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Volumn 312, Issue 5774, 2006, Pages 722-724

Cyclopropenylidenes: From interstellar space to an isolated derivative in the laboratory

Author keywords

[No Author keywords available]

Indexed keywords

AMINO ACIDS; DERIVATIVES; ELECTRON EMISSION; THERMOANALYSIS; X RAY CRYSTALLOGRAPHY;

EID: 33646439534     PISSN: 00368075     EISSN: 10959203     Source Type: Journal    
DOI: 10.1126/science.1126675     Document Type: Article
Times cited : (213)

References (37)
  • 1
    • 2542495781 scopus 로고    scopus 로고
    • R. A. Moss, M. S. Platz, M. Jones Jr., Eds., (Wiley, New York)
    • R. A. Moss, M. S. Platz, M. Jones Jr., Eds., Reactive Intermediate Chemistry (Wiley, New York, 2004).
    • (2004) Reactive Intermediate Chemistry
  • 2
    • 0006976970 scopus 로고    scopus 로고
    • U. H. Brinker, Ed., (JAI, Greenwich, CT)
    • U. H. Brinker, Ed., Advances in Carbene Chemistry (JAI, Greenwich, CT, 2001).
    • (2001) Advances in Carbene Chemistry
  • 20
    • 33646438460 scopus 로고    scopus 로고
    • note
    • Cyclopropenylidene transition metal complexes have been known since 1968 (21), and main group adducts were recently reported (19).
  • 24
    • 33646444231 scopus 로고    scopus 로고
    • note
    • 13C NMR chemical shifts have been calculated at the RI-BP86/TZVP + ZPE correction level, and RI-BP86/TZVPP//RI-BP86/TZVP level, respectively, using Turbomole 5.7 (see www.ipc.uni-karlsruhe. de/tch/tch1/turbomole/index.en.html and references cited therein).
  • 25
    • 33646439785 scopus 로고    scopus 로고
    • note
    • For discussions on carbene dimerization, see (5) and (26); cyclopropenylidene dimers, namely triafulvalenes, remain unknown (27).
  • 35
    • 33646455966 scopus 로고    scopus 로고
    • note
    • Preparation methods and spectroscopic data for compounds 1c and 4c are available as supporting material on Science Online.
  • 37
    • 33646448497 scopus 로고    scopus 로고
    • note
    • We are grateful to NIH (grant R0l GM 68825) and RHODIA for financial support of this work. Metrical data for the solid-state structures of 1c and 4c are available free of charge from the Cambridge Crystallographic Data Centre under reference numbers CCDC-602795 and CCDC-602794, respectively.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.