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Heating during 5 h leads to a mixture of OsH4(py)(P iPr3)2 (3) and OsH3{η 2-C,N-[NC5H4, PiPr 3)2 in a ratio of 60:40. Spectroscopic data for OsH 3{η2-C,N-[NC5H4, P iPr3)2: 1H NMR (300 MHz, benzene-d6, 293 K, σ 7.81 (1H, NC5H4, 6.98 (1H, NC5H4, 6.09 (1H, NC5H4, 5.87 (1H, NC5H4, 1.81 (m, 6H, PCH(CH3) 2, 1.25 (dvt, JH-H, 6.3, N, 12.3, 36H, PCH(CH 3)2, 5.07 (br, 1H. OsH, 11.43 (br, 1H, OsH, 14.11 (t, JH-p, 13.5, 1H, OsH, 31P{1H} NMR (121.42 MHz, benzene-d6, 293 K, σ 37.5 s, These spectroscopic data agree well with those previously reported for th
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2. See reference 14j.
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101
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SHELXTL Package v. 6.10; Bruker-AXS: Madison, WI, 2000, Sheldrick, G. M. Acta Crystallogr. 2008, A64, 112.
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SHELXTL Package v. 6.10; Bruker-AXS: Madison, WI, 2000, Sheldrick, G. M. Acta Crystallogr. 2008, A64, 112.
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Pople, J. A.; et al. et al. Gaussian 03, Revision C.03; Gaussian, Inc.: Wallingford, CT, 2004,
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