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Volumn 30, Issue 5, 2011, Pages 1021-1029

Synthesis and tunability of abnormal 1,2,3-triazolylidene palladium and rhodium complexes

Author keywords

[No Author keywords available]

Indexed keywords

ANION METATHESIS; BIMETALLIC COMPLEXES; CARBENES; CHEMOSELECTIVE; CYCLOPALLADATION; FUNCTIONALIZATIONS; METALATIONS; NMR ANALYSIS; PALLADATION; RHODIUM COMPLEXES; TRANS AND CIS ISOMERS; TRANSMETALATION; TUNABILITIES;

EID: 79952397293     PISSN: 02767333     EISSN: 15206041     Source Type: Journal    
DOI: 10.1021/om101076u     Document Type: Article
Times cited : (130)

References (83)
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    • in press (DOI: 10.1039/C0DT01037E).
    • Han, Y.; Huynh, H. V. Dalton Trans. 2011, 40, in press (DOI: 10.1039/C0DT01037E).
    • (2011) Dalton Trans. , vol.40
    • Han, Y.1    Huynh, H.V.2
  • 30
    • 77956148464 scopus 로고    scopus 로고
    • First catalytic applications of such triazolylidene complexes have been disclosed recently; see ref 6 and
    • First catalytic applications of such triazolylidene complexes have been disclosed recently; see ref 6 and: Nakamura, T.; Ogata, K.; Fukuzawa, S. Chem. Lett. 2010, 39, 920
    • (2010) Chem. Lett. , vol.39 , pp. 920
    • Nakamura, T.1    Ogata, K.2    Fukuzawa, S.3
  • 48
    • 66149190813 scopus 로고    scopus 로고
    • Similar mixtures of dimetallic and monometallic complexes have been reported in the palladation of imidazolium salts
    • Similar mixtures of dimetallic and monometallic complexes have been reported in the palladation of imidazolium salts: Baker, M. V.; Brown, D. H.; Simpson, P. V.; Skelton, B. W.; White, A. H. Eur. J. Inorg. Chem. 2009, 1977
    • (2009) Eur. J. Inorg. Chem. , pp. 1977
    • Baker, M.V.1    Brown, D.H.2    Simpson, P.V.3    Skelton, B.W.4    White, A.H.5
  • 49
    • 0003660535 scopus 로고    scopus 로고
    • In 2a, the carbene resonance coincides with those due to the meta carbons of the phenyl substituent, but was unambiguously identified by long-range CH correlation spectroscopy:; Wiley-VCH: Weinheim, Germany.
    • In 2a, the carbene resonance coincides with those due to the meta carbons of the phenyl substituent, but was unambiguously identified by long-range CH correlation spectroscopy: Fribolin, H. Basic One- and Two-Dimensional NMR Spectroscopy; Wiley-VCH: Weinheim, Germany, 1998.
    • (1998) Basic One- And Two-Dimensional NMR Spectroscopy
    • Fribolin, H.1
  • 52
    • 69249239140 scopus 로고    scopus 로고
    • An earlier report suggested the formation of a monometallic complex under these conditions; see
    • An earlier report suggested the formation of a monometallic complex under these conditions; see: Karthikeyan, T.; Sankararaman, S. Tetrahedron Lett. 2009, 50, 5834
    • (2009) Tetrahedron Lett. , vol.50 , pp. 5834
    • Karthikeyan, T.1    Sankararaman, S.2
  • 56
    • 79952426840 scopus 로고    scopus 로고
    • 2 and subsequent halide metathesis with NaI provides an alternative access to pure dimetallic complexes, thus suppressing the formation of bis(carbene) palladium complexes 3. See Experimental Section for further details.
    • 2 and subsequent halide metathesis with NaI provides an alternative access to pure dimetallic complexes, thus suppressing the formation of bis(carbene) palladium complexes 3. See Experimental Section for further details.
  • 63
    • 79952410236 scopus 로고    scopus 로고
    • See the Supporting Information for representations and crystallographic details.
    • See the Supporting Information for representations and crystallographic details.
  • 73
    • 0141704190 scopus 로고    scopus 로고
    • According to these coupling constants, the triazolylidene ligands in 6 have similar donor strength to normal imidazol-2-ylidenes. See for example
    • According to these coupling constants, the triazolylidene ligands in 6 have similar donor strength to normal imidazol-2-ylidenes. See for example: Burling, S.; Field, L. D.; Li, H. L.; Messerle, B. A.; Turner, P. Eur. J. Inorg. Chem. 2003, 3179
    • (2003) Eur. J. Inorg. Chem. , pp. 3179
    • Burling, S.1    Field, L.D.2    Li, H.L.3    Messerle, B.A.4    Turner, P.5


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.