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Volumn 14, Issue 25, 2008, Pages 7594-7599

Selective C-C coupling of Ir-ethene and Ir-carbenoid radicals

Author keywords

Carbenes; Iridium; Radicals; Redox chemistry

Indexed keywords

ETHYLENE; IRIDIUM COMPOUNDS; ORGANIC COMPOUNDS;

EID: 53849141867     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.200800262     Document Type: Conference Paper
Times cited : (45)

References (64)
  • 1
    • 34548711787 scopus 로고    scopus 로고
    • II species, see: a D. G. H. Hetterscheid, H. Grützmacher, A. J. J. Koekoek, B. de Bruin, Prog. Inorg. Chem. 2007, 55, 247-354;
    • II species, see: a) D. G. H. Hetterscheid, H. Grützmacher, A. J. J. Koekoek, B. de Bruin, Prog. Inorg. Chem. 2007, 55, 247-354;
  • 6
    • 33845279086 scopus 로고
    • b) M. C. Baird, Chem. Rev. 1988, 88, 1217-1227;
    • (1988) Chem. Rev , vol.88 , pp. 1217-1227
    • Baird, M.C.1
  • 7
    • 53849139342 scopus 로고    scopus 로고
    • Organometallic Radical Processes: J. Organomet. Chem. Libr. 1990, 22, whole
    • c) "Organometallic Radical Processes": J. Organomet. Chem. Libr. 1990, 22, whole volume;
  • 9
    • 53849122884 scopus 로고
    • Paramagnetic Organometallic Species in Activation/Selectivity, Catalysis
    • whole
    • e) Paramagnetic Organometallic Species in Activation/Selectivity, Catalysis: NATO ASI Ser. Ser. C 1987, 257, whole volume;
    • (1987) NATO ASI Ser. Ser. C , vol.257
  • 13
    • 0000714026 scopus 로고    scopus 로고
    • i) R. Poli, Chem. Rev. 1996, 96, 2135-2204;
    • (1996) Chem. Rev , vol.96 , pp. 2135-2204
    • Poli, R.1
  • 14
    • 4043120496 scopus 로고    scopus 로고
    • j) C. Limberg, Angew. Chem. 2003, 115 6112-6136;
    • (2003) Angew. Chem , vol.115 , pp. 6112-6136
    • Limberg, C.1
  • 15
    • 0346094026 scopus 로고    scopus 로고
    • Angew. Chem. Int. Ed. 2003, 42, 5932-5954.
    • (2003) Angew. Chem. Int. Ed , vol.42 , pp. 5932-5954
  • 20
  • 32
    • 0000100584 scopus 로고    scopus 로고
    • For examples of Co- and Rh-catalyzed reactions, see: M. P. Doyle, D. C. Forbes, Chem. Rev. 1998, 98, 911-935, and references therein
    • For examples of Co- and Rh-catalyzed reactions, see: M. P. Doyle, D. C. Forbes, Chem. Rev. 1998, 98, 911-935, and references therein.
  • 33
    • 53549099187 scopus 로고    scopus 로고
    • Recently an [IrIIIsalen, complex proved as efficient catalyst for cyclopropanation of styrene
    • III(salen)] complex proved as efficient catalyst for cyclopropanation of styrene: S. Kanchiku, H. Suematsu, K. Matsumoto, T. Uchida, T. Katsuki, Angew. Chem. 2007, 119, 3963-3965;
    • (2007) Angew. Chem , vol.119 , pp. 3963-3965
    • Kanchiku, S.1    Suematsu, H.2    Matsumoto, K.3    Uchida, T.4    Katsuki, T.5
  • 34
    • 34250726079 scopus 로고    scopus 로고
    • Angew. Chem. Int. Ed. 2007, 46, 3889-3891.
    • (2007) Angew. Chem. Int. Ed , vol.46 , pp. 3889-3891
  • 40
    • 0242667840 scopus 로고    scopus 로고
    • Hybrid HF/DFT functionals (such as b3-lyp) tend to overestimate the relative stability of radicals compared to closed-shell systems: a) M. Saeys, M.-F. Reyniers, G. B. Marin, V. Van Speybroeck, Waroquir, J. Phys. Chem. A 2003, 107, 9147-9159;
    • Hybrid HF/DFT functionals (such as b3-lyp) tend to overestimate the relative stability of radicals compared to closed-shell systems: a) M. Saeys, M.-F. Reyniers, G. B. Marin, V. Van Speybroeck, Waroquir, J. Phys. Chem. A 2003, 107, 9147-9159;
  • 44
    • 53849145557 scopus 로고    scopus 로고
    • Ph.D. Thesis, Radboud University Nijmegen The Netherlands
    • a) S. Thewissen, Ph.D. Thesis, Radboud University Nijmegen (The Netherlands), 2005;
    • (2005)
    • Thewissen, S.1
  • 46
    • 33746883511 scopus 로고    scopus 로고
    • Benchmark studies of 5d transition metals are lacking, but for 3d and 4d transition metals hybrid HF-DFT methods such as b3-lyp or B3 LYP tend to underestimate the metal-ligand bond strengths. Deviations from experimental values are generally smaller for pure DFT methods, such as BP86: a J. N. Harvey, Annu. Rep. Prog. Chem. Sect. C 2006, 102, 203-226;
    • Benchmark studies of 5d transition metals are lacking, but for 3d and 4d transition metals hybrid HF-DFT methods such as b3-lyp or B3 LYP tend to underestimate the metal-ligand bond strengths. Deviations from experimental values are generally smaller for pure DFT methods, such as BP86: a) J. N. Harvey, Annu. Rep. Prog. Chem. Sect. C 2006, 102, 203-226;
  • 49
    • 36649000258 scopus 로고    scopus 로고
    • M. P. Waller, H. Braun, N. Hojdis, M. Bühl, J. Chem. Theory Comput. 2007, 3, 2234-2242; see also references [17c] and [17d].
    • d) M. P. Waller, H. Braun, N. Hojdis, M. Bühl, J. Chem. Theory Comput. 2007, 3, 2234-2242; see also references [17c] and [17d].
  • 54
    • 35048851121 scopus 로고    scopus 로고
    • Angew. Chem. Int. Ed. 2007, 46, 7408-7411.
    • (2007) Angew. Chem. Int. Ed , vol.46 , pp. 7408-7411
  • 55
    • 53849118692 scopus 로고    scopus 로고
    • Turbomole Version 5: R. Ahlrichs, M. Bär: H.-P. Baron, R. Bauernschmitt, S. Böcker, M. Ehrig, K. Eichkorn, S. Elliott: F. Furche, F. Haase, M. Häser, C. Hättig, H. Horn, C. Huber, U. Huniar, M. Kattannek, A. Köhn, C. Kölmel, M. Kollwitz, K. May, C. Ochsenfeld, H. Öhm, A. Schäfer, U. Schneider, O. Treutler, K. Tsereteli, B. Unterreiner, M. von Arnim, F. Weigend, P. Weis, H. Weiss, Theoretical Chemistry Group, University of Karlsruhe, January 2002;
    • a) Turbomole Version 5: R. Ahlrichs, M. Bär: H.-P. Baron, R. Bauernschmitt, S. Böcker, M. Ehrig, K. Eichkorn, S. Elliott: F. Furche, F. Haase, M. Häser, C. Hättig, H. Horn, C. Huber, U. Huniar, M. Kattannek, A. Köhn, C. Kölmel, M. Kollwitz, K. May, C. Ochsenfeld, H. Öhm, A. Schäfer, U. Schneider, O. Treutler, K. Tsereteli, B. Unterreiner, M. von Arnim, F. Weigend, P. Weis, H. Weiss, Theoretical Chemistry Group, University of Karlsruhe, January 2002;
  • 57
    • 53849089468 scopus 로고    scopus 로고
    • PQS version 2.4, 2001, Parallel Quantum Solutions, Fayetteville, Arkansas, USA the Baker optimizer is available separately from PQS upon request
    • a) PQS version 2.4, 2001, Parallel Quantum Solutions, Fayetteville, Arkansas, USA (the Baker optimizer is available separately from PQS upon request);
  • 62
    • 53849128417 scopus 로고    scopus 로고
    • Turbomole basisset library, Turbomole Version 5, see [24a].
    • a) Turbomole basisset library, Turbomole Version 5, see [24a].


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.