메뉴 건너뛰기




Volumn 345, Issue 9-10, 2003, Pages 1139-1145

Room Temperature Activation of Aromatic C-H Bonds by Non-Classical Ruthenium Hydride Complexes Containing Carbene Ligands

Author keywords

C H bond activation; Deuterium exchange; Homogeneous catalysis; Hydrido complexes; N heterocyclic carbenes; Ruthenium complexes

Indexed keywords

1,3 DIMESITYL 1,3 DIHYDRO 2H IMIDAZOL 2 YLIDENE; AROMATIC COMPOUND; CARBENE; CARBON; HYDROGEN; IMIDAZOLE DERIVATIVE; LIGAND; ORGANOMETALLIC COMPOUND; PHOSPHINE; RUTHENIUM; UNCLASSIFIED DRUG;

EID: 0242607648     PISSN: 16154150     EISSN: None     Source Type: Journal    
DOI: 10.1002/adsc.200303091     Document Type: Article
Times cited : (87)

References (28)
  • 21
    • 0003471615 scopus 로고    scopus 로고
    • Kluver Academic/Plenum Publishers, New York
    • G. J. Kubas, Metal Dihydrogen and σ-Bond Complexes, Kluver Academic/Plenum Publishers, New York, 2001; b) P. J. Jessop, R. H. Morris, Coord. Chem. Rev. 1992, 121, 155-284.
    • (2001) Metal Dihydrogen and σ-Bond Complexes
    • Kubas, G.J.1
  • 22
    • 2142774500 scopus 로고
    • G. J. Kubas, Metal Dihydrogen and σ-Bond Complexes, Kluver Academic/Plenum Publishers, New York, 2001; b) P. J. Jessop, R. H. Morris, Coord. Chem. Rev. 1992, 121, 155-284.
    • (1992) Coord. Chem. Rev. , vol.121 , pp. 155-284
    • Jessop, P.J.1    Morris, R.H.2
  • 25
    • 0242402669 scopus 로고    scopus 로고
    • note
    • Calculations on 3a were carried out using the Gaussian98 and the Turbomole5.5 suite of programs. Gaussian98 calculations which were used as input for CDA-analysis were done on the B3LYP level of theory using the 6-31G(d) basis set for C, H, N and P and a (441/2111/31/1) valence basis for Ru associated with a non relativistic small core ECP. Turbomole calculations were carried out on the BP86 level of theory taking advantage of the RI-DFT method using the TZVP basis set together with a quasirelativistic ECP for Ru. All geometry optimisations were carried out with no constraints and all geometries were checked to be minima on the hypersurface by frequency calculations (zero imaginary frequencies). Further details and the full references for the computational methods are compiled in the Supplementary Material.
  • 27
    • 0034296864 scopus 로고    scopus 로고
    • and references cited therein
    • For precedence of exchange processes in cyclohexyl groups attached to ruthenium phosphine groups see: C. Six, K. Beck, A. Wegner, W. Leitner, Organometallics 2000, 19, 4639-4642 and references cited therein.
    • (2000) Organometallics , vol.19 , pp. 4639-4642
    • Six, C.1    Beck, K.2    Wegner, A.3    Leitner, W.4


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.