Experimental evidence for cobalt(III)-carbene radicals: Key intermediates in cobalt(II)-based metalloradical cyclopropanation

Journal of the American Chemical Society

Volumn 133, Issue 22, 2011, Pages 8518-8521

  Lu, Hongjian ^a   Dzik, Wojciech I ^b   Xu, Xue ^a   Wojtas, Lukasz ^a   De Bruin, Bas ^b   Zhang, X Peter ^a  

^a UNIVERSITY OF SOUTH FLORIDA   (United States)

^b UNIVERSITY OF AMSTERDAM   (Netherlands)

Author keywords

[No Author keywords available]

Indexed keywords

1 ,5-HEXADIENE; ALLYLIC RADICALS; C-O BOND FORMATION; CARBENES; COBALT COMPLEXES; CYCLOPROPANATION; DFT CALCULATION; DIMERIC STRUCTURE; DINUCLEAR; EXPERIMENTAL EVIDENCE; HYDROGEN ATOMS; METALLOPORPHYRINS; PORPHYRIN COMPLEXES; TOLUENE SOLVENT; UNDERLYING MECHANISM; X RAY STRUCTURAL ANALYSIS;

COBALT; OLEFINS; ORGANIC SOLVENTS; PORPHYRINS; RESONANCE; STRUCTURAL ANALYSIS; TOLUENE;

COBALT COMPOUNDS;

1,5 HEXADIENE; 2,2,6,6 TETRAMETHYLPIPERIDINE N OXIDE; ALKENE DERIVATIVE; CARBENE; CARBON; COBALT; COBALT COMPLEX; COBALT VINYLCARBENE; HYDROGEN; METALLOPORPHYRIN; OXYGEN; PIPERIDINE DERIVATIVE; PORPHYRIN; RADICAL; TOLUENE; UNCLASSIFIED DRUG;

ARTICLE; ATOM; CHEMICAL BOND; COMPLEX FORMATION; CRYSTAL STRUCTURE; CYCLOPROPANATION; DENSITY FUNCTIONAL THEORY; DIMERIZATION; SUBSTITUTION REACTION; X RAY CRYSTALLOGRAPHY;

EID: 79958017831     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja203434c     Document Type: Article

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