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Volumn , Issue 20, 2006, Pages 4747-4754

3,5-Bis(trifluoromethyl)phenyl sulfones in the Julia-Kocienski olefination - Application to the synthesis of tri- and tetrasubstituted olefins

Author keywords

Alkenes; Carbanions; Olefination; Phosphazenes; Sulfones

Indexed keywords


EID: 33750404040     PISSN: 1434193X     EISSN: 10990690     Source Type: Journal    
DOI: 10.1002/ejoc.200600478     Document Type: Article
Times cited : (20)

References (86)
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    • For a review on desulfonylation reactions, see: C. Nájera, M. Yus, Tetrahedron 1999, 55, 10547-10658.
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    • Corrigendum: A. B. Charette, C. Berthelette, D. St-Martin, Tetrahedron Lett. 2001, 42, 6619
    • a) A. B. Charette, C. Berthelette, D. St-Martin, Tetrahedron Lett. 2001, 42, 5149-5153; Corrigendum: A. B. Charette, C. Berthelette, D. St-Martin, Tetrahedron Lett. 2001, 42, 6619;
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    • For the latest applications of PT-sulfones in total synthesis, see
    • For the latest applications of PT-sulfones in total synthesis, see: a) C. Marti, E. M. Carreira, J. Am. Chem. Soc. 2005, 127, 11505-11515;
    • (2005) J. Am. Chem. Soc. , vol.127 , pp. 11505-11515
    • Marti, C.1    Carreira, E.M.2
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    • Very recently, the application of 4-nitrophenyl sulfones in the modified Julia olefination of aldehydes has been reported: D. Mirk, J.-M. Grassot, J. Zhu, Synlett 2006, 1255-1259.
    • (2006) Synlett , pp. 1255-1259
    • Mirk, D.1    Grassot, J.-M.2    Zhu, J.3
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    • note
    • [30a].
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    • This is a simple, green and general method for the oxidation of sulfides to sulfones: D. A. Alonso, C. Nájera, M. Varea, Tetrahedron Lett. 2002, 43, 3459-3461.
    • (2002) Tetrahedron Lett. , vol.43 , pp. 3459-3461
    • Alonso, D.A.1    Nájera, C.2    Varea, M.3
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    • note
    • In this experiment, >90% of the starting BTFP sulfone 8d was recovered, indicating that the failure of the reaction was not due to decomposition of the sulfone carbanion.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.