A general synthesis of N-substituted 1,4-benzoxazine- and 1,4-benzothiazine-2-carboxylates via copper-catalyzed intramolecular amination of arylbromides

Tetrahedron

Volumn 67, Issue 36, 2011, Pages 6826-6832

  Melkonyan, Ferdinand ^a   Topolyan, Artiom ^a   Karchava, Alexander ^a   Yurovskaya, Marina ^a  

^a MOSCOW STATE UNIVERSITY   (Russian Federation)

Author keywords

1,4 Benzothiazine; 1,4 Benzoxazine; Copper catalyzed reactions; Cyclization; Heterocycles; Ullmann amination reaction

Indexed keywords

AMINE; BENZOTHIAZINE DERIVATIVE; CARBOXYLIC ACID DERIVATIVE; COPPER; DIMETHYL 4 (3 BROMOPHENYL) 4H 1,4 BENZOXAZINE 2,6 DICARBOXYLATE; DIMETHYL 4 (4 METHOXYPHENYL) 4H 1,4 BENZOXAZINE 2,6 DICARBOXYLATE; DIMETHYL 4 BENZYL 4H 1,4 BENZOXAZINE 2,6 DICARBOXYLATE; METHYL 2 (2 BROMO 5 FLUOROPHENOXY) 3 OXOPROPANOATE; METHYL 2 (2 BROMOPHENOXY) 3 OXOPROPANOATE; METHYL 2 [(2 BROMOPHENYL)THIO] 3 OXOPROPANOATE; METHYL 3 (TERT BUTYLAMINO) 2 (4 METHYLPHENOXY)ACRYLATE; METHYL 3 BROMO 4 (1 FORMYL 2 METHOXY 2 OXOETHOXY)BENZOATE; METHYL 3 BROMO 4 (2 METHOXY 2 OXOETHOXY)BENZOATE; METHYL 4 (1 NAPHTHYL) 4H 1,4 BENZOXAZINE 2 CARBOXYLATE; METHYL 4 (1 PHENYLETHYL) 4H 1,4 BENZOXAZINE 2 CARBOXYLATE; METHYL 4 (3 BROMOPHENYL) 4H 1,4 BENZOXAZINE 2 CARBOXYLATE; METHYL 4 (4 METHOXYPHENYL) 6 METHYL 4H 1,4 BENZOXAZINE 2 CARBOXYLATE; METHYL 4 (TETRAHYDROFURAN 2 YLMETHYL) 4H 1,4 BENZOXAZINE 2 CARBOXYLATE; METHYL 4 [3 (TRIFLUOROMETHYL)PHENYL] 4H 1,4 BENZOTHIAZINE 2 CARBOXYLATE; METHYL 4 BENZYL 4H 1,4 BENZOTHIAZINE 2 CARBOXYLATE; METHYL 4 BENZYL 6 METHYL 4H 1,4 BENZOXAZINE 2 CARBOXYLATE; METHYL 4 BENZYL 7 FLUORO 4H 1,4 BENZOXAZINE 2 CARBOXYLATE; METHYL 4 CYCLOHEXYL 4H 1,4 BENZOXAZINE 2 CARBOXYLATE; METHYL 4 CYCLOPROPYL 4H 1,4 BENZOTHIAZINE 2 CARBOXYLATE; METHYL 4 MESITYL 4H 1,4 BENZOXAZINE 2 CARBOXYLATE; METHYL 6 METHYL 4 (2 PHENYLETHYL) 4H 1,4 BENZOXAZINE 2 CARBOXYLATE; METHYL 6 METHYL 4 [3 (TRIFLUOROMETHYL)PHENYL] 4H 1,4 BENZOXAZINE 2 CARBOXYLATE; METHYL(2 BROMO 4 METHYLPHENOXY) 3 OXOPROPANOATE; UNCLASSIFIED DRUG;

AMINATION; AMINO ACID SUBSTITUTION; ARTICLE; CATALYSIS; CATALYST; CHEMICAL ANALYSIS; CHEMICAL STRUCTURE; CYCLIZATION; PRIORITY JOURNAL; STRUCTURE ANALYSIS; SUBSTITUTION REACTION; SYNTHESIS; X RAY DIFFRACTION;

EID: 80051548995     PISSN: 00404020     EISSN: 14645416     Source Type: Journal    
DOI: 10.1016/j.tet.2011.06.081     Document Type: Article

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