Direct preparation of Z-1,3-enyne systems with a TMS-propargylic sulfone: Application of a one-pot Julia olefination

Synlett

Volumn , Issue 13, 2006, Pages 2079-2082

  Bonini, Carlo ^a   Chiummiento, Lucia ^a   Videtta, Valeria ^a  

^a UNIVERSITY OF BASILICATA   (Italy)

Author keywords

Aldehydes; Enynes; Natural products; Olefination; Propargylic sulfones

Indexed keywords

SULFONE DERIVATIVE;

ARTICLE; CHEMICAL REACTION; CHEMICAL STRUCTURE; MEDICAL RESEARCH; OLEFINATION;

EID: 33748276427     PISSN: 09365214     EISSN: None     Source Type: Journal    
DOI: 10.1055/s-2006-948196     Document Type: Article

References (38)

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36. Preparation of aldehyde 8f, starting from the alcohol 9 (Scheme 3). Alcohol 9 was prepared according to: Bonini, C.; Chiummiento, L.; Videtta, V.; Colobert, F.; Solladié, G., manuscript in preparation. (Diagram presented) Scheme 3
37. No β-elimination product was observed for aldehyde 8e. Moreover, the optical rotation for the unreacted aldehyde 8f shows the same the value of the starting aldehyde, thus indicating that no epimerization reaction occurs.
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