Theoretical analysis of the mechanism of palladium(II) acetate-catalyzed oxidative heck coupling of electron-deficient arenes with alkenes: Effects of the pyridine-type ancillary ligand and origins of the meta -regioselectivity

Journal of the American Chemical Society

Volumn 133, Issue 50, 2011, Pages 20218-20229

  Zhang, Songlin ^a   Shi, Li ^a   Ding, Yuqiang ^a  

^a JIANGNAN UNIVERSITY   (China)

Author keywords

[No Author keywords available]

Indexed keywords

ACTIVATION BARRIERS; ALKENE INSERTION; ALKENE SUBSTRATE; ANCILLARY LIGANDS; BENZENE RING; BOND METATHESIS; C-H ACTIVATION; C-H BOND; CATALYTIC CYCLES; CH-BOND ACTIVATION; COUPLING REACTION; CROSS-COUPLINGS; DOUBLE BONDS; ELECTRON-DEFICIENT; ELECTRONIC EFFECTS; EXPERIMENTAL OBSERVATION; FURTHER DEVELOPMENT; HECK COUPLING; HOMOCOUPLING; METALATIONS; MONOSUBSTITUTED BENZENES; OXIDATIVE ADDITIONS; PYRIDINE LIGANDS; REACTION PATHWAYS; SIX-MEMBERED RINGS; STERIC REPULSIONS; THEORETICAL STUDY;

ACTIVATION ANALYSIS; AROMATIC COMPOUNDS; BENZENE; CATALYSIS; LIGANDS; OLEFINS; ORGANOMETALLICS; PALLADIUM; PALLADIUM COMPOUNDS; PYRIDINE; REACTION INTERMEDIATES; REGIOSELECTIVITY; TRANSITION METALS;

BIOACTIVITY;

ALKENE DERIVATIVE; PALLADIUM ACETATE; POLYCYCLIC AROMATIC HYDROCARBON; PYRIDINE;

ARTICLE; CATALYSIS; CHEMICAL BOND; CHEMICAL STRUCTURE; CROSS COUPLING REACTION; ELECTRON; HECK COUPLING; OXIDATION; STEREOCHEMISTRY; THEORETICAL STUDY;

CATALYSIS; CYCLIZATION; ELECTRONS; LIGANDS; MODELS, THEORETICAL; OXIDATION-REDUCTION; PALLADIUM;

EID: 83755169020     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja205294y     Document Type: Article

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