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Preliminary results have been communicated: T. Niimi, T. Uchida, R. Irie, T. Katsuki, Tetrahedron Lett., 2000, 41, 3647-3651.
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0346750185
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note
-
[25] Although the degree of folding of the salen ligands depends upon the nature of the apical ligand and the relative configuration of the complexes, both (R,R)- and (R,S)-complexes bend in a similar moderate degree when they bear an aprotic donor ligand. Based on this study, we assumed that both (R,R)- and (R,S)-intermediate carbenoid species bearing NMI at their apical site would adopt a moderately folded stepped-conformation.
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-
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53
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85088336793
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[19d,19f, 19g, 25]
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[19d,19f, 19g, 25]
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-
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54
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0346750183
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It is reasonable to consider that carbenoid species derived Co-salen complexes bearing a bulky substituent at C3 and C3′ do not allow substrate-approach from the C3 and C3′ side because of the short distance between the C3 and C3′ substituents
-
It is reasonable to consider that carbenoid species derived Co-salen complexes bearing a bulky substituent at C3 and C3′ do not allow substrate-approach from the C3 and C3′ side because of the short distance between the C3 and C3′ substituents.
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55
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0033579635
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Hashihayata, T.1
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56
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0028074623
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H. Sasaki, R. Irie, T. Hamada, K. Suzuki, T. Katsuki, Tetrahedron, 1994, 50, 11827-11838.
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57
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0346750182
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Atomic coordinates, bond lengths and angles, and thermal parameters of tert-butyl cis-2-(2-naphthyl)cyclopropane-1-carboxylate will be available on request from the Cambridge Crystallographic Data Center, 12 Union Road, Cambridge, CB2 1EZ, U.K.
-
Atomic coordinates, bond lengths and angles, and thermal parameters of tert-butyl cis-2-(2-naphthyl)cyclopropane-1-carboxylate will be available on request from the Cambridge Crystallographic Data Center, 12 Union Road, Cambridge, CB2 1EZ, U.K.
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