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Volumn , Issue 10, 2007, Pages 1577-1580

A stereoselective synthesis of the C20-C32 fragment of the phorboxazoles

Author keywords

Desymmetrization; Epimerization; Julia olefination; Phorboxazole

Indexed keywords

PHORBOXAZOLE A; PHORBOXAZOLE B;

EID: 34347332420     PISSN: 09365214     EISSN: None     Source Type: Journal    
DOI: 10.1055/s-2007-982556     Document Type: Article
Times cited : (8)

References (48)
  • 40
    • 34347340142 scopus 로고    scopus 로고
    • C3-H-C4-H = 4.53 Hz. (Chemical Equation Presented)
    • C3-H-C4-H = 4.53 Hz. (Chemical Equation Presented)
  • 47
    • 0037038993 scopus 로고    scopus 로고
    • Review on modified Julia olefination: (c) Blakemore, P. R. J. Chem. Soc., Perkin Trans. 1 2002, 2563.
    • Review on modified Julia olefination: (c) Blakemore, P. R. J. Chem. Soc., Perkin Trans. 1 2002, 2563.
  • 48
    • 34347365818 scopus 로고    scopus 로고
    • Spectral Data: Compound 1 [α]D +28.26 (c 0.01, CHCl3, 1H NMR (200 MHz, CDCl 3, δ, 0.82 (d, J, 6.07 Hz, 3 H, 0.96 (d, J, 6.96 Hz, 3 H, 1.60-2.16 (m, 4 H) 1.87 (s, 3 H, 2.42 (s, 3 H, 3.24 (dd, J, 5.20, 10.41 Hz, 1 H, 3.44-3.76 (m, 3 H, 4.30-4.68 (m, 5 H, 6.10 (s, 1 H, 7.20-7.34 (m, 10 H, 7.38 (s, 1 H, 13C NMR (50 MHz, CDCl3, δ, 5.80, 13.23, 13.69, 18.72, 33.02, 33,38, 34.44, 67.03, 69.97, 72.95, 74.46, 76.28, 76.92, 77.56, 79.77, 83.99, 119.46, 127.44, 127.62, 128.26, 135.18, 137.24, 138.49, 138.67; LC-MS: m/z, 476 [M, H, Compound 10: [α]D +57.29 (c 1.85, CHCl3, 1H NMR (200 MHz, CDCl3, δ, 0.98 (d, J, 7.18 Hz, 3 H, 1.05 (d, J, 7.81 Hz, 3 H, 2.0-2.20 (m, 2 H, 2.25-2.36 (dd, J, 3.9, 15.6 Hz, 1 H, 2.57-2.70 (m, 1 H, 3.30 s, 3 H
    • +].


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.