Diversity-oriented synthesis of functionalized diaryl sulfones by regioselective [3+3] cyclizations of 1,3-bis(siloxy)buta-1,3-dienes with 2-(arylsulfonyl)-3-ethoxy-2-en-1-ones: Scope and limitations

Synthesis

Volumn , Issue 13, 2009, Pages 2223-2235

  Shkoor, Mohanad ^a   Riahi, Abdolmajid ^a   Fatunsin, Olumide ^a   Reinke, Helmut ^a   Fischer, Christine ^a   Langer, Peter ^a  

^a UNIVERSITY OF ROSTOCK   (Germany)

Author keywords

Arenes; Cyclizations; Regioselectivity; Silyl enol ethers; Sulfones

Indexed keywords

ARENES; CYCLIZATIONS; DIVERSITY-ORIENTED SYNTHESIS; FUNCTIONALIZED; REGIO-SELECTIVE; SILYL ENOL ETHERS; SULFONES;

AROMATIC COMPOUNDS; ETHERS; REGIOSELECTIVITY; SILANES;

CYCLIZATION;

1 ETHOXY 2 (PHENYLSULFONYL)HEPT 1 EN 3 ONE; 1,3 BUTADIENE DERIVATIVE; 3 (4 CHLOROPHENYLSULFONYL) 4 ETHOXYBUT 3 EN 2 ONE; 3 ETHOXY 1 (4 NITROPHENYL) 2 TOSYLPROP 2 EN 1 ONE; 4 ETHOXY 3 (PHENYLSULFONYL)BUT 3 EN 2 ONE; 4 ETHOXYL 3 TOSYLBUT 3 EN 2 ONE; ETHYL 3 (4 CHLOROPHENYLSULFONYL) 5 ETHYL 6 HYDROXY 2 METHYL BENZOATE; ETHYL 3 ETHYL 2 HYDROXY 6 METHYL 5 (PHENYLSULFONYL)BENZOATE; ETHYL 3 ETHYL 2 HYDROXY 6 METHYL 5 TOSYLBENZOATE; METHYL 2 HYDROXY 3 ISOBUTYL 6 METHYL 5 (PHENYLSULFONYL)BENZOATE; METHYL 2 HYDROXY 3 METHOXY 6 METHYL 5 TOSYLBENZOATE; METHYL 2 HYDROXY 3,6 DIMETHYL 5 (PHENYLSULFONYL)BENZOATE; METHYL 2 HYDROXY 3,6 DIMETHYL 5 TOSYLBENZOATE; METHYL 2 HYDROXY 6 METHYL 3 NONYL 5 (PHENYLSULFONYL)BENZOATE; METHYL 2 HYDROXY 6 METHYL 3 OCTYL 5 (PHENYLSULFONYL)BENZOATE; METHYL 2 HYDROXY 6 METHYL 3 OCTYLE 5 TOSYLBENZOATE; METHYL 3 (4 CHLOROPHENYLSULFONYL) 6 HYDROXY 2 METHYLBENZOATE; METHYL 3 (4 CHLOROPHENYLSULFONYL) 6 HYDROXY 2,5 DIMETHYL BENZOATE; METHYL 3 BUTYL 2 HYDROXY 6 METHYL 5 (PHENYLSULFONYL)BENZOATE; METHYL 3 BUTYL 2 HYDROXY 6 METHYL 5 TOSYLBENZOATE; METHYL 3 DECYL 2 HYDROXY 6 METHYL 5 (PHENYLSULFONYL)BENZOATE; METHYL 3 HEPTYL 2 HYDOXY 6 METHYL 5 (PHENYLSYLFONYL)BENZOATE; METHYL 3 HEPTYL 2 HYDROXY 6 METHYL 5 TOSYLBENZOATE; METHYL 3 HEXYL 2 HYDROXY 6 METHYL 5 (PHENYLSULFONYL)BENZOATE; METHYL 3 HEXYL 2 HYDROXY 6 METHYL 5 TOSYLBENZOATE; METHYL 5 BUTYL 3 (4 CHLOROPHENYLSULFONYL) 6 HYDROXY 2 METHYLBENZOATE; METHYL 6 HYDROXY 2 METHYL 3 (PHENYLSULFONYL)BENZOATE; METHYL 6 HYDROXY 2 METHYL 3 TOSYLBENZOATE; PHENOL DERIVATIVE; UNCLASSIFIED DRUG; UNINDEXED DRUG;

ARTICLE; CHEMICAL REACTION; CYCLIZATION; DRUG DETERMINATION; DRUG STRUCTURE; DRUG SYNTHESIS; HETERONUCLEAR MULTIPLE BOND CORRELATION; NUCLEAR OVERHAUSER EFFECT; STEREOCHEMISTRY; X RAY CRYSTALLOGRAPHY;

EID: 67651091918     PISSN: 00397881     EISSN: 1437210X     Source Type: Journal    
DOI: 10.1055/s-0029-1216801     Document Type: Article

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