Cyclopropanation of olefins with diazoalkanes, catalyzed by CoII(porphyrin) complexes - A synthetic and mechanistic investigation and the molecular structure of CoIII(TPP)(CH2CO2Et) (TPP = dianion of meso-tetraphenylporphyrin)

European Journal of Inorganic Chemistry

Volumn , Issue 7, 2003, Pages 1452-1460

  Penoni, Andrea ^a   Wanke, Riccardo ^a   Tollari, Stefano ^b   Gallo, Emma ^a   Musella, Danilo ^a   Ragaini, Fabio ^a   Demartin, Francesco ^c   Cenini, Sergio ^a  

^a CNR Consiglio Nazionale delle Ricerche   (Italy)

^b Fis Matematiche   (Italy)

^c Dipto di Chim Organ e Industriale   (Italy)

Author keywords

Cobalt; Cyclopropanation; Olefins; Porphyrinoids

Indexed keywords

COBALT COMPOUNDS; OLEFINS; PROPANE; STYRENE; X RAY DIFFRACTION;

CATALYZE REACTION; CYCLOPROPANATION; DIANIONS; DIAZOALKANES; ETHYL DIAZOACETATE; MECHANISTICS; PORPHYRIN COMPLEXES; PORPHYRINOIDS; TETRAPHENYL PORPHYRINS; TETRAPHENYLPORPHYRINS;

PORPHYRINS;

ACETIC ACID DERIVATIVE; ALKANE DERIVATIVE; ALKENE DERIVATIVE; BENZENE DERIVATIVE; COBALT DERIVATIVE; CYCLOPROPANE DERIVATIVE; DIAZONIUM COMPOUND; DIETHYLMALEATE; ETHYLDIAZOACETATE; FUMARIC ACID; MALIC ACID DERIVATIVE; PORPHYRIN DERIVATIVE; STYRENE DERIVATIVE; UNCLASSIFIED DRUG;

ARTICLE; CATALYSIS; CHEMICAL STRUCTURE; COMPLEX FORMATION; CYCLOPROPANATION; KINETICS; STOICHIOMETRY; SYNTHESIS; X RAY DIFFRACTION;

EID: 0037394943     PISSN: 14341948     EISSN: None     Source Type: Journal    
DOI: 10.1002/ejic.200390189     Document Type: Article

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