Unexpected cis-selectivity in (Sylvestre) Julia Olefinations with Bu 3Sn-containing allyl benzothiazolyl sulfones: Stereoselective synthesis of 1,3-butadienyl- and 1,3,5-hexatrienylstannanes

Synlett

Volumn , Issue 2, 2005, Pages 289-293

  Sorg, Achim ^a   Brückner, Reinhard ^a  

^a UNIVERSITY OF FREIBURG   (Germany)

Author keywords

Alkenylstannanes; Dienes; Julia Lythgoe olefination; Stereoselectivity; Trienes

Indexed keywords

1,3 BUTADIENYLSTANNANE DERIVATIVE; 1,3,5 HEXATRIENYLSTANNANE DERIVATIVE; ALDEHYDE; ALLYL BENZOTHIAZOLYL SULFONE DERIVATIVE; BENZOTHIAZOLE DERIVATIVE; BENZOTHIAZOLYLSULFONE DERIVATIVE; SULFONE DERIVATIVE; TIN DERIVATIVE; TRIBUTYLTIN; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL STRUCTURE; CIS ISOMER; JULIA LYTHGOE OLEFINATION; OLEFINATION; STEREOCHEMISTRY; STRUCTURE ANALYSIS; SYNTHESIS;

EID: 13844262686     PISSN: 09365214     EISSN: None     Source Type: Journal    
DOI: 10.1055/s-2004-837213     Document Type: Article

References (43)

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4. (a) A cis-selective variant of the (Marc) Julia-Lythgoe olefination was reported, too: Bremmer, J.; Julia, M.; Launay, M.; Stacino, J. P. Tetrahedron Lett. 1982, 23, 3265.
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