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C3-H-C4-H = 4.53 Hz. (Chemical Equation Presented)
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C3-H-C4-H = 4.53 Hz. (Chemical Equation Presented)
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48
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34347365818
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Spectral Data: Compound 1 [α]D +28.26 (c 0.01, CHCl3, 1H NMR (200 MHz, CDCl 3, δ, 0.82 (d, J, 6.07 Hz, 3 H, 0.96 (d, J, 6.96 Hz, 3 H, 1.60-2.16 (m, 4 H) 1.87 (s, 3 H, 2.42 (s, 3 H, 3.24 (dd, J, 5.20, 10.41 Hz, 1 H, 3.44-3.76 (m, 3 H, 4.30-4.68 (m, 5 H, 6.10 (s, 1 H, 7.20-7.34 (m, 10 H, 7.38 (s, 1 H, 13C NMR (50 MHz, CDCl3, δ, 5.80, 13.23, 13.69, 18.72, 33.02, 33,38, 34.44, 67.03, 69.97, 72.95, 74.46, 76.28, 76.92, 77.56, 79.77, 83.99, 119.46, 127.44, 127.62, 128.26, 135.18, 137.24, 138.49, 138.67; LC-MS: m/z, 476 [M, H, Compound 10: [α]D +57.29 (c 1.85, CHCl3, 1H NMR (200 MHz, CDCl3, δ, 0.98 (d, J, 7.18 Hz, 3 H, 1.05 (d, J, 7.81 Hz, 3 H, 2.0-2.20 (m, 2 H, 2.25-2.36 (dd, J, 3.9, 15.6 Hz, 1 H, 2.57-2.70 (m, 1 H, 3.30 s, 3 H
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+].
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