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Volumn 129, Issue 2, 2007, Pages 406-416

Isomerization dynamics and control of the η2/N equilibrium for pyridine complexes

Author keywords

[No Author keywords available]

Indexed keywords

COMPLEXATION; ISOMERIZATION; OXIDATION; SOLUBILITY; X RAY ANALYSIS;

EID: 33846240093     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja066623f     Document Type: Article
Times cited : (21)

References (49)
  • 3
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    • Abel, E. W, Stone, F. G. A, Wilkinson, G, Eds, Pergamon Press: Oxford, UK
    • Semmelhack, M. F. In Comprehensive Organometallic Chemistry II; Abel, E. W., Stone, F. G. A., Wilkinson, G., Eds.; Pergamon Press: Oxford, UK, 1995; Vol. 12, pp 979-1015.
    • (1995) Comprehensive Organometallic Chemistry II , vol.12 , pp. 979-1015
    • Semmelhack, M.F.1
  • 8
    • 0000987672 scopus 로고    scopus 로고
    • Harman, W. D. Chem. Rev. 1997, 97, 1953-1978.
    • (1997) Chem. Rev , vol.97 , pp. 1953-1978
    • Harman, W.D.1
  • 22
    • 33846215815 scopus 로고    scopus 로고
    • This complex reacts violently with oxygen even as a solid and must be kept under inert atmosphere
    • This complex reacts violently with oxygen even as a solid and must be kept under inert atmosphere.
  • 24
    • 33846198637 scopus 로고    scopus 로고
    • The pyridine complex 2 and other N-coordinated pyridine complexes described herein have reduction potentials similar to cobaltocene. Exposure to even trace amounts of an oxidant (e.g. air, water) will wipe out the NMR signals.
    • The pyridine complex 2 and other N-coordinated pyridine complexes described herein have reduction potentials similar to cobaltocene. Exposure to even trace amounts of an oxidant (e.g. air, water) will wipe out the NMR signals.
  • 26
    • 33846261419 scopus 로고    scopus 로고
    • Gaussian, Inc, Wallingford CT
    • Frisch, M. J. et al. Gaussian 03, Revision C.02, Gaussian, Inc., Wallingford CT, 2004.
    • (2004) Gaussian 03, Revision , Issue.C.02
    • Frisch, M.J.1
  • 32
    • 33846229529 scopus 로고    scopus 로고
    • At 22 °C, these peaks are well resolved, indicating that any fluxional process (e.g, ring-whizzing) is slower than the NMR measurement 300 MHz
    • At 22 °C, these peaks are well resolved, indicating that any fluxional process (e.g., "ring-whizzing") is slower than the NMR measurement (300 MHz).
  • 38
    • 33846226915 scopus 로고    scopus 로고
    • -1.
    • -1.
  • 41
    • 33846261080 scopus 로고    scopus 로고
    • ORTEP diagram shown in Ref 20.
    • ORTEP diagram shown in Ref 20.
  • 44
    • 33846259040 scopus 로고    scopus 로고
    • identified by a unique set of Tp signals and a H3 doublet at 5.88 ppm.
    • identified by a unique set of Tp signals and a H3 doublet at 5.88 ppm.
  • 48
    • 33846196114 scopus 로고    scopus 로고
    • A similar event was observed with a N-bound pyrimidine complex in which a cycloaddition takes place with the purported minor eta-2 isomer. Organometallics 2006, 25, 5852-5853
    • A similar event was observed with a N-bound pyrimidine complex in which a cycloaddition takes place with the purported minor eta-2 isomer. Organometallics 2006, 25, 5852-5853.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.