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For the first discussion of the concept of “on-water reactions” see: For a review, see
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For representative examples of the use of water as solvent in common organic reactions, see: Cycloaddition reactions: Claisen rearrangement
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For representative examples of the use of water as solvent in common organic reactions, see: Cycloaddition reactions: R. N. Butler W. J. Cunningham A. G. Coyne Helv. Chim. Acta 2005 88 1611. Claisen rearrangement.
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Coyne, A.G.3
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Two previous reports exist of the synthesis of dihydrofurans using pyridinium ylides, involving (i) aromatic aldehydes and cyclohexane-1,3-dione/dimedone/4-hydroxycoumarin which formed the Michael acceptors, viz.α,β-unsaturated 1,3-diones and (ii) acyclic α,β-unsaturated ketones/esters. All these reactions were performed in organic solvents, namely acetonitrile or i-PrOH. See
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Two previous reports exist of the synthesis of dihydrofurans using pyridinium ylides, involving (i) aromatic aldehydes and cyclohexane-1,3-dione/dimedone/4-hydroxycoumarin which formed the Michael acceptors, viz.α,β-unsaturated 1,3-diones and (ii) acyclic α,β-unsaturated ketones/esters. All these reactions were performed in organic solvents, namely acetonitrile or i-PrOH. See: C. P. Chuang A. I. Tsai Synthesis 2006 4 675.
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