메뉴 건너뛰기




Volumn 129, Issue 46, 2007, Pages 14130-14131

Rearrangement of pyridine to its 2-carbene tautomer mediated by iridium

Author keywords

[No Author keywords available]

Indexed keywords

CARBENE; IRIDIUM; PYRIDINE;

EID: 36448953136     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja075685i     Document Type: Article
Times cited : (75)

References (28)
  • 8
    • 0037059869 scopus 로고    scopus 로고
    • For recent examples of related isomerizations, see: a
    • For recent examples of related isomerizations, see: (a) Sini, G.; Eisenstein, O.; Crabtree, R. H. Inorg. Chem. 2002, 41, 602.
    • (2002) Inorg. Chem , vol.41 , pp. 602
    • Sini, G.1    Eisenstein, O.2    Crabtree, R.H.3
  • 13
    • 36448963616 scopus 로고    scopus 로고
    • DFT calculations on a model system reveal that the N-adduct is more stable than the NHC complex by ca. 9 kcal·mol-1, although the difference becomes smaller for 2-substituted pyridines. Calculations also point to very similar barriers for the pathways leading to the two products, although the simplified nature of the model used advises caution
    • -1, although the difference becomes smaller for 2-substituted pyridines. Calculations also point to very similar barriers for the pathways leading to the two products, although the simplified nature of the model used advises caution.
  • 15
    • 84944048647 scopus 로고
    • Katritzky, A. R, Rees, C. W, Eds, Pergamon Press: Oxford
    • (b) Boulton, A. J.; McKillop, A. In Comprehensive Heterocyclic Chemistry; Katritzky, A. R., Rees, C. W., Eds.; Pergamon Press: Oxford, 1984; Vol. 2, pp 1-27.
    • (1984) Comprehensive Heterocyclic Chemistry , vol.2 , pp. 1-27
    • Boulton, A.J.1    McKillop, A.2
  • 16
    • 36448947794 scopus 로고    scopus 로고
    • 11 LLedós, A.; Moncho, S.; Ujaque, G. Unpublished results.
    • 11 LLedós, A.; Moncho, S.; Ujaque, G. Unpublished results.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.