Bromoporphyrins as versatile synthons for modular construction of chiral porphyrins: Cobalt-catalyzed highly enantioselective and diastereoselective cyclopropanation

Journal of the American Chemical Society

Volumn 126, Issue 45, 2004, Pages 14718-14719

  Chen, Ying ^a   Fields, Kimberly B ^a   Zhang, X Peter ^a  

^a UNIVERSITY OF TENNESSEE   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ALCOHOL DERIVATIVE; AMIDE; AMINE; CARBON; COBALT; NITROGEN; PALLADIUM; PORPHYRIN; THIOL DERIVATIVE;

ARTICLE; CATALYSIS; CHIRALITY; CYCLOPROPANATION; ENANTIOSELECTIVITY; PROTON NUCLEAR MAGNETIC RESONANCE; STEREOCHEMISTRY;

EID: 8844247934     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja044889l     Document Type: Article

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31. It is reasonable to expect that the same results would be obtained for the frans-(1S,2S)-isomer if the enantiomer of 41 is employed as a catalyst.