sci. Technol., 39(7), 637-658, doi:10.1080/02786820500182040. (Pubitemid 41318222)
12. 5 hydrolysis on global model budgets of tropospheric nitrogen oxides, ozone, and OH, Geophys. Res. Lett., 32, L09813, doi:10.1029/0 2005GL022469.
13. 2, Nature, 337(6204), 241-244, doi:10.1038/ 337241a0.
14. 5, Geophys. Res. Lett., 30(12), 1644, doi:10.1029/ 2003GL017168.
15. 5 by aerosols containing dicarboxylic acids. Effect of particle phase, composition, and nitrate content, J. Phys. Chem. A, 113(17), 5082-5090, doi:10.1021/jp8096814.
16. Jayne, J. T., et al. (2000), Development of an aerosol mass spectrometer for size and composition analysis of submicron particles, Aerosp. Sci. Technol., 33(1-2), 49-70.
17. 5 by chemical ionization mass spectrometry, Atmos. Meas. Tech., 2, 193-204.
18. Kondo, Y., Y. Miyazaki, N. Takegawa, T. Miyakawa, R. J. Weber, J. L. Jimenez, Q. Zhang, and D. R. Worsnop (2007), Oxygenated and water-soluble organic aerosols in Tokyo, J. Geophys. Res., 112, D01203, doi:10.1029/ 2006JD007056. (Pubitemid 47260899)
19. Martin, S. T., T. Rosenoern, Q. Chen, and D. R. Collins (2008), Phase changes of ambient particles in the Southern Great Plains of Oklahoma, Geophys. Res. Lett., 35, L22801, doi:10.1029/2008GL035650.
20. McNeill, V. F., et al. (2006), The effect of varying levels of surfactant on the reactive uptake of N2O5 to aqueous aerosol, Atmos. Chem. Phys., 6, 1635-1644. (Pubitemid 44198619)
21. Mentel, T. F., et al. (1999), Nitrate effect in the heterogeneous hydrolysis of dinitrogen pentoxide on aqueous aerosols, Phys. Chem. Chem. Phys., 1(24), 5451-5457.
22. Mochida, M., T. Miyakawa, N. Takegawa, Y. Morino, K. Kawamura, and Y. Kondo (2008), Significant alteration in the hygroscopic properties of urban aerosol particles by the secondary formation of organics, Geophys. Res. Lett., 35, L02804, doi:10.1029/2007GL031310.
23. Mozurkewich, M., and J. G. Calvert (1988), Reaction probability of N2O5 on aqueous aerosols, J. Geophys. Res., 93(D12), 15,889-15,896, doi:10.1029/JD093iD12p15889.
24. Murphy, D. M., D. J. Cziczo, K. D. Froyd, P. K. Hudson, B. M. Matthew, A. M. Middlebrook, R. E. Peltier, A. Sullivan, D. S. Thomson, and R. J. Weber (2006), Single-particle mass spectrometry of tropospheric aerosol particles, J. Geophys. Res., 111, D23S32, doi:10.1029/2006JD007340.
25. 3), Atmos. Chem. Phys., 8, 4117-4140.
26. Parsons, M. T., J. Mak, S. R. Lipetz, and A. K. Bertram (2004), Deliquescence of malonic, succinic, glutaric, and adipic acid particles, J. Geophys. Res., 109, D06212, doi:10.1029/2003JD004075.
27. Quinn, P. K., et al. (2005), Impact of particulate organic matter on the relative humidity dependence of light scattering: A simplified parameterization, Geophys. Res. Lett., 32, L22809, doi:10.1029/2005GL024322.
28. 5 on chemistry and nitrate aerosol formation in the lower troposphere under photosmog conditions, J. Geophys. Res., 108(D4), 4144, doi:10.1029/2002JD002436.
29. 5 hydrolysis on sub-micron organic aerosols: the effect of relative humidity, particle phase, and particle size, Phys. Chem. Chem. Phys., 5(20), 4593-4603.
30. 5 on sodium nitrate aerosol, J. Geophys. Res., 103(D23), 31,103-31,112, doi:10.1029/ 1998JD100022.
31. Zhang, Q., et al. (2007), Ubiquity and dominance of oxygenated species in organic aerosols in anthropogenically-influenced Northern Hemisphere midlatitudes, Geophys. Res. Lett., 34, L13801, doi:10.1029/ 2007GL029979. (Pubitemid 47399659)