Alkane C-H Activation and Catalysis by an O-Donor Ligated Iridium Complex

Journal of the American Chemical Society

Volumn 125, Issue 47, 2003, Pages 14292-14293

  Wong Foy, Antek G ^a   Bhalla, Gaurav ^a   Liu, Xiang Yang ^a   Periana, Roy A ^a  

^a UNIVERSITY OF SOUTHERN CALIFORNIA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ALKANE; CARBON; HYDROCARBON; HYDROGEN; IRIDIUM COMPLEX; LIGAND; OXYGEN;

ARTICLE; CARBON NUCLEAR MAGNETIC RESONANCE; CATALYSIS; CHEMICAL ANALYSIS; CHEMICAL BOND; CHEMICAL STRUCTURE; GAS CHROMATOGRAPHY; MASS SPECTROMETRY; REACTION ANALYSIS; STOICHIOMETRY; STRUCTURE ANALYSIS;

EID: 0344443365     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja037849a     Document Type: Article

References (37)

1. (a) Jia, C. G.; Kitamura, T.; Fujiwara, Y. Acc. Chem. Res. 2001, 34, 633 and references therein.
2. (b) Jones, W. D. Acc. Chem. Res. 2003, 36, 140.
3. (c) Shilov, A. E.; Shul'pin, G. B. Activation and Catalytic Reactions of Saturated Hydrocarbons in the Presence of Metal Complexes; Kluwer Academic: Dordrecht, 2000.
4. (d) Crabtree, R. H. J. Chem. Soc. Dalton Trans. 2001, 19, 2437.
5. (e) Labinger, J. A.; Bercaw, J. E. Nature 2002, 417, 507.
6. (a) Fulton, J. R.; Holland, A. W.; Fox, D. J.; Bergman, R. G. Acc. Chem. Res. 2002, 35, 44.
7. (b) Jones, W. D.; Feher, F. J. Acc. Chem. Res. 1989, 22, 91.
8. (c) Harper, T. G. P.; Shinomoto, R. S.; Deming, M. A.; Flood, T. C. J. Am. Chem. Soc. 1988, 110, 7915.
9. (d) Wang, C. M.; Ziller, J. W.; Flood, T. C. J. Am. Chem. Soc. 1995, 117, 1647.
10. (e) Holtcamp, M. W.; Labinger, J. A.; Bercaw, J. E. J. Am. Chem. Soc. 1997, 119, 848.
11. (f) Periana, R. A.; Taube, D. J.; Gamble, S.; Taube, H.; Satoh, T.; Fujii, H. Science 1998, 280, 560.
12. (g) Johansson, L.; Ryan, O. B.; Tilset, M. J. Am. Chem. Soc. 1999, 121, 1974.
13. (h) Fekl, U.; Goldberg, K. I. Adv. Inorg. Chem. 2003, 5454, 259.
14. (i) Liu, F. C.; Pak, E. B.; Singh, B.; Jensen, C. M.; Goldman, A. S. J. Am. Chem. Soc. 1999, 121, 4086.
15. (j) Nuckel, S.; Burger, P. Angew. Chem., Int. Ed. 2003, 42, 1632.
16. (a) Cinellu, M. A.; Minghetti, G. Gold Bull. 2002, 35, 11.
17. (b) Sharp, P. R. J. Chem. Soc., Dalton Trans. 2000, 2647.
18. (c) Mayer, J. M. Polyhedron 1995, 3273.
19. (d) Bergman, R. G. Polyhedron 1995, 3227.
20. (e) Wigley, D. E. Prog. Inorg. Chem. 1994, 42, 239.
21. (f) Fryzuk, M. D.; Montgomery, C. D. Coord. Chem. Rev. 1989, 95, 1.
22. (g) Power, P. P. Comments Inorg. Chem. 1989, 8, 177.
23. (h) West, B. O. Polyhedron 1989, 8, 219.
24. (i) Bryndza, H. E.; Tam, W. Chem. Rev. 1988, 88, 1163.
25. (j) Griffith, W. P. Coord. Chem. Rev. 1970, 5, 459.
26. (k) LaPointe, R. E.; Wolczanski, P. T.; Van Duyne, G. D. Organometallics 1985, 4, 1810.
27. (I) Klaui, W.; Muller, A.; Eberspech, W.; Boese, R.; Goldberg, I. J. Am. Chem. Soc. 1987, 109, 164.
28. (m) Besecker, C. J.; Day, V. W.; Klemperer, W. G. Organometallics 1985, 4, 564.
29. (n) Grim, S. O.; Sangokoya, S. A.; Colquhoun, I. J.; McFarlane, W.; Khanna, R. K. Inorg. Chem. 1986, 25, 2699.
30. (o) Burk, M. J.; Crabtree, R. H. J. Am. Chem. Soc. 1987, 109, 8025.
31. (p) Tanke, R. S.; Crabtree, R. H. J. Am. Chem. Soc. 1990, 112, 7984.
32. (a) Periana, R. A.; Liu, X. Y.; Bhalla, G. Chem. Commun. 2002, 3000.
33. (b) Matsumoto, T.; Periana, R. A.; Taube, D. J.; Yoshida, H. J. Mol. Catal. A: Chem. 2002, 180, 1.
34. (c) Matsumoto, T.; Periana, R. A.; Taube, D. J.; Yoshida, H. J. Catal. 2002, 206, 272.
35. (d) Matsumoto, T.; Taube, D. J.; Periana, R. A.; Taube, H.; Yoshida, H. J. Am. Chem. Soc. 2000, 122, 7414.
36. Related Ir(V), seven-coordinate intermediates have been proposed and observed in CH activation by Ir(III) complexes. (a) Webster, C. E.; Hall, M. B. Coord. Chem. Rev. 2003, 238-239, 315-331.
37. (b) Klei, S. R.; Tilley, T. D.; Bergman, R. G. J. Am. Chem. Soc. 2000, 122, 1816.