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Volumn , Issue 12, 2009, Pages 1831-1844

Mechanistic manifold and new developments of the Julia-Kocienski reaction

Author keywords

Modified Julia Kocienski reaction; Olefination; Sulfones

Indexed keywords


EID: 63849216637     PISSN: 1434193X     EISSN: 10990690     Source Type: Journal    
DOI: 10.1002/ejoc.200801117     Document Type: Article
Times cited : (239)

References (119)
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    • Under Barbier-type conditions, the base is added on a mixture of aldehyde and sulfone. These conditions often limit the selfcondensation of the sulfones. On the other hand, premetallate conditions consist of the deprotonation of the sulfone with a base prior addition of the aldehydes. The schemes used in this microreview are self-explanatory in regard to which reaction conditions have been used by the respective authors
    • Under Barbier-type conditions, the base is added on a mixture of aldehyde and sulfone. These conditions often limit the selfcondensation of the sulfones. On the other hand, premetallate conditions consist of the deprotonation of the sulfone with a base prior addition of the aldehydes. The schemes used in this microreview are self-explanatory in regard to which reaction conditions have been used by the respective authors.
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    • For an alternative preparation of alkyl and aryl benzylidcnecyclopropanes relying on TBT cyclopropyl sulfones, see: A. Fürstner, C. Aïssa, J. Am. Chem. Soc. 2006, 128, 6306-6307
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    • For a notable and to the best of our knowledge unique example of stereoselective transformation of trisubstituted olefins using BT sulfones, see: J. S. Yadav, M. Satyanarayana, G. Srinivasulu, A. C. Kunwar, Synlett 2007, 1577-1580
    • For a notable and to the best of our knowledge unique example of stereoselective transformation of trisubstituted olefins using BT sulfones, see: J. S. Yadav, M. Satyanarayana, G. Srinivasulu, A. C. Kunwar, Synlett 2007, 1577-1580.
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* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.